Bipyridines and oligopyridines
Bipyridines and oligopyridines represent a class of organic compounds characterized by the presence of two or more pyridine rings linked together through their aromatic moieties. These molecules are widely studied in chemistry due to their unique electronic properties, stability, and potential applications in various fields.
Bipyridines, specifically, feature two pyridine rings connected through their nitrogen atoms, forming a planar structure with strong π-electron delocalization. This results in the formation of extended conjugation systems that enhance their redox activity and photophysical behavior, making them valuable reagents in organic synthesis and potential ligands for metal complexes.
Oligopyridines extend this concept to include three or more pyridine rings. These compounds exhibit even greater π-electron delocalization and enhanced stability compared to bipyridines. Their extended conjugation systems significantly influence their electronic properties, making them interesting candidates in the development of conductive polymers, sensors, and other functional materials.
The synthesis of these compounds typically involves multistep organic reactions such as Friedel-Crafts alkylation or acylation, followed by coupling reactions to form the desired structures. Due to their versatile chemical behavior, bipyridines and oligopyridines find applications in areas including catalysis, materials science, and pharmaceuticals.
| Structure | Chemical Name | CAS | MF |
|---|---|---|---|
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N,N,6'-Trimethyl-3-(4-(methylsulfonyl)phenyl)-2,3'-bipyridin-5-amine | 646459-39-4 | C20H21N3O2S |
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Hydrogen chlorotrioxochromate(1-) , compound with 2,2-bipyridine (1:1) | 76899-34-8 | C10H9ClCrN2O3 |
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3-Pyridinecarboxamide,5-[3-(2-methoxyphenyl)-1H-pyrrolo[2,3-b]pyridin-5-yl]-N,N-dimethyl- | 875634-01-8 | C22H20N4O2 |
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2,2':6',2''-Terpyridine,4-(4-methoxyphenyl)- (9CI) | 337511-97-4 | C22H17N3O |
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[2,3'-Bipyridine]-3,4'-diol | 89945-98-2 | C10H8N2O2 |
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1H-Pyrrolo[2,3-b]pyridine, 5-(6-methoxy-3-pyridinyl)- | 918522-25-5 | C13H11N3O |
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2-Methyl-6-oxo-1,6-dihydro-[3,4'-bipyridine]-5-carboxamide | 8004-99-7 | C12H11N3O2 |
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5-(4-Bromophenyl)-2,3'-bipyridine | 917897-54-2 | C16H11BrN2 |
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2,2-Bipyridine-3,3-dicarboxylic Acid | 4433-01-6 | C12H8N2O4 |
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4,4'-Bis(diethylmethylphosphonate)-2,2'-bipyridine | 176220-38-5 | C20H30N2O6P2 |
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