Production Method 1

96-17-3

Reaction Conditions

1.1 Reagents: Chlorotrimethylsilane ,  Hexamethylphosphoramide ,  Lithium iodide Solvents: Dimethyl sulfide

Reference

New copper chemistry. Part 15. Organocopper reagents in dimethyl sulfide

Bertz, Steven H.; Dabbagh, Gary, Tetrahedron, 1989, 45(2), 425-34

Production Method 2

497-03-0

96-17-3

Reaction Conditions

1.1 Reagents: Hydrogen

Reference

Interconversion of pure individual isomers of hydroperoxides of unsaturated fatty acid methyl esters

Chan, H. W. S.; Levett, G., Actes Congr. Mond. - Soc. Int. Etude Corps Gras, 1976, , 13-18

Production Method 3

1115-11-3

96-17-3

Reaction Conditions

1.1 Reagents: Hydrogen Catalysts: Oxygen ,  Palladium, bis[bis(1,1-dimethylethyl)phosphine]bis[μ-[bis(1,1-dimethylethyl)phos… Solvents: Tetrahydrofuran

Reference

Mild reduction of α,β-unsaturated ketones and aldehydes with an oxygen-activated palladium catalyst

Sommovigo, Milena; Alper, Howard, Tetrahedron Letters, 1993, 34(1), 59-62

Production Method 4

624-64-6

96-17-3

Reaction Conditions

1.1 Solvents: Tetrahydrofuran

Reference

Distribution of labeled plant growth regulators within cells

Zwar, J. A.; Brown, Robert, Nature (London, 1968, 220(5166), 500-1

Production Method 5

96-17-3

Reaction Conditions

1.1 Reagents: Oxygen Catalysts: Titania Solvents: (Trifluoromethyl)benzene ;  30 min, 1 atm, 303 K; 24 h, 1 atm, 303 K

Reference

Visible light induced Efficient Selective Oxidation of Non-Activated Alcohols over {001} Faceted TiO2 with Molecular Oxygen

Ghosh, Subhash Chandra; Vadakkekara, Raji; Biswas, Abulkalam; Sahoo, Tapan; Pal, Provas; et al, Chemistry - An Asian Journal, 2016, 11(21), 3084-3089

Production Method 6

30095-63-7

96-17-3

Reaction Conditions

1.1 Reagents: Silica ,  Oxygen Catalysts: Bismuthate(3-), hexachloro-, (OC-6-11)-, hydrogen, compd. with piperazine hydroc… Solvents: Ethyl acetate ;  2 - 4 h, 20 °C

Reference

Application of (C4H12N2)2[BiCl6]Cl·H2O/SiO2 in the synthesis of hydratropic aldehyde and its analogs

Nie, Shipeng; Shen, Wei; Gao, Yuhua; Tang, Yan; Zhang, Xiang; et al, Youji Huaxue, 2015, 35(11), 2393-2398

Production Method 7

116-53-0

96-17-3

Reaction Conditions

1.1 Reagents: 4-Methylmorpholine ,  2-Chloro-4,6-dimethoxy-1,3,5-triazine Solvents: 1,2-Dimethoxyethane
1.2 Reagents: Hydrogen Catalysts: Palladium Solvents: Ethanol
1.3 Solvents: Ethyl acetate

Reference

A Simple Method for the Reduction of Carboxylic Acids to Aldehydes or Alcohols Using H2 and Pd/C

Falorni, Massimo; Giacomelli, Giampaolo; Porcheddu, Andrea; Taddei, Maurizio, Journal of Organic Chemistry, 1999, 64(24), 8962-8964

Production Method 8

96-17-3

Reaction Conditions

1.1 Reagents: Dimethyl sulfoxide ,  Oxalyl chloride ,  Triethylamine Solvents: Dichloromethane

Reference

Approaches to Carbons 6-14 of Ebelactone A, Using Silicon

Ware, Anne Carole, 1988, , ,

Production Method 9

6038-09-1

96-17-3

Reaction Conditions

1.1 Reagents: Hydrogen Catalysts: Water ,  Dichlorohydrobis(tricyclohexylphosphine)rhodium Solvents: Xylene

Reference

Chemospecific, biphasic reduction of α,β-unsaturated aldehydes and ketones catalyzed by rhodium complex (Cy3P)2Rh(H)Cl2

Grushin, Vladimir V.; Alper, Howard, Organometallics, 1991, 10(4), 831-3

Production Method 10

624-64-6

96-17-3

Reaction Conditions

1.1 Reagents: Monosodium phosphate ,  Hydrogen peroxide ,  Dipotassium phosphate ,  Aluminate(1-), hydrotrimethoxy-, lithium (1:1), (T-4)- ,  (T-4)-Trihydro(tetrahydrofuran)boron Solvents: Water

Reference

Formation of carbon-carbon and carbon-heteroatom bonds via organoboranes and organoborates

Negishi, Ei-Ichi; Idacavage, Michael J., Organic Reactions (Hoboken, 1985, 33,

Production Method 11

624-64-6

96-17-3

Reaction Conditions

1.1 Reagents: Hydrogen peroxide ,  Aluminate(1-), hydrotrimethoxy-, lithium (1:1), (T-4)- ,  Borane Solvents: Tetrahydrofuran ,  Water

Reference

Reductions by metal alkoxyaluminum hydrides

Malek, Jaroslav, Organic Reactions (Hoboken, 1985, 34,

Production Method 12

96-17-3

Reaction Conditions

1.1 Reagents: N-Methylformanilide Solvents: Tetrahydrofuran

Reference

Carbenes from alkyl halides and organolithium compounds. V. Formation of alkylcyclopropenes by ring closure of alkenyl substituted carbenoid intermediates

Closs, Gerhard L.; Closs, Liselotte E., Journal of the American Chemical Society, 1963, 85, 99-104

Production Method 13

96-17-3

Reaction Conditions

1.1 Reagents: Hydrogen Catalysts: Triphenylphosphine ,  Dichloronitrosylbis(triphenylphosphine)rhodium ;  6 h, 3 MPa, 100 °C

Reference

Organic rhodium catalyst for hydroformylation reaction and its application in alkanal manufacture

, China, , ,

Production Method 14

590-18-1

96-17-3

Reaction Conditions

1.1 Reagents: Hydrogen ,  Cholestan-3-one, cyclic 1,2-bis[(diphenylphosphino)methyl]-1,2-ethanediyl acetal… Catalysts: Carbonylhydridotris(triphenylphosphine)rhodium Solvents: Benzene

Reference

The hydroformylation reaction

Ojima, Iwao; Tsai, Chung-Ying; Tzamarioudaki, Maria; Bonafoux, Dominique, Organic Reactions (Hoboken, 2000, 56,

Production Method 15

96-17-3

Reaction Conditions

1.1 Catalysts: Tempo ,  Sulfuric acid ,  Iron chloride (FeCl3) ,  Sodium bromate Solvents: Dichloromethane ,  Water ;  1 h, rt

Reference

Catalyzed oxidation of alcohols by 2,2,6,6-tetramethyl-1-iperidinyloxy with sodium bromate and ferric chloride as accelerators

Chu, Chaosen; Wang, Xiaoli; Hu, Yutao; Yan, Xiumei; Wang, Zheng, Yingyong Huaxue, 2015, 32(6), 666-670

Production Method 16

96-17-3

Reaction Conditions

Reference

Byproducts of the aqueous halogenation of amino derivatives

Abia, Li.; Armesto, X. L.; Canle, L.; Garcia, M. V.; Losada, M.; et al, Bulletin des Societes Chimiques Belges, 1996, 105(6), 349-353

Production Method 17

598-30-1

96-17-3

Reaction Conditions

Reference

Synthesis methods and reactions. 102. Aldehydes by formylation of Grignard and organolithium reagents with N-formylpiperidine

Olah, George A.; Arvanaghi, Massoud, Angewandte Chemie, 1981, 93(10), 925-6

Production Method 18

96-17-3

Reaction Conditions

1.1 Reagents: Potassium carbonate ,  Oxygen Catalysts: (3-Aminopropyl)triethoxysilane ,  Iron oxide (Fe3O4) ,  Palladium ,  Silica ,  2-Propenoic acid, methyl ester, polymer with 1-ethenyl-1H-imidazole Solvents: Water ;  22 h, 100 °C

Reference

Highly dispersible and magnetically recyclable poly(1-vinyl imidazole) brush coated magnetic nanoparticles: an effective support for the immobilization of palladium nanoparticles

Pourjavadi, Ali; Safaie, Niloofar; Hosseini, Seyed Hassan; Bennett, Craig, New Journal of Chemistry, 2016, 40(2), 1729-1736

Production Method 19

674-26-0

96-17-3

763-32-6

3944-36-3

1758-88-9

769-57-3

57-55-6

488-23-3

563-80-4

590-18-1

630-19-3

527-84-4

2381-87-5

700-12-9

Reaction Conditions

1.1 Catalysts: Davicat SiAl 3113 Solvents: Water ;  36 bar, 300 °C

Reference

Processes for conversion of biologically derived mevalonic acid

, United States, , ,

2-Methylbutyraldehyde Raw materials

• 2-Methylbutanoic acid
• D,L-Mevalonic Acid Lactone
• Tiglic aldehyde
• 2-methylbut-2-enal, trans
• trans-Methyl-2-butenal
• 2-ethyl-2-methyloxirane
• 2-BUTENE
• cis-2-Butene
• lithium(1+) ion butan-2-ide

2-Methylbutyraldehyde Preparation Products

• 3-Methyl-3-buten-1-ol (763-32-6)
• 2-Propanol,1-(1-methylethoxy)- (3944-36-3)
• 2-Ethyl-1,4-dimethylbenzene (1758-88-9)
• NSC245044 (769-57-3)
• (±)-1,2-Propanediol (57-55-6)
• 1,2,3,4-Tetramethylbenzene (488-23-3)
• 3-Methyl-2-butanone (563-80-4)
• cis-2-Butene (590-18-1)
• Trimethylacetaldehyde (630-19-3)
• o-Cymene (527-84-4)
• 4-methyl-5,6-dihydro-2H-pyran-2-one (2381-87-5)
• 1,2,3,4,5-pentamethylbenzene (700-12-9)

• 1. Establishing new scaling relations on two-dimensional MXenes for CO2 electroreduction?
  Albertus D. Handoko,Khoong Hong Khoo,Teck Leong Tan,Hongmei Jin,Zhi Wei Seh J. Mater. Chem. A, 2018,6, 21885-21890
• 2. Fate of Sb(v) and Sb(iii) species along a gradient of pH and oxygen concentration in the Carnoulès mine waters (Southern France)
  Eléonore Resongles,Corinne Casiot,Fran?oise Elbaz-Poulichet,Rémi Freydier,Odile Bruneel,Christine Piot,Sophie Delpoux,Aurélie Volant,Angélique Desoeuvre Environ. Sci.: Processes Impacts, 2013,15, 1536-1544
• 3. Emulsifier-free, organotellurium-mediated living radical emulsion polymerization (emulsion TERP) of styrene: poly(dimethylaminoethyl methacrylate) macro-TERP agent?
  Yukiya Kitayama Polym. Chem., 2014,5, 2784-2792
• 4. Excellent peroxidase mimicking property of CuO/Pt nanocomposites and their application as an ascorbic acid sensor?
  Xinhuan Wang,Shuangfei Cai,Cui Qi Analyst, 2017,142, 2500-2506
• 5. Excellent electrochemical performance of LiFe0.4Mn0.6PO4 microspheres produced using a double carbon coating process?
  Yong Ping Huang,Tao Tao,Zheng Chen,Wei Han,Ying Wu,Chunjiang Kuang,Shaoxiong Zhou,Ying Chen J. Mater. Chem. A, 2014,2, 18831-18837

• Solvents and Organic Chemicals Organic Compounds Organic oxygen compounds Organooxygen compounds Short-chain aldehydes
• Solvents and Organic Chemicals Organic Compounds Aldehyde/Ketone

• 72590-78-4((R)-form-2-Methylhexanal,)
• 1730-97-8(Butanal, 2-methyl-,(2S)-)
• 77713-01-0(Butanedial, methyl-)
• 131597-27-8(mouse vas deferens protein)
• 33204-48-7(Butanal, 2-methyl-, (2R)-)
• 97334-46-8(Pentanal, 2-ethyl-, (R)-)
• 57456-98-1((R)-2-Methylbutanal)
• 49642-48-0(2,3-dimethylbutanal)
• 2109-98-0(2,3-dimethylbutanal)
• 26140-47-6(Butanal, methyl-)