Cas no 95-12-5 (Bicyclo2.2.1hept-5-en-2-ylmethanol)

Bicyclo2.2.1hept-5-en-2-ylmethanol structure
95-12-5 structure
Product Name:Bicyclo2.2.1hept-5-en-2-ylmethanol
CAS No:95-12-5
MF:C8H12O
MW:124.180282592773
MDL:MFCD00167571
CID:34777
PubChem ID:78946
Update Time:2024-10-25

Bicyclo2.2.1hept-5-en-2-ylmethanol Chemical and Physical Properties

Names and Identifiers

    • Bicyclo[2.2.1]hept-5-en-2-ylmethanol
    • 5-Norbornene-2-methanol,mixture of endo and exo
    • 2-Hydroxymethyl-5-norbornene
    • 5-Norborene-2-methanol
    • 5-norbornene-2-methanol(NMO)mixture of endo and exo
    • 5-Norbornen-2-methanol (mixture of isomers)
    • 5-Norbornene-2-methanol
    • 5-bicyclo[2.2.1]hept-2-enylmethanol
    • Bicyclo[2.2.1]hept-5-ene-2-methanol (mixture of isomers)
    • Bicyclo[2.2.1]hept-5-ene-2-methanol
    • Cyclol
    • 5-Hydroxymethyl-2-norbornene
    • 5-Norbornene 2-methanol
    • Bicyclo(2.2.1)hept-5-ene-2-methanol
    • 5-Hydroxymethylbicyclo(2.2.1)hept-2-ene
    • 2-(Hydroxymethyl)bicyclo(2.2.1)hept-5-ene
    • LUMNWCHHXDUKFI-UHFFFAOYSA-N
    • 5-Hydroxymethylbicyclo[2.2.1]hept-2-ene
    • 2-(Hydroxymethyl)bicyclo[2.2.1]hept-5-ene
    • norbornen-5-methanol
    • 5-norbornen-
    • 5-Norbornene-2-methanol (6CI, 7CI, 8CI)
    • 2-Norbornen-5-methanol
    • 5-(Hydroxymethyl)bicyclo[2.2.1]hept-2-ene
    • [Bicyclo[2.2.1]hept-5-en-2-yl]methanol
    • Norbornene-5-methyl alcohol
    • NSC 403110
    • DTXSID3038698
    • N43L8J2KTL
    • DB-003096
    • NS00040437
    • DS-18405
    • UNII-N43L8J2KTL
    • NSC-403110
    • AKOS009156947
    • J-802157
    • SY015570
    • 30421-42-2
    • STL563998
    • F1995-0286
    • AI3-08981
    • bicyclo-[2,2,1]-hept-5-en-2-yl-methyl alcohol
    • EN300-246230
    • Bicyclo[2.2.1]5-heptene-2-methanol
    • EINECS 202-392-0
    • (4s)-bicyclo[2.2.1]hept-5-en-2-ylmethanol
    • FD14041
    • 2-bicyclo[2.2.1]hept-5-enylmethanol
    • NSC403110
    • MFCD00167571
    • F16263
    • Exo-5-norbornene-2-methanol(exo)
    • SCHEMBL33077
    • N0979
    • 5-norbornen-2-methanol
    • 95-12-5
    • 5-Norbornene-2-yl methanol
    • {bicyclo[2.2.1]hept-5-en-2-yl}methanol
    • CS-0114684
    • 5-norbornen -2-methanol
    • 5-Norbornene-2-methanol, mixture of isomers
    • 5-hydroxy methyl-2-norbornene
    • Bicyclo2.2.1hept-5-en-2-ylmethanol
    • MDL： MFCD00167571
    • Inchi： 1S/C8H12O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-9H,3-5H2
    • InChI Key： LUMNWCHHXDUKFI-UHFFFAOYSA-N
    • SMILES： OCC1C2CC(C=C2)C1

Computed Properties

  • Exact Mass: 124.08900
  • Monoisotopic Mass: 124.089
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 1
  • Hydrogen Bond Acceptor Count: 1
  • Heavy Atom Count: 9
  • Rotatable Bond Count: 1
  • Complexity: 140
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 3
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Topological Polar Surface Area: 20.2
  • Surface Charge: 0
  • Tautomer Count: nothing
  • XLogP3: 1.2

Experimental Properties

  • Color/Form: Not determined
  • Density: 1.027?g/mL?at 25?°C(lit.)
  • Boiling Point: 97?°C/20?mmHg(lit.)
  • Flash Point: Fahrenheit: 188.6 ° f < br / > Celsius: 87 ° C < br / >
  • Refractive Index: n20/D 1.500(lit.)
  • PSA: 20.23000
  • LogP: 1.19090
  • Solubility: Not determined
  • Vapor Pressure: 0.2±0.8 mmHg at 25°C

Bicyclo2.2.1hept-5-en-2-ylmethanol Security Information

  • Symbol: GHS07
  • Prompt：warning
  • Signal Word：Warning
  • Hazard Statement： H302 + H312 + H332
  • Warning Statement： P280
  • WGK Germany：3
  • Hazard Category Code： 20/21/22
  • Safety Instruction： S36/37/39-S45
  • Hazardous Material Identification： Xn
  • Storage Condition：Sealed in dry,2-8°C
  • Risk Phrases：R20/21/22

Bicyclo2.2.1hept-5-en-2-ylmethanol Customs Data

  • HS CODE：2906199090
  • Customs Data：

    China Customs Code:

    2906199090

    Overview:

    2906199090. Other naphthenic alcohols,Cycloenol and cycloterpenol. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:5.5%. general tariff:30.0%

    Declaration elements:

    Product Name, component content, use to

    Summary:

    2906199090. cyclanic, cyclenic or cyclotherpenic alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Bicyclo2.2.1hept-5-en-2-ylmethanol Pricemore >>

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Bicyclo2.2.1hept-5-en-2-ylmethanol Production Method

Production Method 1

Reaction Conditions
1.1 Reagents: (±)-2-Butanol Catalysts: Zirconium dioxide
Reference
Preparation of unsaturated cyclic alcohols from aldehydes
, Japan, , ,

Production Method 2

Reaction Conditions
1.1 Catalysts: Iridium, aqua[[2,2′-bipyridine]-6,6′(1H,1′H)-dionato(2-)-κN1,κN1′][(1,2,3,4,5-η)… Solvents: Isopropanol ;  12 h, 120 °C
Reference
Method for preparation of unsaturated primary alcohols
, China, , ,

Production Method 3

Reaction Conditions
1.1 Reagents: Lithium aluminum hydride Solvents: Tetrahydrofuran ;  reflux
Reference
Mechanochemical ring-opening metathesis polymerization: development, scope, and mechano-exclusive polymer synthesis
Lee, Gue Seon; Lee, Hyo Won; Lee, Hyun Sub; Do, Taeyang; Do, Jean-Louis; et al, Chemical Science, 2022, 13(39), 11496-11505

Production Method 4

Reaction Conditions
1.1 Reagents: Lithium aluminum hydride
Reference
Bicontinuous Alkaline Fuel Cell Membranes from Strongly Self-Segregating Block Copolymers
Price, Samuel C.; Ren, Xiaoming; Jackson, Aaron C.; Ye, Yuesheng; Elabd, Yossef A.; et al, Macromolecules (Washington, 2013, 46(18), 7332-7340

Production Method 5

Reaction Conditions
1.1 Reagents: Lithium aluminum hydride Solvents: Dichloromethane ,  Tetrahydrofuran ;  2 min, 0 °C; 2 h, rt
Reference
LiAlH4-induced reductive dephosphonylation of α,α-dialkyl triethyl β-phosphonyl esters: mechanistic study and synthetic application
Zhu, Jia-Liang; Bau, Sheng Jr.; Shih, You-Cheng, Synlett, 2012, 23(6), 863-866

Production Method 6

Reaction Conditions
1.1 99 h, pH 4 - 5, 170 - 180 °C
Reference
Norbornene-containing mannich bases on the basis of aliphatic amines
Hajiyeva, G. E.; Mammadbayli, E. H.; Ibrahimli, S. I.; Jafarov, I. A., Azerbaidzhanskii Khimicheskii Zhurnal, 2018, (3), 50-56

Production Method 7

Reaction Conditions
1.1 2 h, 100 - 200 psi, 210 °C
Reference
High Tg sulfonated insertion polynorbornene ionomers prepared by catalytic insertion polymerization
Pierre, Florian; Commarieu, Basile; Tavares, Ana C.; Claverie, Jerome, Polymer, 2016, 86, 91-97

Production Method 8

Reaction Conditions
1.1 Reagents: Lithium aluminum hydride Solvents: Tetrahydrofuran ;  0 °C; 10 h, rt
1.2 Reagents: Hydrochloric acid Solvents: Water ;  pH 6, 0 °C
Reference
Ligand Design for Luminescent Lanthanide-Containing Metallopolymers
de Bettencourt-Dias, Ana; Rossini, Jeffrey S. K., Inorganic Chemistry, 2016, 55(20), 9954-9963

Production Method 9

Reaction Conditions
1.1 Reagents: Potassium carbonate ,  Carbon monoxide Catalysts: Tricarbonyl[(1,3,3a,7a-η)-4,5,6,7-tetrahydro-1,3-bis(trimethylsilyl)-2H-inden-2-… Solvents: Dimethyl sulfoxide ,  Water ;  20 h, 10 bar, 100 °C; 100 °C → rt
1.2 Reagents: Hydrochloric acid Solvents: Water ;  1 h, rt
Reference
Discrete iron complexes for the selective catalytic reduction of aromatic, aliphatic, and α,β-unsaturated aldehydes under water-gas shift conditions
Tlili, Anis; Schranck, Johannes; Neumann, Helfried; Beller, Matthias, Chemistry - A European Journal, 2012, 18(50), 15935-15939

Production Method 10

Reaction Conditions
1.1 Reagents: Sodium borohydride ;  20 min, 25 °C
1.2 Reagents: Water ;  rt
Reference
Sodium Tetraalkoxyborates: Intermediates for the Quantitative Reduction of Aldehydes and Ketones to Alcohols through Ball Milling with NaBH4
Naimi-Jamal, M. Reza; Mokhtari, Javad; Dekamin, Mohammad G.; Kaupp, Gerd, European Journal of Organic Chemistry, 2009, (21), 3567-3572

Production Method 11

Reaction Conditions
1.1 Catalysts: Iridium, aqua[[2,2′-bipyridine]-6,6′(1H,1′H)-dionato(2-)-κN1,κN1′][(1,2,3,4,5-η)… Solvents: Isopropanol ;  12 h, 120 °C; 120 °C → rt
Reference
Transfer Hydrogenation of Aldehydes and Ketones with Isopropanol under Neutral Conditions Catalyzed by a Metal-Ligand Bifunctional Catalyst [Cp*Ir(2,2'-bpyO)(H2O)]
Wang, Rongzhou; Tang, Yawen; Xu, Meng; Meng, Chong; Li, Feng, Journal of Organic Chemistry, 2018, 83(4), 2274-2281

Production Method 12

Reaction Conditions
1.1 Reagents: Lithium aluminum hydride Solvents: Tetrahydrofuran ;  overnight, rt
1.2 Solvents: Water ;  rt
Reference
Utilizing thiol-ene chemistry for crosslinked nickel cation-based anion exchange membranes
Kwasny, Michael T.; Zhu, Liang; Hickner, Michael A.; Tew, Gregory N., Journal of Polymer Science, 2018, 56(3), 328-339

Production Method 13

Reaction Conditions
1.1 Reagents: Sodium carbonate ,  Chlorosulfonyl isocyanate Solvents: Dichloromethane ;  rt; 20 h, reflux; reflux → 0 °C
1.2 Reagents: Sodium hydroxide Solvents: Methanol ;  1 h
1.3 Reagents: Hydrochloric acid Solvents: Water ;  neutralized
Reference
Deprotection of benzyl and p-methoxybenzyl ethers by chlorosulfonyl isocyanate-sodium hydroxide
Kim, Ji Duck; Han, Gyoonhee; Zee, Ok Pyo; Jung, Young Hoon, Tetrahedron Letters, 2003, 44(4), 733-735

Production Method 14

Reaction Conditions
1.1 Reagents: Hydroquinone ;  19 h, rt → 190 °C
Reference
Influence of Hydroxyl Group Concentration on Mechanical Properties and Impact Resistance of ROMP Copolymers
Dennis, Joseph M.; Long, Tyler R.; Krishnamurthy, Ajay ; Tran, Ngon T.; Patterson, Brendan A.; et al, ACS Applied Polymer Materials, 2020, 2(6), 2414-2425

Production Method 15

Reaction Conditions
1.1 9 h, 4 - 5 atm, 170 - 180 °C
Reference
Synthesis and properties of mannich bases on the basis of norbornenylmethanol, aliphatic amines and benzaldehyde
Hajiyeva, Gulsum E.; Mammadbayli, Eldar H.; Ibrahimli, Sahil I.; Abiyev, Huseyn A., Neft Kimyasi va Neft E'mali Proseslari, 2020, 21(1), 36-44

Production Method 16

Reaction Conditions
1.1 9 h, 4 - 5 atm, 170 - 180 °C
Reference
Synthesis of Mannich bases based on norbornenylmethanol, cyclic amines and benzaldehyde and their antimicrobial activity
Hajiyeva, G. E., Azerbaidzhanskii Khimicheskii Zhurnal, 2019, (3), 68-74

Production Method 17

Reaction Conditions
1.1 9 h, 4 - 5 atm, 170 - 180 °C
Reference
Norbornene containing Mannich bases on the basis of cyclic amines
Hajiyeva, Gulsum E.; Mammadbayli, Eldar H.; Ibrahimly, Sahil I.; Talybov, Gulahmad M., Neft Kimyasi va Neft E'mali Proseslari, 2017, 18(4), 331-340

Production Method 18

Reaction Conditions
1.1 9 h, 4 - 5 atm, 170 - 180 °C
Reference
Mannich Bases from Bicyclo[2.2.1]hept-5-en-2-ylmethanol, Secondary Amines and Formaldehyde
Mammadbayli, E. H.; Hajiyeva, G. E.; Ibrahimli, S. I.; Jafarova, N. A., Russian Journal of General Chemistry, 2018, 88(10), 2204-2208

Production Method 19

Reaction Conditions
1.1 Reagents: 1,4-Naphthalenedicarbonitrile Solvents: Acetonitrile ,  Water
Reference
Photoinduced single-electron-transfer (set)-initiated oxidative cleavage of benzylic ether protecting group: a mild and efficient procedure
Pandey, G.; Krishna, A., Synthetic Communications, 1988, 18(18), 2309-14

Production Method 20

Reaction Conditions
1.1 -78 °C; 2 h, -78 °C → rt; rt → 45 °C; 8 h, 45 °C
1.2 Reagents: Sodium hydroxide ,  Sodium borohydride Solvents: Methanol ,  Water ;  1 h, rt
Reference
Synthesis and Characterization of Lithium-Ion Conductive Membranes with Low Water Permeation
Stone, David A.; Welna, Daniel T.; Allcock, Harry R., Chemistry of Materials, 2007, 19(10), 2473-2482

Bicyclo2.2.1hept-5-en-2-ylmethanol Raw materials

Bicyclo2.2.1hept-5-en-2-ylmethanol Preparation Products

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Amadis Chemical Company Limited
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(CAS:95-12-5)Bicyclo2.2.1hept-5-en-2-ylmethanol
Order Number:A845189
Stock Status:in Stock
Quantity:500g/1kg
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 07:05
Price ($):151.0/302.0
Suzhou Senfeida Chemical Co., Ltd
Gold Member
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(CAS:95-12-5)5-Norbornene-2-methanol
Order Number:sfd10414
Stock Status:in Stock
Quantity:200KG
Purity:99%
Pricing Information Last Updated:Friday, 19 July 2024 14:35
Price ($):discuss personally
Tiancheng Chemical (Jiangsu) Co., Ltd
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(CAS:95-12-5)5-降冰片烯-2-甲醇
Order Number:LE20755364
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:48
Price ($):discuss personally

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Amadis Chemical Company Limited
(CAS:95-12-5)Bicyclo2.2.1hept-5-en-2-ylmethanol
A845189
Purity:99%/99%
Quantity:500g/1kg
Price ($):151.0/302.0
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Suzhou Senfeida Chemical Co., Ltd
(CAS:95-12-5)5-Norbornene-2-methanol
sfd10414
Purity:99%
Quantity:200KG
Price ($):Inquiry
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