- In Situ Generation of Carboxylate: An Efficient Strategy for a One-Pot Synthesis of Homo- and Heterometallic Polynuclear ComplexesGavrilenko, Konstantin S.; Punin, Sergey V.; Cador, Olivier; Golhen, Stephane; Ouahab, Lahcene; et al, Journal of the American Chemical Society, 2005, 127(35), 12246-12253
Cas no 932-69-4 (Cobalt(II) benzoate tetrahydrate)
Cobalt(II) benzoate tetrahydrate (Co(C?H?O?)?·4H?O) is a coordination compound consisting of cobalt(II) ions complexed with benzoate ligands and four water molecules. This purple to pink crystalline solid is sparingly soluble in water and organic solvents. It serves as a precursor in catalysis, particularly for oxidation reactions, and finds applications in materials science for synthesizing cobalt-based complexes or nanomaterials. The tetrahydrate form ensures stability and controlled reactivity in synthetic processes. Its defined stoichiometry and purity make it suitable for research and industrial use, where precise cobalt incorporation is required. Handling should follow standard safety protocols for cobalt compounds.
932-69-4 structure
Product Name:Cobalt(II) benzoate tetrahydrate
CAS No:932-69-4
MF:C7H6CoO2
MW:181.054543018341
MDL:MFCD00050769
CID:83223
PubChem ID:164760
Update Time:2025-05-27
Cobalt(II) benzoate tetrahydrate Chemical and Physical Properties
Names and Identifiers
-
- Cobalt(II) benzoate tetrahydrate
- cobalt(2+),dibenzoate
- Cobalt(II) benzoate
- Benzoic acid, cobalt(2+) salt (8CI, 9CI)
- Cobalt benzoate (Co(BzO)2) (7CI)
- Bis(benzoato)cobalt
- Cobalt benzoate
- Cobalt dibenzoate
- Cobalt(2+) benzoate
- EINECS 213-257-0
- Q28411463
- SCHEMBL114426
- Benzoic acid, cobalt(2+) salt
- GAYAMOAYBXKUII-UHFFFAOYSA-L
- AKOS015839084
- COBALT (II) BENZOATE
- Benzoic acid, cobalt(2+) salt (2:1)
- cobalt(2+);dibenzoate
- DTXSID30890532
- NS00079974
- 932-69-4
- G79970
-
- MDL: MFCD00050769
- Inchi: 1S/C7H6O2.Co/c8-7(9)6-4-2-1-3-5-6;/h1-5H,(H,8,9);
- InChI Key: GPXJPCNTGZFWPM-UHFFFAOYSA-N
- SMILES: [Co].O=C(C1C=CC=CC=1)O
Computed Properties
- Exact Mass: 300.99100
- Monoisotopic Mass: 300.991
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 4
- Heavy Atom Count: 19
- Rotatable Bond Count: 2
- Complexity: 98
- Covalently-Bonded Unit Count: 3
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: nothing
- XLogP3: nothing
- Topological Polar Surface Area: 80.3A^2
Experimental Properties
- Color/Form: Not determined
- Melting Point: 115°C
- Boiling Point: 249.3 °C at 760 mmHg
- Flash Point: 111.4 °C
- Water Partition Coefficient: Insoluble in water.
- PSA: 52.60000
- LogP: 2.61540
- Sensitiveness: Hygroscopic
- Solubility: Not determined
Cobalt(II) benzoate tetrahydrate Security Information
- Hazard Category Code: 20/21/22-36/37/38
- Safety Instruction: S26; S36/37/39
- Risk Phrases:R20/21/22
- TSCA:Yes
Cobalt(II) benzoate tetrahydrate Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| A FA AI SHA , SAI MO FEI SHI ER KE JI QI XIA GONG SI | 87380-10g |
Cobalt(II) benzoate |
932-69-4 | 10g |
¥518.00 | 2023-04-13 | ||
| A FA AI SHA , SAI MO FEI SHI ER KE JI QI XIA GONG SI | 87380-50g |
Cobalt(II) benzoate |
932-69-4 | 50g |
¥2593.00 | 2023-04-13 | ||
| A FA AI SHA , SAI MO FEI SHI ER KE JI QI XIA GONG SI | 87380-250g |
Cobalt(II) benzoate |
932-69-4 | 250g |
¥7440.00 | 2023-04-13 | ||
| abcr | AB205023-10 g |
Cobalt(II) benzoate |
932-69-4 | 10g |
€58.80 | 2022-06-02 | ||
| abcr | AB205023-50 g |
Cobalt(II) benzoate |
932-69-4 | 50g |
€136.40 | 2022-06-02 | ||
| abcr | AB205023-10g |
Cobalt(II) benzoate; . |
932-69-4 | 10g |
€70.30 | 2025-04-15 | ||
| abcr | AB205023-50g |
Cobalt(II) benzoate; . |
932-69-4 | 50g |
€149.40 | 2025-04-15 | ||
| Cooke Chemical | F247521-10g |
Cobalt(II) benzoate |
932-69-4 | Null | 10g |
RMB 424.00 | 2025-02-21 | |
| Cooke Chemical | F247521-50g |
Cobalt(II) benzoate |
932-69-4 | Null | 50g |
RMB 2228.00 | 2025-02-21 | |
| Cooke Chemical | F247521-250g |
Cobalt(II) benzoate |
932-69-4 | Null | 250g |
RMB 10595.20 | 2025-02-21 |
Cobalt(II) benzoate tetrahydrate Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Cobalt dinitrate ; heated; cooled
1.2 Solvents: Toluene ; rt
1.2 Solvents: Toluene ; rt
Reference
Production Method 2
Reaction Conditions
1.1 Reagents: Cobalt chloride (CoCl2) Solvents: Water ; 2 h, rt
Reference
- Thermo-electrochemical generation capabilities of octahedral spin crossover complexes of Mn(II), Fe(II) and Co(II) with N-donor ligands and benzoate counter ionHasnan, M. M. I. Megat; Abdullah, N.; Said, S. M.; Salleh, M. F. Mohd.; Hussin, S. A. Mat; et al, Electrochimica Acta, 2018, 261, 330-339
Production Method 3
Reaction Conditions
Reference
- Cobaltous arenemonocarboxylate methanol solvates, Japan, , ,
Production Method 4
Reaction Conditions
1.1 Reagents: Zinc oxide (ZnO) Solvents: Carbon dioxide ; 6 h, 100 bar, 60 °C
Reference
- Solvent free synthesis of organometallic catalysts for the copolymerisation of carbon dioxide and propylene oxideZhong, Xia; Dehghani, Fariba, Applied Catalysis, 2010, 98(3-4), 101-111
Production Method 5
Reaction Conditions
1.1 Reagents: Cobalt chloride (CoCl2)
Reference
- Coordination Compounds of Cobalt(II), Nickel(II), and Zinc(II) Valerates and Benzoates with PhenylacethydrazideKoksharova, T. V.; Mandzii, T. V.; Stoyanova, I. V., Russian Journal of General Chemistry, 2018, 88(10), 2114-2118
Production Method 6
Reaction Conditions
1.1 Reagents: Cobalt chloride (CoCl2)
Reference
- Coordination compounds of cobalt(II), nickel(II), and zinc(II) valerates and benzoates with benzohydrazideKoksharova, T. V.; Mandzii, T. V.; Stoyanova, I. V.; Polishchuk, A. A., Russian Journal of General Chemistry, 2016, 86(10), 2361-2366
Production Method 7
Reaction Conditions
1.1 Reagents: Cobalt carbonate (CoCO3) Solvents: Water ; 12 h, 90 °C
Reference
- Synthesis of cobalt benzoate by rheological phase reaction and its thermal decomposition mechanismSong, Li; He, Yibo; Yuan, Lianjie; Sun, Jutang; Zhang, Keli, Huaxue Shijie, 2006, 47(4), 204-207
Production Method 8
Cobalt(II) benzoate tetrahydrate Raw materials
Cobalt(II) benzoate tetrahydrate Preparation Products
Cobalt(II) benzoate tetrahydrate Suppliers
Amadis Chemical Company Limited
Gold Member
(CAS:932-69-4)Cobalt(II) benzoate tetrahydrate
Order Number:A1211722
Stock Status:in Stock
Quantity:10g
Purity:99%
Pricing Information Last Updated:Monday, 2 September 2024 15:59
Price ($):169.0
Email:[email protected]
Cobalt(II) benzoate tetrahydrate Related Literature
-
A. B. F. da Silva,K. Capelle Phys. Chem. Chem. Phys., 2009,11, 4564-4569
-
Amandine Altmayer-Henzien,Valérie Declerck,David J. Aitken,Ewen Lescop,Denis Merlet,Jonathan Farjon Org. Biomol. Chem., 2013,11, 7611-7615
-
Bin Han,Yasuo Shimizu,Gabriele Seguini,Celia Castro,Gérard Ben Assayag,Koji Inoue,Yasuyoshi Nagai,Sylvie Schamm-Chardon,Michele Perego RSC Adv., 2016,6, 3617-3622
-
Shun-Ze Zhan,Mian Li,Xiao-Ping Zhou,Dan Li,Seik Weng Ng RSC Adv., 2011,1, 1457-1459
-
Saeideh Mirfakhraei,Malak Hekmati,Fereshteh Hosseini Eshbala,Hojat Veisi New J. Chem., 2018,42, 1757-1761
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Recommended suppliers
Amadis Chemical Company Limited
(CAS:932-69-4)Cobalt(II) benzoate tetrahydrate
Purity:99%
Quantity:10g
Price ($):169.0