Production Method 1

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Methyl phenyl sulfoxide ,  Dimethyldioxirane Solvents: Acetone ,  Chloroform

Reference

Dioxirane epoxidation of alkenes

Adam, Waldemar; Saha-Moeller, Chantu R.; Zhao, Cong-Gui, Organic Reactions (Hoboken, 2002, 61,

Production Method 2

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Oxygen Catalysts: 2739695-52-2 ;  4.5 h, 1 atm, rt

Reference

Photocatalytic Activity of Ruthenium(II) Complex with 1,10-Phenanthroline-3,8-dicarboxylic Acid in Aerobic Oxidation Reactions

Zenkov, I. S.; Yakushev, A. A.; Abel, A. S.; Averin, A. D.; Bessmertnykh-Lemeune, A. G.; et al, Russian Journal of Organic Chemistry, 2021, 57(9), 1398-1404

Production Method 3

123-09-1

934-73-6

Reaction Conditions

1.1 Catalysts: 2685787-09-9 Solvents: Methanol ;  10 h, 25 °C

Reference

Incorporating Photochromic Triphenylamine into a Zirconium-Organic Framework for Highly Effective Photocatalytic Aerobic Oxidation of Sulfides

Zou, Xin-Nan; Zhang, Deshan; Luan, Tian-Xiang; Li, Qiang ; Li, Lei; et al, ACS Applied Materials & Interfaces, 2021, 13(17), 20137-20144

Production Method 4

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Oxygen Catalysts: [4-[2-[10-[2-(4-Carboxyphenyl)ethynyl]-9-anthracenyl]ethynyl]benzoato(2-)-κO,κO′… Solvents: Methanol ,  Chloroform ;  3 h, rt

Reference

Selective photooxidation of sulfides mediated by singlet oxygen using visible-light-responsive coordination polymers

Liang, Xiao; Guo, Zhifen; Wei, Hongxia; Liu, Xin; Lv, Hui; et al, Chemical Communications (Cambridge, 2018, 54(92), 13002-13005

Production Method 5

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Catalysts: Vanadium, [[2,2′-[(2,2-dimethyl-1,3-propanediyl)bis[(nitrilo-κN)methylidyne]]bis… Solvents: Ethanol ;  10 min, 25 °C

Reference

Ni(II) and V(IV) Schiff base complexes derived from 2,2'-dimethylpropandiamine: the crystal structure, electrochemical properties and catalytic activities in oxidation of sulfides

Rayati, Saeed; Khodaei, Elham; Jafarian, Majid; Bahrami, Arezo; Wojtczak, Andrzej; et al, Journal of Coordination Chemistry, 2017, 70(8), 1424-1437

Production Method 6

123-09-1

934-73-6

Reaction Conditions

1.1 Catalysts: Molybdovanadophosphoric acid (H5PMo10V2O40) Solvents: Acetic acid ;  1 h, 70 °C; cooled

Reference

Electron Transfer-Oxygen Transfer Oxygenation of Sulfides Catalyzed by the H5PV2Mo10O40 Polyoxometalate

Khenkin, Alexander M.; Leitus, Gregory; Neumann, Ronny, Journal of the American Chemical Society, 2010, 132(33), 11446-11448

Production Method 7

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Oxygen Catalysts: 12-Hexyl-6-hydroxy-5H-dibenzo[b,h]fluorene-5,11,13-trione Solvents: 1,1,1,3,3,3-Hexafluoro-2-propanol ;  2 min, rt; 60 min, rt

Reference

KuQuinone as a Highly Stable and Reusable Organic Photocatalyst in Selective Oxidation of Thioethers to Sulfoxides

Forchetta, Mattia ; Sabuzi, Federica; Stella, Lorenzo ; Conte, Valeria; Galloni, Pierluca, Journal of Organic Chemistry, 2022, 87(21), 14016-14025

Production Method 8

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: 2,3-Benzodioxin-1,4-dione Solvents: Dichloromethane ;  8 h, 25 °C

Reference

Metal- and additive-free oxygen-atom transfer reaction: an efficient and chemoselective oxidation of sulfides to sulfoxides with cyclic diacyl peroxides

Gan, Shaoyan; Yin, Junjie; Yao, Yuan; Liu, Yang; Chang, Denghu; et al, Organic & Biomolecular Chemistry, 2017, 15(12), 2647-2654

Production Method 9

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Catalysts: Niobium (complexes with O2 and chitosan, sodium salts) ,  Chitosan Solvents: Water ;  3 h, rt

Reference

Organic-solvent-free oxidation of styrene, phenol and sulfides with H2O2 over eco-friendly niobium and tantalum based heterogeneous catalysts

Talukdar, Hiya; Saikia, Gangutri; Das, Arpita; Sultana, Sazida Y.; Islam, Nashreen S., Journal of Industrial and Engineering Chemistry (Amsterdam, 2023, 121, 249-263

Production Method 10

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Iodobenzene diacetate ,  Water Catalysts: Chromium(1+), [[rel-2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne… Solvents: Methanol ;  60 min, 23 °C

Reference

Visible light generation of chromium(V)-oxo salen complexes and mechanistic insights into catalytic sulfide oxidation

Klaine, Seth; Fung Lee, Ngo; Dames, Angeline; Zhang, Rui, Inorganica Chimica Acta, 2020, 509,

Production Method 11

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Catalysts: Copper, [[4,4′-[(1-methyl-1,2-ethanediyl)bis[(nitrilo-κN)ethylidyne]]bis[1,3-ben… Solvents: Ethanol ;  20 min, 25 °C

Reference

Catalytic activity and electrochemical properties of Cu(II)-Schiff base complex encapsulated in the nanocavities of zeolite-Y for oxidation of olefins and sulfides

Rayati, Saeed; Khodaei, Elham; Jafarian, Majid, Journal of Coordination Chemistry, 2017, 70(15), 2736-2750

Production Method 12

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Acetic anhydride ,  Carbamide peroxide Catalysts: Imidazole ,  Iron oxide (Fe3O4) ,  Silica ,  2102606-38-0 Solvents: Ethanol ;  5 min, rt

Reference

Mn-Schiff base complex supported on magnetic nanoparticles: Synthesis, crystal structure, electrochemical properties and catalytic activities for oxidation of olefins and sulfides

Rayati, Saeed; Khodaei, Elham; Jafarian, Majid; Wojtczak, Andrzej, Polyhedron, 2017, 133, 327-335

Production Method 13

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Iodobenzene diacetate Catalysts: (SP-5-31)-Carbonyl[5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-21H,23H-porphinato… Solvents: Chloroform-d ;  100 h, 25 °C

Reference

Visible light-promoted selective oxidation of sulfides to sulfoxides catalyzed by ruthenium porphyrins with iodobenzene diacetate

Chen, Tse-Hong; Yuan, Zhibo; Carver, Aaron; Zhang, Rui, Applied Catalysis, 2014, 478, 275-282

Production Method 14

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: 2-Iodyl-3-propoxypyridine Solvents: Acetonitrile ;  rt
1.2 rt → reflux; 2.5 h, reflux; reflux → rt
1.3 Reagents: Sodium thiosulfate Solvents: Water ;  rt

Reference

Preparation, X-ray Structure, and Reactivity of 2-Iodylpyridines: Recyclable Hypervalent Iodine(V) Reagents

Yoshimura, Akira; Banek, Christopher T.; Yusubov, Mekhman S.; Nemykin, Victor N.; Zhdankin, Viktor V., Journal of Organic Chemistry, 2011, 76(10), 3812-3819

Production Method 15

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Acetic acid ;  0 °C
1.2 Reagents: (-)-Methyl phenyl sulfoxide Solvents: Water ;  overnight, rt; rt → 0 °C
1.3 Reagents: Sodium hydroxide Solvents: Water ;  basified

Reference

Access to N-cyanosulfoximines by transition metal-free iminations of sulfoxides

Dannenberg, C. A.; Fritze, L.; Krauskopf, F.; Bolm, C., Organic & Biomolecular Chemistry, 2017, 15(5), 1086-1090

Production Method 16

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Iodobenzene diacetate Catalysts: 1989691-31-7 Solvents: Methanol ,  Methanol-d4 ,  Water ;  3 h, 23 °C
1.2 Reagents: Sodium hydroxide Solvents: Water

Reference

Highly efficient and chemoselective oxidation of sulfides catalyzed by iron(III) corroles with iodobenzene diacetate

Chen, Tse-Hong; Kwong, Ka Wai; Lee, Ngo Fung; Ranburger, Davis; Zhang, Rui, Inorganica Chimica Acta, 2016, 451, 65-72

Production Method 17

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Hydrochloric acid ,  Oxygen Catalysts: Rose Bengal Solvents: Ethanol ;  18 h, rt

Reference

A simple metal-free catalytic sulfoxidation under visible light and air

Gu, Xiangyong; Li, Xiang; Chai, Yahong; Yang, Qi; Li, Pixu; et al, Green Chemistry, 2013, 15(2), 357-361

Production Method 18

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Catalysts: 1-Butanaminium, N,N,N-tributyl-, stereoisomer of dioxobis[μ-(peroxy-κO1:κO1,κO2)… Solvents: Acetonitrile ,  Water ;  120 min, 293 K

Reference

Highly efficient oxidation of sulfides with hydrogen peroxide catalyzed by [SeO4{WO(O2)2}2]2-

Kamata, Keigo; Hirano, Tomohisa; Mizuno, Noritaka, Chemical Communications (Cambridge, 2009, (26), 3958-3960

Production Method 19

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Solvents: Water ;  15 min, rt

Reference

Selective oxidation of sulfides with H2O2 catalyzed by silica-tungstate core-shell nanoparticles

Sreedhar, B.; Radhika, P.; Neelima, B.; Hebalkar, Neha; Mishra, A. K., Catalysis Communications, 2008, 10(1), 39-44

Production Method 20

123-09-1

934-73-6

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Catalysts: 2962812-46-8 Solvents: Methanol ;  30 min, 50 °C

Reference

Two 3D Two-Fold Interpenetrated Dia-Like Polyoxometalate-Based Metal-Organic Frameworks: Synthesis and Sulfide Selective Oxidation Activity

Bai, Xue; Han, Xu; Wang, Yuxin; Zhang, Ange; Yang, Yanli; et al, Inorganic Chemistry, 2023, 62(33), 13221-13229

1-Chloro-4-(methylsulfinyl)benzene Raw materials

• 4-Chlorothioanisole

1-Chloro-4-(methylsulfinyl)benzene Preparation Products

• 1-Chloro-4-(methylsulfinyl)benzene (934-73-6)

• 1. Excellent energy storage performance in NaNbO3-based relaxor antiferroeic ceramics under a low electric field
  XuxinCheng,XiaomingChen,PengyuanFan
• 2. Establishing new scaling relations on two-dimensional MXenes for CO2 electroreduction?
  Albertus D. Handoko,Khoong Hong Khoo,Teck Leong Tan,Hongmei Jin,Zhi Wei Seh J. Mater. Chem. A, 2018,6, 21885-21890
• 3. Empowering microfluidics by micro-3D printing and solution-based mineral coating?
  Hongxia Li,Aikifa Raza,Qiaoyu Ge,Jin-You Lu,TieJun Zhang Soft Matter, 2020,16, 6841-6849
• 4. Fate of nitrogen-15 in the subsequent growing season of greenhouse tomato plants (Lycopersicon esculentum Mill) as influenced by alternate partial root-zone irrigation
  Maomao Hou,Fenglin Zhong,Qiu Jin,Enjiang Liu,Jie Feng,Tengyun Wang,Yue Gao RSC Adv., 2017,7, 34392-34400
• 5. Evolution in surface coverage of CH3NH3PbI3?XClXvia heat assisted solvent vapour treatment and their effects on photovoltaic performance of devices
  Dhirendra K. Chaudhary,Pramendra Kumar,Lokendra Kumar RSC Adv., 2016,6, 94731-94738

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Phenyl sulfoxides

• 80-00-2(4-Chlorophenyl phenyl sulfone)
• 7321-57-5(Benzene, 1-chloro-2-(methylsulfinyl)-)
• 112456-62-9(Benzene, 1-chloro-4-[(S)-methylsulfinyl]-)
• 38452-22-1(3,5-dichlorophenyl methyl sulfoxide)
• 1016-82-6(Benzene,1-chloro-4-(phenylsulfinyl)-)
• 98-57-7(4-Chlorophenyl methyl sulfone)
• 3085-42-5(4-Chlorophenyl sulfoxide)
• 80-07-9(4,4'-Dichlorodiphenyl sulfone)
• 61645-25-8(Magnesium, chloro[[(4-chlorophenyl)sulfonyl]methyl]-)
• 30605-10-8(Benzene, 1,1-sulfonylbis4-chloro-, homopolymer)