Production Method 1

811711-33-8

95970-22-2

Reaction Conditions

1.1 Solvents: Methanol ,  Dimethyl sulfoxide ;  reflux

Reference

Efficient and Complementary Methods Offering Access to Synthetically Valuable 1,2-Dibromobenzenes

Diemer, Vincent; Leroux, Frederic R.; Colobert, Francoise, European Journal of Organic Chemistry, 2011, (2), 327-340

Production Method 2

608-21-9

95970-22-2

38603-09-7

Reaction Conditions

1.1 Reagents: Sodium methoxide Solvents: Pyridine

Reference

Polybromo aromatic compounds. IV. Methoxydebromination of polybromobenzenes in pyridine

Shishkin, V. N.; Lapin, K. K.; Tanaseichuk, B. S.; Butin, K. P., Zhurnal Organicheskoi Khimii, 1988, 24(3), 577-83

Production Method 3

95970-21-1

95970-22-2

Reaction Conditions

1.1 Reagents: Sodium nitrite ,  Sulfuric acid Catalysts: Ethanol

Reference

Polybromo-aromatic compounds. III. Synthesis of bromo-substituted anisoles

Shishkin, V. N.; Tanaseichuk, B. S.; Lapin, K. K.; Ivkina, A. A.; Butin, K. P., Zhurnal Organicheskoi Khimii, 1984, 20(12), 2588-99

Production Method 4

95970-22-2

Reaction Conditions

Reference

Regioselective halogen-metal exchange reaction of 3-substituted 1,2-dibromo arenes: the synthesis of 2-substituted 5-bromobenzoic acids

Menzel, Karsten; Dimichele, Lisa; Mills, Paul; Frantz, Doug E.; Nelson, Todd D.; et al, Synlett, 2006, (12), 1948-1952

Production Method 5

95970-22-2

Reaction Conditions

Reference

Remote Electronic Effects in the Rhodium-Catalyzed Nucleophilic Ring Opening of Oxabenzonorbornadienes

Lautens, Mark; Schmid, Gavin A.; Chau, Anh, Journal of Organic Chemistry, 2002, 67(23), 8043-8053

1,2-dibromo-3-methoxybenzene Raw materials

• 1,2-Dibromo-3-fluorobenzene
• 3,4-Dibromo-5-methoxyaniline
• 1,2,3-Tribromobenzene

1,2-dibromo-3-methoxybenzene Preparation Products

• 1,3-Dibromo-2-methoxybenzene (38603-09-7)
• 1,2-dibromo-3-methoxybenzene (95970-22-2)

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• Solvents and Organic Chemicals Organic Compounds Alcohol/Ether

• 63936-56-1(Benzene,1,2,3,4,5-pentabromo-6-(tetrabromophenoxy)-)
• 73931-44-9(Benzene, 1,2,5-tribromo-3-methoxy-)
• 147217-78-5(2',3,4-Tribromodiphenyl Ether)
• 63387-28-0(1,2,3,4,5-Pentabromo-6-(2,3,4,5-tetrabromophenoxy)benzene)
• 602326-25-0(Benzene, 2,3-dibromo-1-(2,4-dibromophenoxy)-4-methoxy-)
• 19403-94-2(Benzene, 1,2,4,5-tetrabromo-3,6-dimethoxy-)
• 5030-61-5(2,3-Dibromo-1,4-dimethoxybenzene)
• 49690-94-0(tribromodiphenyl ether)
• 1825-26-9(1,2,3,4,5-pentabromo-6-methoxybenzene)
• 53563-56-7(1,2-dibromo-3-phenoxybenzene)