- Synthesis of vanitropeLi, Hong; Li, Yingchun, Henan Huagong, 2005, 22(3), 18-19
Cas no 94-86-0 (2-Ethoxy-5-(1-propenyl)phenol)
2-Ethoxy-5-(1-propenyl)phenol is a phenolic compound featuring an ethoxy substituent and a propenyl group on the aromatic ring. This structure imparts unique reactivity and functional properties, making it valuable in organic synthesis and specialty chemical applications. Its phenolic moiety allows for participation in electrophilic substitution reactions, while the propenyl group offers potential for further functionalization, such as hydrogenation or oxidation. The ethoxy group enhances solubility in organic solvents, facilitating its use in synthetic processes. This compound is of interest in pharmaceutical intermediates, fragrance development, and polymer chemistry due to its versatile chemical behavior and structural adaptability.
2-Ethoxy-5-(1-propenyl)phenol structure
Product Name:2-Ethoxy-5-(1-propenyl)phenol
CAS No:94-86-0
MF:C11H14O2
MW:178.227663516998
MDL:MFCD00009283
CID:34767
PubChem ID:24853639
Update Time:2025-05-27
2-Ethoxy-5-(1-propenyl)phenol Chemical and Physical Properties
Names and Identifiers
-
- trans-2-ethoxy-5-(1-propenyl)phenol
- 2-Ethoxy-5-prop-1-enylphenol
- 5-propenylguaethol
- Vanitrope
- PROPENYL GUAETHOL
- 2-Ethoxy-5-(1-propenyl)phenol
- 1-Ethoxy-2-hydroxy-4-(1-propenyl)benzene
- 2-Ethoxy-5-propenylphenol
- Propenylguaethol
- PHENOL, 2-ETHOXY-5-(1-PROPENYL)-
- m-Anol, 6-ethoxy-
- Phenol, 2-ethoxy-5-(1-propen-1-yl)-
- 3-Propenyl-6-ethoxyphenol
- 2-ethoxy-5-[(E)-prop-1-enyl]phenol
- (E)-2-Ethoxy-5-(prop-1-en-1-yl)phenol
- DSSTox_CID_27716
- DSSTox_GSID_47727
- KSC490Q3L
- Tox21_303945
- TRA0108295
- DB-0
- 2-Ethoxy-5-(1-propen-1-yl)phenol (ACI)
- m-Anol, 6-ethoxy- (6CI)
- Phenol, 2-ethoxy-5-(1-propenyl)- (9CI)
- Phenol, 2-ethoxy-5-propenyl- (7CI, 8CI)
- 1-Ethoxy-2-hydroxy-4-propenylbenzene
- 6-Ethoxy-m-anol
- Hydroxy methyl anethol
- Isosafroeugenol
- NSC 5194
- Propenylguaetol
- CAS-94-86-0
- D77808
- Propenylguaethol [FHFI]
- FEMA 2922
- Propenyl guaethol [II]
- DTXSID7047726
- Isosafroeugenole
- 1-Ethoxy-2-hydroxy-4-propenybenzene
- JP95W81L3F
- DTXCID4032401
- Hydroxymethyl anethole
- InChI=1/C11H14O2/c1-3-5-9-6-7-11(13-4-2)10(12)8-9/h3,5-8,12H,4H2,1-2H3/b5-3
- W-100180
- 2-ethoxy-5-(prop-1-en-1-yl)phenol
- AS-9932
- (E)-2-ethoxy-5-(prop-1-enyl)phenol
- CHEBI:173836
- 2-ethoxy-5-[(1E)-prop-1-en-1-yl]phenol
- E0804
- NSC5194
- NCGC00256742-01
- DTXCID1027716
- MFCD00009283
- NSC-5194
- STL195347
- FEMA No. 2922
- trans
- CAS-63477-41-8
- CCG-357198
- 6-ethoxy-
- Phenol, 2-ethoxy-5-propenyl-
- trans-2-Ethoxy-5-(1-propenyl)phenol, 97%
- -2-Ethoxy-5-(1-propenyl)phenol
- 2-ethoxy-5-[(E)-prop-1-enyl]-phenol
- NCGC00357273-01
- 2-Ethoxy-5-propenyl-phenol
- 63477-41-8
- UNII-JP95W81L3F
- m-Anol
- DTXSID2047727
- 2-Ethoxy-5-(1-propenyl)phenol, 9CI
- Propenylguaethole
- Propenyl guaethol, >=99%, FCC, FG
- Tox21_302539
- WLN: 2U1R CQ DO2
- Propenylguaethol [FCC]
- BBL018765
- 94-86-0
- VANIBON
- 2-Ethoxy-5-[(1E)-1-propenyl]phenol
- CS-W017326
- AKOS015838841
-
- MDL： MFCD00009283
- Inchi： 1S/C11H14O2/c1-3-5-9-6-7-11(13-4-2)10(12)8-9/h3,5-8,12H,4H2,1-2H3
- InChI Key： RADIRXJQODWKGQ-UHFFFAOYSA-N
- SMILES： OC1C(OCC)=CC=C(C=CC)C=1
- BRN： 2259898
Computed Properties
- Exact Mass: 178.09900
- Monoisotopic Mass: 178.09938
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 1
- Hydrogen Bond Acceptor Count: 2
- Heavy Atom Count: 13
- Rotatable Bond Count: 3
- Complexity: 166
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 1
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 29.5
- Surface Charge: 0
- Tautomer Count: 3
- XLogP3: 2.9
Experimental Properties
- Color/Form: Scaly white crystals or powders. It has a strong aroma like vanillin.
- Density: 1.0196 (rough estimate)
- Melting Point: 84.0 to 88.0 deg-C
- Boiling Point: 116°C/2mmHg(lit.)
- Flash Point: 165.2 °C
- Refractive Index: 1.5670 (estimate)
- PSA: 29.46000
- LogP: 2.82400
- FEMA: 2922 | PROPENYLGUAETHOL
- Solubility: It is easily soluble in most vegetable oils, edible solvents and essential oils, but very difficult to dissolve in water.
2-Ethoxy-5-(1-propenyl)phenol Security Information
-
Symbol:
- Prompt：warning
- Signal Word：Warning
- Hazard Statement： H315,H319,H335
- Warning Statement： P261,P305+P351+P338
- Hazardous Material transportation number：NONH for all modes of transport
- WGK Germany：2
- Hazard Category Code： 36/37/38
- Safety Instruction： S26-S37/39
- RTECS：SL3850000
-
Hazardous Material Identification：
- Risk Phrases：R36/37/38
2-Ethoxy-5-(1-propenyl)phenol Customs Data
- HS CODE：2909500000
- Customs Data：
China Customs Code:
2909500000Overview:
2909500000. Ether phenol\Ether alcohol phenol and its halogenation\sulfonation\Nitrosative or nitrosative derivatives. VAT:17.0%. Tax refund rate:9.0%. Regulatory conditions:nothing. MFN tariff:5.5%. general tariff:30.0%
Declaration elements:
Product Name, component content, use to
Summary:
2909500000 ether-phenols, ether-alcohol-phenols and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
2-Ethoxy-5-(1-propenyl)phenol Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| XI GE MA AO DE LI QI （ SHANG HAI ） MAO YI Co., Ltd. | 227544-50G |
2-Ethoxy-5-(1-propenyl)phenol |
94-86-0 | 50g |
￥1552.85 | 2023-12-09 | ||
| SHANG HAI MAI KE LIN SHENG HUA Technology Co., Ltd. | E808649-100g |
trans-2-Ethoxy-5-(1-propenyl)phenol |
94-86-0 | 98% | 100g |
665.00 | 2021-05-17 | |
| XI GE MA AO DE LI QI （ SHANG HAI ） MAO YI Co., Ltd. | W292206-SAMPLE-K |
2-Ethoxy-5-(1-propenyl)phenol |
94-86-0 | ≥99%, FCC, FG | 587.6 | 2021-05-17 | ||
| XI GE MA AO DE LI QI （ SHANG HAI ） MAO YI Co., Ltd. | W292206-100G-K |
2-Ethoxy-5-(1-propenyl)phenol |
94-86-0 | ≥99%, FCC, FG | 100G |
1146.59 | 2021-05-17 | |
| XI GE MA AO DE LI QI （ SHANG HAI ） MAO YI Co., Ltd. | W292206-1KG-K |
2-Ethoxy-5-(1-propenyl)phenol |
94-86-0 | ≥99%, FCC, FG | 1KG |
4161.68 | 2021-05-17 | |
| XI GE MA AO DE LI QI （ SHANG HAI ） MAO YI Co., Ltd. | W292206-5KG-K |
2-Ethoxy-5-(1-propenyl)phenol |
94-86-0 | ≥99%, FCC, FG | 5KG |
17191.98 | 2021-05-17 | |
| TI XI AI ( SHANG HAI ) HUA CHENG GONG YE FA ZHAN Co., Ltd. | E0804-100G |
2-Ethoxy-5-(1-propenyl)phenol |
94-86-0 | >98.0%(GC) | 100g |
￥1295.00 | 2023-09-08 | |
| SHANG HAI YI EN HUA XUE JI SHU Co., Ltd. | R016630-100g |
2-Ethoxy-5-(1-propenyl)phenol |
94-86-0 | 98% | 100g |
￥638 | 2024-07-19 | |
| SHANG HAI YI EN HUA XUE JI SHU Co., Ltd. | R016630-25g |
2-Ethoxy-5-(1-propenyl)phenol |
94-86-0 | 98% | 25g |
￥227 | 2024-07-19 | |
| SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd. | T51570-5g |
2-Ethoxy-5-propenylphenol |
94-86-0 | 98% | 5g |
￥58.0 | 2023-09-06 |
2-Ethoxy-5-(1-propenyl)phenol Production Method
Production Method 1
Production Method 2
Reaction Conditions
1.1 Reagents: Alumina , Potassium fluoride Solvents: Ethylene glycol
Reference
- Potassium fluoride on alumina - a new reagent for selective O-demethylation of aryl alkyl ethersRadhakrishna, A. S.; Rao, K. R. K. Prasad; Suri, S. K.; Sivaprakash, K.; Singh, B. B., Synthetic Communications, 1991, 21(3), 379-83
Production Method 3
Reaction Conditions
Reference
- A review on the synthesis of vanitropeYe, Jianfeng, Xiangliao Xiangjing Huazhuangpin, 2003, (4), 24-26
Production Method 4
Reaction Conditions
Reference
- Selective dealkylation of alkyl aryl ethers in heterogeneous basic media under microwave irradiationOussaid, Abdelouahad; Thach, Le Ngoc; Loupy, Andre, Tetrahedron Letters, 1997, 38(14), 2451-2454
Production Method 5
Reaction Conditions
Reference
- 4-Ethoxy-3-hydroxy-1-(1-propenyl)benzene (Vanitrope), Hungary, , ,
Production Method 6
2-Ethoxy-5-(1-propenyl)phenol Raw materials
2-Ethoxy-5-(1-propenyl)phenol Preparation Products
2-Ethoxy-5-(1-propenyl)phenol Suppliers
Amadis Chemical Company Limited
Gold Member
Audited Supplier
(CAS:94-86-0)2-Ethoxy-5-(1-propenyl)phenol
Order Number:A845117
Stock Status:in Stock
Quantity:500g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 07:05
Price ($):304.0
Email:[email protected]
Tiancheng Chemical (Jiangsu) Co., Ltd
Gold Member
Audited Supplier
(CAS:94-86-0)濃馥香蘭素
Order Number:LE1934789
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:37
Price ($):discuss personally
Email:[email protected]
2-Ethoxy-5-(1-propenyl)phenol Related Literature
-
Xing Zhao,Lu Bai,Rui-Ying Bao,Zheng-Ying Liu,Ming-Bo Yang,Wei Yang RSC Adv., 2017,7, 46297-46305
-
Max Attwood,Hiroki Akutsu,Lee Martin,Toby J. Blundell,Pierre Le Maguere,Scott S. Turner Dalton Trans., 2021,50, 11843-11851
-
J. Matthew Kurley,Phillip W. Halstenberg,Abbey McAlister,Stephen Raiman,Richard T. Mayes RSC Adv., 2019,9, 25602-25608
-
Matthew J. Gaunt,Jinquan Yu,Jonathan B. Spencer Chem. Commun., 2001, 1844-1845
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