- Preparation and catalytic properties of biaryl diphosphines, World Intellectual Property Organization, , ,
Cas no 959864-38-1 ([6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane)
![[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane structure](https://ossimg.kuujia.com/scimg/960000/959864-38-1x500.png)
959864-38-1 structure
Product Name:[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane
CAS No:959864-38-1
MF:C40H32O2P2
MW:606.628412246704
MDL:MFCD10565624
CID:2356485
PubChem ID:89471619
Update Time:2024-10-25
[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane Chemical and Physical Properties
Names and Identifiers
-
- 1,1′-(1,1′,3,3′-Tetrahydro[5,5′-biisobenzofuran]-6,6′-diyl)bis[1,1-diphenylphosphine] (ACI)
- CS-0087847
- 959864-38-1
- SCHEMBL14821763
- 6,6'-Bis(diphenylphosphino)-1,1',3,3'-tetrahydro[5,5']biisobenzofuran
- 1,1'-(1,1',3,3'-Tetrahydro[5,5'-biisobenzofuran]-6,6'-diyl)bis[1,1-diphenylphosphine]
- MFCD10565624
- 6,6'-Bis(diphenylphosphino)-1,1',3,3'-tetrahydro[5,5']biisobenzofuran; 99%
- [6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane
-
- MDL： MFCD10565624
- Inchi： 1S/C40H32O2P2/c1-5-13-33(14-6-1)43(34-15-7-2-8-16-34)39-23-31-27-41-25-29(31)21-37(39)38-22-30-26-42-28-32(30)24-40(38)44(35-17-9-3-10-18-35)36-19-11-4-12-20-36/h1-24H,25-28H2
- InChI Key： ACRXDELLSSHMIK-UHFFFAOYSA-N
- SMILES： O1CC2C(=CC(=C(P(C3C=CC=CC=3)C3C=CC=CC=3)C=2)C2C(P(C3C=CC=CC=3)C3C=CC=CC=3)=CC3COCC=3C=2)C1
Computed Properties
- Exact Mass: 606.18775425g/mol
- Monoisotopic Mass: 606.18775425g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 2
- Heavy Atom Count: 44
- Rotatable Bond Count: 7
- Complexity: 780
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- XLogP3: 7.4
- Topological Polar Surface Area: 18.5?2
Experimental Properties
- Color/Form: NA
- Boiling Point: 722.3±60.0 °C at 760 mmHg
[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane Security Information
- Signal Word：warning
- Hazard Statement： H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
- Warning Statement： P264+P280+P305+P351+P338+P337+P313
- Safety Instruction： H303+H313+H333
- Storage Condition：Storage at -4 ℃ (6-12weeks), long storage period at -20 ℃ (1-2years), transport at 0 ℃
[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 601080-500mg |
[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane |
959864-38-1 | 99% | 500mg |
￥3196.0 | 2024-07-19 | |
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 601080-250mg |
[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane |
959864-38-1 | 99% | 250mg |
￥1757.8 | 2024-07-19 | |
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 601080-100mg |
[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane |
959864-38-1 | 99% | 100mg |
￥799.0 | 2024-07-19 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 15-0504-100mg |
6,6'-Bis(diphenylphosphino)-1,1',3,3'-tetrahydro[5,5']biisobenzofuran,99% |
959864-38-1 | 99% | 100mg |
912CNY | 2021-05-08 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 15-0504-500mg |
6,6'-Bis(diphenylphosphino)-1,1',3,3'-tetrahydro[5,5']biisobenzofuran,99% |
959864-38-1 | 99% | 500mg |
3648CNY | 2021-05-08 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 15-0504-100mg |
6,6'-Bis(diphenylphosphino)-1,1',3,3'-tetrahydro[5,5']biisobenzofuran,99% |
959864-38-1 | 99% | 100mg |
912.0CNY | 2021-07-12 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | 15-0504-500mg |
6,6'-Bis(diphenylphosphino)-1,1',3,3'-tetrahydro[5,5']biisobenzofuran,99% |
959864-38-1 | 99% | 500mg |
3648.0CNY | 2021-07-12 | |
| abcr | AB249272-100 mg |
6,6'-Bis(diphenylphosphino)-1,1',3,3'-tetrahydro[5,5']biisobenzofuran, 99%; . |
959864-38-1 | 99% | 100mg |
€80.70 | 2023-04-27 | |
| abcr | AB249272-500 mg |
6,6'-Bis(diphenylphosphino)-1,1',3,3'-tetrahydro[5,5']biisobenzofuran, 99%; . |
959864-38-1 | 99% | 500mg |
€300.00 | 2023-04-27 | |
| abcr | AB249272-100mg |
6,6'-Bis(diphenylphosphino)-1,1',3,3'-tetrahydro[5,5']biisobenzofuran, 99%; . |
959864-38-1 | 99% | 100mg |
€85.20 | 2025-04-14 |
[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Toluene , Tetrahydrofuran , Triethyl phosphite , Trichlorosilane ; 48 h, 100 °C
1.2 Reagents: Sodium hydroxide Solvents: Diethyl ether , Water ; 1 h, 60 °C
1.2 Reagents: Sodium hydroxide Solvents: Diethyl ether , Water ; 1 h, 60 °C
Reference
Production Method 2
Reaction Conditions
1.1 Reagents: Triethyl phosphite , Trichlorosilane Solvents: Toluene , Tetrahydrofuran ; 48 h, 100 °C
1.2 Solvents: Diethyl ether ; 0 °C
1.3 Reagents: Sodium hydroxide Solvents: Water ; 0 °C; 1 h, 60 °C
1.2 Solvents: Diethyl ether ; 0 °C
1.3 Reagents: Sodium hydroxide Solvents: Water ; 0 °C; 1 h, 60 °C
Reference
- Rhodium-Catalyzed Double [2 + 2 + 2] Cycloaddition of 1,4-Bis(diphenylphosphinoyl)buta-1,3-diyne with Tethered Diynes: A Modular, Highly Versatile Single-Pot Synthesis of NU-BIPHEP Biaryl DiphosphinesDoherty, Simon; Knight, Julian G.; Smyth, Catherine H.; Harrington, Ross W.; Clegg, William, Organic Letters, 2007, 9(23), 4925-4928
[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane Raw materials
[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane Preparation Products
[6-(6-diphenylphosphanyl-1,3-dihydro-2-benzofuran-5-yl)-1,3-dihydro-2-benzofuran-5-yl]-diphenylphosphane Related Literature
-
J. Matthew Kurley,Phillip W. Halstenberg,Abbey McAlister,Stephen Raiman,Richard T. Mayes RSC Adv., 2019,9, 25602-25608
-
Manickam Bakthadoss,Tadiparthi Thirupathi Reddy,Vishal Agarwal,Duddu S. Sharada Chem. Commun., 2022,58, 1406-1409
-
Min Kim,Jae-Joon Lee,Tengling Ye,Panagiotis E. Keivanidis,Kilwon Cho J. Mater. Chem. C, 2020,8, 1686-1696
-
Maomao Hou,Fenglin Zhong,Qiu Jin,Enjiang Liu,Jie Feng,Tengyun Wang,Yue Gao RSC Adv., 2017,7, 34392-34400
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