- A method of producing ingenol-3-angelate from ingenol, World Intellectual Property Organization, , ,
Cas no 94487-74-8 (Angelic anhydride)
Angelic anhydride structure
Product Name:Angelic anhydride
CAS No:94487-74-8
MF:C10H14O3
MW:182.216363430023
MDL:MFCD00198080
CID:798619
PubChem ID:87562658
Update Time:2024-10-25
Angelic anhydride Chemical and Physical Properties
Names and Identifiers
-
- 2-Butenoic acid,2-methyl-, anhydride, (2Z,2'Z)-
- CIS-2-METHYLCROTONIC ANHYDRIDE
- CIS-2,3-DIMETHYLACRYLIC ANHYDRIDE
- Bis[(Z)-2-methyl-2-butenoic acid] anhydride
- Bis[(Z)-2-methyl-2-butenoic] anhydride
- (Z)-2-Methyl-2-butenoic Anhydride 2-Methylisocrotonic Anhydride
- Angelic anhydride
- (Z)-2-Methylbut-2-enoic anhydride
- (Z)-2-Methyl-2-butenoic Anhydride
- 2-Methylisocrotonic Anhydride
- (2Z,2'Z)-2-Methyl-2-butenoic acid anhydride
- Tiglic Anhydride
- 2-Methylcrotonic Anhydride
- (E)-2-methylbut-2-enoic anhydride
- TIGLICANHYDRIDE
- LIHLSLRANKCHLV-KQQUZDAGSA-N
- (E)-2-Methyl-2-butenoic Anhydride
- 2-Butenoic acid, 2-methyl-, anhydride, (Z,Z)- (9CI)
- Angelic anhydride (7CI)
- LIHLSLRANKCHLV-SFECMWDFSA-N
- AKOS024258413
- DB-253796
- s3806
- CS-0032513
- SCHEMBL15101930
- BS-44061
- [(Z)-2-methylbut-2-enoyl] (Z)-2-methylbut-2-enoate
- CCG-266454
- A1180
- 2-Butenoic acid, 2-methyl-, anhydride, (2Z,2'Z)-
- 2-Butenoic acid, 2-methyl-, anhydride, (Z,Z)-
- 94487-74-8
- MFCD00198080
- HUP8L9D9RF
- HY-N6086
-
- MDL： MFCD00198080
- Inchi： 1S/C10H14O3/c1-5-7(3)9(11)13-10(12)8(4)6-2/h5-6H,1-4H3/b7-5-,8-6-
- InChI Key： LIHLSLRANKCHLV-SFECMWDFSA-N
- SMILES： C(=O)(/C(/C)=C\C)OC(=O)/C(/C)=C\C
Computed Properties
- Exact Mass: 182.09400
- Monoisotopic Mass: 182.094294304 g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 3
- Heavy Atom Count: 13
- Rotatable Bond Count: 4
- Complexity: 244
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 2
- Topological Polar Surface Area: 43.4
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: 2.3
- Molecular Weight: 182.22
Experimental Properties
- Color/Form: Powder
- Density: 1.006±0.06 g/cm3 (20 oC 760 Torr),
- Melting Point: No data available
- Boiling Point: 108°C/13mmHg(lit.)
- Flash Point: 119.8±15.9 oC,
- Refractive Index: 1.4720-1.4750
- Solubility: Slightly soluble (1.2 g/l) (25 o C),
- PSA: 43.37000
- LogP: 1.98860
- Solubility: Not determined
Angelic anhydride Security Information
-
Symbol:
- Prompt：dangerous
- Signal Word：warning
- Hazard Statement： H290-H314
- Warning Statement： P234-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501
- Hazardous Material transportation number：3265
- Safety Instruction： H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
- HazardClass：8
- PackingGroup：III
- Storage Condition：0-10°C
Angelic anhydride Customs Data
- HS CODE：2916190090
- Customs Data：
China Customs Code:
2916190090Overview:
2916190090 Other unsaturated acyclic monocarboxylic acids(Including its anhydride\Acyl halide,Peroxides and peroxyacids and their derivatives).Regulatory conditions:AB(Customs clearance form for Inbound Goods,Customs clearance form for outbound goods).VAT:17.0%.Tax refund rate:9.0%.MFN tariff:6.5%.general tariff:30.0%
Declaration elements:
Product Name, component content, use to, Acrylic acid\Acrylates or esters shall be packaged clearly
Regulatory conditions:
A.Customs clearance form for Inbound Goods
B.Customs clearance form for outbound goodsInspection and quarantine category:
R.Sanitary supervision and inspection of imported food
S.Sanitary supervision and inspection of exported food
M.Import commodity inspection
N.Export commodity inspectionSummary:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives.supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward).VAT:17.0%.tax rebate rate:9.0%.MFN tariff:6.5%.general tariff:30.0%
Angelic anhydride Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| S e l l e c k ZHONG GUO | S3806-25mg |
Angelic anhydride |
94487-74-8 | 98% | 25mg |
￥1204.78 | 2023-09-15 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | A1180-5g |
Angelic anhydride |
94487-74-8 | 98.0%(T) | 5g |
￥3890.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | A1180-1g |
Angelic anhydride |
94487-74-8 | 98.0%(T) | 1g |
￥1290.0 | 2022-05-30 | |
| TRC | A637810-10mg |
Angelic Anhydride |
94487-74-8 | 10mg |
$ 207.00 | 2023-04-19 | ||
| TRC | A637810-100mg |
Angelic Anhydride |
94487-74-8 | 100mg |
$ 1642.00 | 2023-04-19 | ||
| Chengdu Biopurify Phytochemicals Ltd | BP1639-1000mg |
Angelic anhydride |
94487-74-8 | 98% | 1000mg |
$190 | 2023-09-20 | |
| Chengdu Biopurify Phytochemicals Ltd | BP1639-50mg |
Angelic anhydride |
94487-74-8 | 98% | 50mg |
$50 | 2023-09-20 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | A46930-20mg |
Angelic Anhydride |
94487-74-8 | ,HPLC≥97% | 20mg |
￥288.0 | 2023-09-08 | |
| WU HAN AN JIE KAI Biomedical Technology Co., Ltd. | ajce54930-1mg |
Angelic anhydride |
94487-74-8 | 98% | 1mg |
￥0.00 | 2023-09-07 | |
| WU HAN AN JIE KAI Biomedical Technology Co., Ltd. | ajce54930-5mg |
Angelic anhydride |
94487-74-8 | 98% | 5mg |
￥0.00 | 2023-09-07 |
Angelic anhydride Production Method
Production Method 1
Reaction Conditions
1.1 Solvents: Dichloromethane ; rt
1.2 Reagents: Dicyclohexylcarbodiimide Solvents: Xylene ; 1 h, rt
1.2 Reagents: Dicyclohexylcarbodiimide Solvents: Xylene ; 1 h, rt
Reference
Production Method 2
Reaction Conditions
1.1 Reagents: Dicyclohexylcarbodiimide Solvents: Dichloromethane , Xylene ; 1 h, rt
Reference
- Semisynthesis of ingenol 3-angelate (PEP005): efficient stereoconservative angeloylation of alcoholsLiang, Xifu; Grue-Soerensen, Gunnar; Petersen, Anders Klarskov; Hogberg, Thomas, Synlett, 2012, 23(18), 2647-2652
Angelic anhydride Raw materials
Angelic anhydride Preparation Products
Angelic anhydride Suppliers
Amadis Chemical Company Limited
Gold Member
Audited Supplier
(CAS:94487-74-8)Angelic anhydride
Order Number:A1205852
Stock Status:in Stock
Quantity:1g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 03:43
Price ($):399.0
Email:[email protected]
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
Audited Supplier
(CAS:94487-74-8)Angelic Anhydride, ≥ 98.0%
Order Number:LE12107
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:06
Price ($):discuss personally
Email:[email protected]
Angelic anhydride Related Literature
-
Partha Laskar,Christine Dufès Nanoscale Adv., 2021,3, 6007-6026
-
Long Deng,Qian Zou,Biao Liu,Wenhui Ye,Chengfei Zhuo,Li Chen,Ze-Yuan Deng,Ya-Wei Fan,Jing Li Food Funct., 2018,9, 4234-4245
-
Xinhuan Wang,Shuangfei Cai,Cui Qi Analyst, 2017,142, 2500-2506
-
4. Fatty acid eutectic mixtures and derivatives from non-edible animal fat as phase change materials?Pau Gallart-Sirvent,Marc Martín,Gemma Villorbina,Mercè Balcells,Aran Solé,Luisa F. Cabeza,Ramon Canela-Garayoa RSC Adv., 2017,7, 24133-24139
-
Gaurav J. Shah,Eric P.-Y. Chiou,Ming C. Wu,Chang-Jin “CJ” Kim Lab Chip, 2009,9, 1732-1739
94487-74-8 (Angelic anhydride) Related Products
- 14316-68-8(2-Butenoic acid,2-methyl-, 1,1'-anhydride, (2E,2'E)-)
- 61692-82-8(2-Butenoic acid,2-methyl-, 2-methyl-2-propen-1-yl ester, (2E)-)
- 61692-78-2(2-Butenoic acid,2-methyl-, 2-methyl-2-propen-1-yl ester, (2Z)-)
- 5837-78-5(Ethyl tiglate)
- 616-02-4(3-methyl-2,5-dihydrofuran-2,5-dione)
- 53082-57-8(2-Butenoic acid,2-methyl-, propyl ester, (2Z)-)
- 55514-48-2(2-Butenoic acid,2-methyl-, ethyl ester)
- 61692-83-9(Propyl tiglate)
- 766-39-2(2,3-Dimethylmaleic anhydride)
- 691-83-8(2-Butenedioic acid, 2-methyl-, diethyl ester, (2Z)-)
