- Low viscosity azide-containing mono and dicationic ionic liquids with unsaturated side chainFareghi-Alamdari, Reza; Hatefipour, Razieh, Journal of Molecular Liquids, 2017, 225, 793-799
Cas no 98806-09-8 (1H-Imidazolium, 1-methyl-3-(2-propenyl)-)
98806-09-8 structure
Product Name:1H-Imidazolium, 1-methyl-3-(2-propenyl)-
CAS No:98806-09-8
MF:C7H11N2
MW:123.175641298294
CID:4377520
PubChem ID:11229455
Update Time:2025-04-24
1H-Imidazolium, 1-methyl-3-(2-propenyl)- Chemical and Physical Properties
Names and Identifiers
-
- 1H-Imidazolium, 1-methyl-3-(2-propenyl)-
- DTXSID6048094
- DTXCID7028065
- SCHEMBL173392
- NS00114808
- 1-ALLYL-3-METHYLIMIDAZOLIUM
- 7KXP39NT49
- 98806-09-8
- 1-Methyl-3-(2-propen-1-yl)-1H-imidazolium
- CHEMBL3306823
- NCGC00248726-01
- 1H-Imidazolium, 1-methyl-3-(2-propen-1-yl)-
- 1-allyl-3-methylimidazolium fluoride
-
- Inchi: 1S/C7H11N2/c1-3-4-9-6-5-8(2)7-9/h3,5-7H,1,4H2,2H3/q+1
- InChI Key: WWVMHGUBIOZASN-UHFFFAOYSA-N
- SMILES: N1(C=C[N+](C)=C1)CC=C
Computed Properties
- Exact Mass: 123.092223359g/mol
- Monoisotopic Mass: 123.092223359g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 9
- Rotatable Bond Count: 2
- Complexity: 101
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- XLogP3: 0.9
- Topological Polar Surface Area: 8.8?2
1H-Imidazolium, 1-methyl-3-(2-propenyl)- Production Method
Production Method 1
Reaction Conditions
1.1 Solvents: Water ; 24 h, 313 K
Reference
Production Method 2
Reaction Conditions
1.1 333 K
Reference
- Synthesis and characterization of imidazolium dicyanamide ionic liquidsZheng, Yong; Lu, Huichao; Tian, Dayong; Zheng, Yongjun, Guangdong Huagong, 2015, 42(17),
Production Method 3
Reaction Conditions
Reference
- The Enhanced Dissolution of β-Cyclodextrin in Some Hydrophilic Ionic LiquidsZheng, Yong; Xuan, Xiaopeng; Wang, Jianji; Fan, Maohong, Journal of Physical Chemistry A, 2010, 114(11), 3926-3931
Production Method 4
Reaction Conditions
1.1 Solvents: Acetone ; 48 h, rt
Reference
Thermophysical properties of ionic liquid with thiocyanate anion: effect of cations
Gonfa, G.; et al,
Advanced Materials Research (Durnten-Zurich,
2013,
626,
686-690
Production Method 5
Reaction Conditions
1.1 Reagents: Triphenylphosphine , Diisopropyl azodicarboxylate Solvents: Acetonitrile ; 15 h, rt
Reference
An efficient protocol for the preparation of pyridinium and imidazolium salts based on the Mitsunobu reaction
Petit, Sylvain;
Azzouz, Rabah;
Fruit, Corinne;
Bischoff, Laurent;
Marsais, Francis,
Tetrahedron Letters,
2008,
49(22),
3663-3665
Production Method 6
Reaction Conditions
1.1 Solvents: Acetonitrile ; 0 °C; 24 - 48 h, 30 °C
1.2 Reagents: Sodium tetrafluoroborate Solvents: Acetone ; 24 h, rt
1.2 Reagents: Sodium tetrafluoroborate Solvents: Acetone ; 24 h, rt
Reference
Synthesis and properties of ionic liquids: imidazolium tetrafluoroborates with unsaturated side chains
Min, Gwan-Hong;
Yim, Taeeun;
Lee, Hyun Yeong;
Huh, Dal Ho;
Lee, Eunjoo; et al,
Bulletin of the Korean Chemical Society,
2006,
27(6),
847-852
Production Method 7
Reaction Conditions
1.1 Reagents: Tetrafluoroboric acid Solvents: Water ; 0 °C; 1 h, 0 °C → rt
1.2 10 min, 150 °C
1.2 10 min, 150 °C
Reference
Rapid Continuous-Flow Water-Free Synthesis of Ultrapure Ionic Liquids Assisted by Microwaves
Cao, Lei;
Kim, Hong Won;
Jeong, Yu Jin;
Han, Seung Chang;
Park, Jin Kyoon,
Organic Process Research & Development,
2022,
26(1),
207-214
Production Method 8
Reaction Conditions
1.1 Reagents: Ammonium tetrafluoroborate ; 22 h, 110 °C
Reference
A general and direct synthesis of imidazolium ionic liquids using orthoesters
Kim, Do Joong;
Oh, Kyung Hwan;
Park, Jin Kyoon,
Green Chemistry,
2014,
16(9),
4098-4101
Production Method 9
Reaction Conditions
1.1 Reagents: Sodium tetrafluoroborate Solvents: Dichloromethane ; 12 h, 25 °C
Reference
Direct Synthesis of Imidazolium-Functional Polyethylene by Insertion Copolymerization
Jian, Zhongbao;
Leicht, Hannes;
Mecking, Stefan,
Macromolecular Rapid Communications,
2016,
37(11),
934-938
Production Method 10
Reaction Conditions
1.1 Reagents: Sodium borohydride Solvents: Acetone ; 24 h, rt
Reference
Preparation of ionic liquids containing unsaturated double bonds for use in cellulose dissolving and derivatizing
,
China,
,
,
Production Method 11
Reaction Conditions
1.1 Solvents: Acetone ; 60 h, rt
Reference
- Ionic Liquid Screening for Ethylbenzene/Styrene Separation by Extractive DistillationJongmans, Mark T. G.; Schuur, Boelo; de Haan, Andre B., Industrial & Engineering Chemistry Research, 2011, 50(18), 10800-10810
Production Method 12
Reaction Conditions
1.1 Solvents: Acetone ; 48 h, rt
Reference
- Thermodynamic properties of binary systems containing 1-allyl-3-methylimidazolium dicyanamide [Amim][DCA] with short chain alcohols and prediction of surface tension based on molar surface Gibbs free energyWei, Jie; Miao, Jialin; Li, Li; Zhang, Yuxin; Gao, Peizhen; et al, Journal of the Taiwan Institute of Chemical Engineers, 2022, 134,
Production Method 13
Reaction Conditions
Reference
- Synthesis and hypergolic activity evaluation of some new ammonium-imidazolium based ionic liquidsFareghi-Alamdari, Reza; Ghorbani-Zamani, Faezeh; Zekri, Negar, RSC Advances, 2016, 6(31), 26386-26391
Production Method 14
Reaction Conditions
Reference
- Thermophysical properties of ionic liquid with thiocyanate and dicynamide anionsGonfa, G.; Bustam, M. A.; Murugesan, T.; Man, Z.; Abdul Mutalib, M. I., Key Engineering Materials, 2014, 594, 594-595
Production Method 15
Reaction Conditions
1.1 Solvents: Methanol ; 3 d, rt
Reference
- Nonaborane and Decaborane Cluster Anions Can Enhance the Ignition Delay in Hypergolic Ionic Liquids and Induce Hypergolicity in Molecular SolventsMcCrary, Parker D.; Barber, Patrick S.; Kelley, Steven P.; Rogers, Robin D., Inorganic Chemistry, 2014, 53(9), 4770-4776
Production Method 16
Reaction Conditions
Reference
- Synthesis and thermal characterization of mono and dicationic imidazolium pyridinium based ionic liquidsAlamdari, Reza Fareghi; Zamani, Faezeh Ghorbani; Shekarriz, Marzieh, Oriental Journal of Chemistry, 2015, 31(2), 1127-1132
Production Method 17
Reaction Conditions
1.1 Solvents: Acetone ; 24 h
Reference
Preparation of ionic liquids containing unsaturated double bonds for use in cellulose dissolving and derivatizing
,
China,
,
,
Production Method 18
Reaction Conditions
1.1 12 h, reflux
2.1 Solvents: Acetone ; 24 h
2.1 Solvents: Acetone ; 24 h
Reference
Preparation of ionic liquids containing unsaturated double bonds for use in cellulose dissolving and derivatizing
,
China,
,
,
Production Method 19
Reaction Conditions
1.1 -
2.1 Solvents: Acetone ; 48 h, rt
2.1 Solvents: Acetone ; 48 h, rt
Reference
Thermophysical properties of ionic liquid with thiocyanate anion: effect of cations
Gonfa, G.; et al,
Advanced Materials Research (Durnten-Zurich,
2013,
626,
686-690
Production Method 20
Reaction Conditions
1.1 Solvents: Hexane ; 10 min, -78 °C; -78 °C → rt
Reference
Allyl-functionalised ionic liquids: synthesis, characterisation, and reactivity
Zhao, Dongbin;
Fei, Zhaofu;
Geldbach, Tilmann J.;
Scopelliti, Rosario;
Laurenczy, Gabor; et al,
Helvetica Chimica Acta,
2005,
88(3),
665-675
Production Method 21
Reaction Conditions
1.1 Reagents: Tetrafluoroboric acid ; 2 h, rt
Reference
Polymeric ionic liquid modified silica for CO2 adsorption and diffusivity
Sun, Yachai;
Zhu, Jiamei;
Huang, Junhua;
Xin, Feng;
Liu, Jingxia,
Polymer Composites,
2017,
38(4),
759-766
1H-Imidazolium, 1-methyl-3-(2-propenyl)- Raw materials
- Borate(1-),tetrafluoro-
- Cyanamide, cyano-, silver(1+) salt
- 1H-Imidazolium,1-methyl-3-(2-propen-1-yl)-, bromide (1:1)
- 1-Allyl-3-methylimidazolium chloride
- N-Cyanocyanamide Sodium Salt
- Oxonium, trimethyl-(9CI)
- dicyanamide
- Sodium sulfocyanate
- 1-Allylimidazole
- 1-Methylimidazole
1H-Imidazolium, 1-methyl-3-(2-propenyl)- Preparation Products
1H-Imidazolium, 1-methyl-3-(2-propenyl)- Related Literature
-
Shun-Ze Zhan,Mian Li,Xiao-Ping Zhou,Dan Li,Seik Weng Ng RSC Adv., 2011,1, 1457-1459
-
Gloria Belén Ramírez-Rodríguez,José Manuel Delgado-López,Jaime Gómez-Morales CrystEngComm, 2013,15, 2206-2212
-
Huading Zhang,Lee R. Moore,Maciej Zborowski,P. Stephen Williams,Shlomo Margel,Jeffrey J. Chalmers Analyst, 2005,130, 514-527
-
Jason Y. C. Lim,Yong Yu,Guorui Jin,Kai Li,Yi Lu,Jianping Xie Nanoscale Adv., 2020,2, 3921-3932
-
Tao Wang,Yangyang Liu,Yue Deng,Hongbo Fu,Jianmin Chen Environ. Sci.: Nano, 2018,5, 1821-1833
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