- Palladium-catalyzed Grignard cross-coupling using highly concentrated Grignards in methyltetrahydrofuranBy Milton, Edward J. and Clarke, Matthew L., Green Chemistry, 2010, 12(3), 381-383
Cas no 95408-45-0 (1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II))
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) is a highly efficient palladium-based catalyst, widely utilized in cross-coupling reactions such as Suzuki-Miyaura, Heck, and Negishi couplings. Its key advantages include exceptional air and moisture stability, facilitated by the sterically demanding di-tert-butylphosphino ligands, which enhance catalyst longevity and handling convenience. The ferrocene backbone provides structural rigidity, improving selectivity and reactivity in challenging transformations. This complex is particularly valuable for demanding synthetic applications, offering high turnover numbers (TON) and tolerance to diverse functional groups. Its robustness and predictable performance make it a preferred choice for pharmaceutical and fine chemical synthesis, where reproducibility and efficiency are critical.
95408-45-0 structure
Product Name:1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II)
CAS No:95408-45-0
MF:C26H46Cl2FeP2Pd
MW:653.761967182159
MDL:MFCD08064219
CID:91107
PubChem ID:87560219
Update Time:2025-06-07
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) Chemical and Physical Properties
Names and Identifiers
-
- 1,1'-Bis(di-tert-butylphosphino)ferrocene palladium dichloride
- [1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride
- 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
- 1,1'-Bis(di-tert-butylphosphino)-ferrocene-palladium dichloride
- 1,1'-Bis(di-tert-butylphosphino)ferrocene-palladium dichloride
- 1,1′-Bis-(di-tert.-butylphosphino-)ferrocen-palladiumdichlorid
- PdCl2(dtbpf)
- [1,1'-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)
- Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(II)
- 1,1'-Bis(di-t-butylphosphino)ferrocene palladium(II)dichloride
- Palladium, [1,1'-bis[bis(1,1-dimethylethyl)phosphino]ferrocene-P,P']dichloro-
- (SP-4-2)-[1,1'-Bis[bis(1,1-dimethylethyl)phosphino-κP]ferrocene]dichloropalladium
- Ferrocene, 1,1'-bis[bis(1,1-dimethylethyl)phosphino]-, palladium complex
- Dichloro(1,1'-bis(di-tert-butylphosphino)ferrocene)palladium
- [1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium dichloride
- 1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II)
-
- MDL： MFCD08064219
- Inchi： 1S/2C13H22P.2ClH.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h2*7-10H,1-6H3;2*1H;;/q2*-1;;;2*+2
- InChI Key： LZWLLMFYVGUUAL-UHFFFAOYSA-N
- SMILES： [Pd](Cl)Cl.[Fe+2].[PH+](C1=CC=C[CH-]1)(C(C)(C)C)C(C)(C)C.[PH+](C1=CC=C[CH-]1)(C(C)(C)C)C(C)(C)C
Computed Properties
- Exact Mass: 650.06800
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 32
- Rotatable Bond Count: 6
Experimental Properties
- Color/Form: Red crystals
- Melting Point: 203-208?°C
- Solubility: Soluble in dichloromethane and chloroform. Partially soluble in acetone, alcohols, tertrahydrofuran and dioxane.
- PSA: 27.18000
- LogP: 9.65990
- Solubility: Not determined
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) Security Information
-
Symbol:
- Prompt：warning
- Signal Word：Warning
- Hazard Statement： H315-H319
- Warning Statement： P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
- Hazardous Material transportation number：NONH for all modes of transport
- WGK Germany：3
- Safety Instruction： 24/25
-
Hazardous Material Identification：
- Storage Condition：?20°C
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600073-250mg |
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) |
95408-45-0 | 98% | 250mg |
￥120.0 | 2024-07-19 | |
| SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd. | 600073-1g |
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) |
95408-45-0 | 98% | 1g |
￥258.0 | 2024-07-19 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | B124576-1g |
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) |
95408-45-0 | 98% | 1g |
￥978.90 | 2023-09-04 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | B124576-250mg |
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) |
95408-45-0 | 98% | 250mg |
￥514.90 | 2023-09-04 | |
| SHANG HAI A LA DING SHENG HUA KE JI GU FEN Co., Ltd. | B124576-5g |
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) |
95408-45-0 | 98% | 5g |
￥3707.90 | 2023-09-04 | |
| Alichem | A450000507-10g |
1,1'-Bis(di-tert-butylphosphino)ferrocene-palladium dichloride |
95408-45-0 | 98% | 10g |
$402.78 | 2023-08-31 | |
| Alichem | A450000507-25g |
1,1'-Bis(di-tert-butylphosphino)ferrocene-palladium dichloride |
95408-45-0 | 98% | 25g |
$898.80 | 2023-08-31 | |
| Alichem | A450000507-100g |
1,1'-Bis(di-tert-butylphosphino)ferrocene-palladium dichloride |
95408-45-0 | 98% | 100g |
$2935.50 | 2023-08-31 | |
| Chemenu | CM102819-5g |
1,1'-Bis(di-tert-butylphosphino)ferrocene-palladium dichloride |
95408-45-0 | 98% | 5g |
$209 | 2021-08-06 | |
| YAN FENG KE JI （ BEI JING ） Co., Ltd. | H77044-250mg |
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) |
95408-45-0 | 98% | 250mg |
￥100 | 2023-09-19 |
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) Production Method
Production Method 1
Reaction Conditions
1.1R:PdCl4 ?2Na, S:25265-68-3, S:MeCN, 10 min, 140°C
Reference
Production Method 2
Reaction Conditions
1.1R:PdCl2(CH3CN)2
Reference
- Palladium-catalyzed borylation of aryl iodides with 2,3-dihydro-1H-benzo[d][1,3,2]diazaborolesBy Murata, Miki et al, Heterocycles, 2014, 88(1), 193-199
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) Raw materials
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) Preparation Products
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) Suppliers
Amadis Chemical Company Limited
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(CAS:95408-45-0)1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride
Order Number:A857645
Stock Status:in Stock
Quantity:10g/25g/100g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 08:08
Price ($):230.0/548.0/2192.0
Email:[email protected]
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
Audited Supplier
(CAS:95408-45-0)1,1-雙(二-叔丁基膦)二茂鐵二氯合鈀
Order Number:LE2471525
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:39
Price ($):discuss personally
Email:[email protected]
1,1'-Bis(di-tert-butylphosphino)ferrocenedichloropalladium(II) Related Literature
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Marcin Czapla,Jack Simons Phys. Chem. Chem. Phys., 2018,20, 21739-21745
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Dongjia Han,Bing Xue,Juan Du,Tomohiro Miyatake,Hitoshi Tamiaki,Xin Xing,Wei Yuan,Yanyan Li Phys. Chem. Chem. Phys., 2016,18, 24252-24260
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Daniel Messmer,Stefan Salentinig,Jakob Heier Nanoscale, 2019,11, 6929-6938
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Recommended suppliers
Amadis Chemical Company Limited
(CAS:95408-45-0)1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride
Purity:99%/99%/99%
Quantity:10g/25g/100g
Price ($):230.0/548.0/2192.0
Tiancheng Chemical (Jiangsu) Co., Ltd
(CAS:95408-45-0)1,1-雙(二-叔丁基膦)二茂鐵二氯合鈀
Purity:99%
Quantity:25KG,200KG,1000KG
Price ($):Inquiry