Production Method 1

23235-61-2

94108-97-1

Reaction Conditions

1.1 Reagents: Sulfuric acid Catalysts: Lanthanum sesquioxide ,  Titania Solvents: Water ;  14 h, rt
1.2 Catalysts: 4-Methoxyphenol ;  2 h, rt

Reference

Preparation of polyol acrylates

, China, , ,

Production Method 2

94108-97-1

94108-97-1

Reaction Conditions

1.1 Catalysts: Triethylamine Solvents: Dichloromethane ;  rt

Reference

Synthesis and photopolymerization properties of self-initiated photopolymerized acrylate oligomers

Zhang, Yong; Shi, Wen-Fang, Gaodeng Xuexiao Huaxue Xuebao, 2012, 33(3), 635-639

Production Method 3

3121-61-7

23235-61-2

94108-97-1

115633-58-4

Reaction Conditions

1.1 Reagents: 4-Methoxyphenol Catalysts: Dabco ,  Zinc acetate ;  24 h, 250 - 760 mm Hg, 120 - 145 °C

Reference

Method for manufacturing polyalcohol (meth)acrylate esters

, World Intellectual Property Organization, , ,

Production Method 4

23235-61-2

94108-97-1

Reaction Conditions

1.1 Reagents: 4-Methoxyphenol ,  Phosphinic acid Catalysts: p-Toluenesulfonic acid Solvents: Toluene ,  Cyclohexane ;  rt → 95 °C; 9 - 10 h, 85 - 95 °C; 95 - 105 °C; 105 °C → 40 °C
1.2 Reagents: Sodium hydroxide Solvents: Water ;  30 min

Reference

Clean production method for bis(trimethylolpropane) tetraacrylate or pentaerythritol tetraacrylate

, China, , ,

Production Method 5

23235-61-2

94108-97-1

Reaction Conditions

1.1 Reagents: Hydroquinone ,  Oxygen Catalysts: Carbon ,  12-Tungstosilicic acid Solvents: Benzene ;  4 h, heated

Reference

Catalytic synthesis of ditrimethylol propane tetraacrylate (di-TMPTA) over H4SiW12O40/C

Jiang, Wei; Ding, Guo-rong; Cao, Jing; Li, Wei; Zhang, Ji-bo, Tanxingti, 2010, 20(5), 50-52

Production Method 6

23235-61-2

94108-97-1

Reaction Conditions

1.1 Reagents: Phenothiazine ,  Hydroquinone Catalysts: p-Toluenesulfonic acid Solvents: Toluene ;  rt → 116 °C; 4 h, 116 °C

Reference

Research on the synthesis of ditrimethylolpropane tetraacrylate (Di-TMPTA)

Song, Yan; Zhang, Chaoqun; Yang, Qingbiao; Wang, Hengguo; Li, Yaoxian; et al, Yingyong Huagong, 2008, 37(9), 1002-1005

Production Method 7

23235-61-2

94108-97-1

Reaction Conditions

1.1 Reagents: Phenothiazine Catalysts: p-Toluenesulfonic acid Solvents: Toluene ;  reflux; reflux → 25 °C
1.2 Reagents: Sodium hydroxide Solvents: Water ;  pH 8
1.3 Reagents: 2,6-Di-tert-butyl-4-methylphenol

Reference

Method for preparing bistrimethylolpropane tetraacrylate

, China, , ,

Production Method 8

23235-61-2

94108-97-1

Reaction Conditions

1.1 Reagents: Phosphinic acid Catalysts: Phenothiazine ,  p-Toluenesulfonic acid Solvents: Toluene ;  6 h, rt → 105 °C; 105 °C → rt
1.2 Reagents: Sodium carbonate ,  Sodium hydroxide Solvents: Hexane ,  Water ;  pH 7.6, rt
1.3 Solvents: Water ;  pH 7

Reference

Preparation of ditrimethylolpropane tetraacrylate

, China, , ,

Production Method 9

23235-61-2

94108-97-1

Reaction Conditions

Reference

Acrylate compounds

, Japan, , ,

Production Method 10

77-99-6

94108-97-1

37275-47-1

15625-89-5

Reaction Conditions

1.1 Reagents: 4-Methoxyphenol Catalysts: Cuprous chloride ,  Phosphonic acid ,  2-Acrylamido-2-methylpropanesulfonic acid Solvents: Toluene ,  Heptane ;  reflux

Reference

Curable material and continuous production method

, China, , ,

2-Propenoic acid,1,1'-[2-[[2,2-bis[[(1-oxo-2-propen-1-yl)oxy]methyl]butoxy]methyl]-2-ethyl-1,3-propanediyl]ester Raw materials

• 2-Propenoic acid,1,1'-[2-[[2,2-bis[[(1-oxo-2-propen-1-yl)oxy]methyl]butoxy]methyl]-2-ethyl-1,3-propanediyl]ester
• 2-Methoxyethyl Acrylate
• Ethyl-2-(hydroxymethyl)-1,3-propanediol
• Di(trimethylolpropane)

2-Propenoic acid,1,1'-[2-[[2,2-bis[[(1-oxo-2-propen-1-yl)oxy]methyl]butoxy]methyl]-2-ethyl-1,3-propanediyl]ester Preparation Products

• 2-Propenoic acid,1,1'-[2-ethyl-2-(hydroxymethyl)-1,3-propanediyl] ester (37275-47-1)
• 2-Propenoic acid,1,1'-[2-[[2,2-bis[[(1-oxo-2-propen-1-yl)oxy]methyl]butoxy]methyl]-2-ethyl-1,3-propanediyl]ester (94108-97-1)
• Trimethylolpropane Triacrylate, 85%, stabilized with MEHQ (15625-89-5)
• (115633-58-4)

• 1. Distinctive size effects of Pt nanoparticles immobilized on Fe3O4@PPy used as an efficient recyclable catalyst for benzylic alcohol aerobic oxidation and hydrogenation reduction of nitroaromatics
  Yu Long,Bing Yuan,Jianrui Niu,Xin Tong,Jiantai Ma New J. Chem., 2015,39, 1179-1185
• 2. Embedding cyclic nitrone in mesoporous silica particles for EPR spin trapping of superoxide and other radicals?
  Eric Besson,Stéphane Gastaldi,Emily Bloch,Selma Aslan,Hakim Karoui,Olivier Ouari,Micael Hardy Analyst, 2019,144, 4194-4203
• 3. Excimer and exciplex formation in a pair of bright phosphorescent isomers constructed from Cu3(pyrazolate)3 and Cu3I3 coordination luminophores?
  Shun-Ze Zhan,Mian Li,Xiao-Ping Zhou,Dan Li,Seik Weng Ng RSC Adv., 2011,1, 1457-1459
• 4. Fatty acid eutectic mixtures and derivatives from non-edible animal fat as phase change materials?
  Pau Gallart-Sirvent,Marc Martín,Gemma Villorbina,Mercè Balcells,Aran Solé,Luisa F. Cabeza,Ramon Canela-Garayoa RSC Adv., 2017,7, 24133-24139
• 5. Fe3O4 nanoparticle chains with N-doped carbon coating: magnetotactic bacteria assisted synthesis and high-rate lithium storage?
  Dan Yang,Yanping Zhou,Xianhong Rui,Jixin Zhu,Ziyang Lu,Eileen Fong,Qingyu Yan RSC Adv., 2013,3, 14960-14962

• Solvents and Organic Chemicals Organic Compounds Organic acids and derivatives Carboxylic acids and derivatives Tetracarboxylic acids and derivatives

• 824950-12-1(2-Propenoic acid, 2-[2-[2-[(3-ethyl-3-oxetanyl)methoxy]ethoxy]ethoxy]ethyl ester)
• 37275-47-1(2-Propenoic acid,1,1'-[2-ethyl-2-(hydroxymethyl)-1,3-propanediyl] ester)
• 302911-84-8(2-Propenoic acid,[2-ethyl-2-[(2-methoxyethoxy)methyl]-1,3-propanediyl]bis(oxy-2,1-ethanediyl)ester (9CI))
• 15625-89-5(Trimethylolpropane Triacrylate, 85%, stabilized with MEHQ)
• 824950-13-2(2-Propenoic acid, 19-(3-ethyl-3-oxetanyl)-3,6,9,12,15,18-hexaoxanonadec-1-yl ester)
• 53879-54-2(Trimethylolpropane propoxylate triacrylate)
• 28961-43-5(trimethylolpropane ethoxylate (1 eo/oh) triacryla)
• 75577-70-7(2-Propenoic acid,1,1'-[[2-ethyl-2-[[2-[(1-oxo-2-propen-1-yl)oxy]ethoxy]methyl]-1,3-propanediyl]bis(oxy-2,1-ethanediyl)]ester)
• 7024-08-0(2-Propenoic acid,2,2-bis(hydroxymethyl)butyl ester)
• 13141-04-3(2-Propenoic acid,2,2-dimethylhexyl ester)