Production Method 1

4412-96-8

930-27-8

Reaction Conditions

1.1 Catalysts: Copper Solvents: Quinoline ;  250 °C

Reference

Quinoline

Sherman, Angela R.; Caron, Antoine; Collins, Shawn K., e-EROS Encyclopedia of Reagents for Organic Synthesis, 2015, 1, 1-4

Production Method 2

153681-93-7

930-27-8

Reaction Conditions

1.1 Catalysts: Trifluoroacetic acid

Reference

Synthesis and ene reactions of 3-methylene-2,3-dihydrofuran

Miles, William H.; Berreth, Christina L.; Smiley, Patricia M., Tetrahedron Letters, 1993, 34(33), 5221-2

Production Method 3

61842-14-6

930-27-8

Reaction Conditions

Reference

A convenient synthesis of furans

Camus, Francis; Hasiak, Bruno; Martin, Marius; Couturier, Daniel, Synthetic Communications, 1982, 12(8), 647-50

Production Method 4

4090-48-6

930-27-8

Reaction Conditions

1.1 Reagents: Sulfuric acid ,  Mercuric sulfate

Reference

Synthesis of furans from acetylenic epoxides and diols

Miller, David, Journal of the Chemical Society [Section] C: Organic, 1969, (1), 12-15

Production Method 5

82698-68-8

930-27-8

Reaction Conditions

Reference

Photochemistry of 3,6-dihydro-1,2-oxazines: a versatile route to substituted pyrroles

Givens, R. S.; Choo, D. J.; Merchant, S. N.; Stitt, R. P.; Matuszewski, B., Tetrahedron Letters, 1982, 23(13), 1327-30

Production Method 6

955998-81-9

930-27-8

Reaction Conditions

Reference

Product class 9: furans

Koenig, B., Science of Synthesis, 2002, 9, 183-285

Production Method 7

534-22-5

930-27-8

Reaction Conditions

Reference

Photoisomerization of 2-alkylfurans to 3-alkylfurans

Hiraoka, H.; Srinivasan, R., Journal of the American Chemical Society, 1968, 90(10), 2720-1

Production Method 8

930-27-8

Reaction Conditions

Reference

Carbohydrate pyrolysis mechanisms from isotopic labeling

Paine, John B. III; Pithawalla, Yezdi B.; Naworal, John D., Journal of Analytical and Applied Pyrolysis, 2008, 83(1), 37-63

Production Method 9

4412-96-8

930-27-8

Reaction Conditions

1.1 Reagents: Copper Solvents: Quinoline

Reference

3-Methyl-2-furoic acid and 3-methylfuran

Burness, D. M., Organic Syntheses, 1959, 39, 46-8

Production Method 10

4412-91-3

930-27-8

Reaction Conditions

1.1 Catalysts: p-Toluenesulfonic acid ,  Titania ,  Palladium, bis(acetonitrile)dichloro- (supported on TiO2) Solvents: Methanol ;  18 h

Reference

Process for the preparation of organic compounds via reduction of allylic compounds

, Japan, , ,

Production Method 11

930-27-8

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Catalysts: Molybdenum, [[2,2′-[1,2-ethanediylbis[(nitrilo-κN)methylidyne]]bis[phenolato-κO]… Solvents: Benzene ;  6 h, 40 °C

Reference

Process for preparation of 3-methylfuran

, China, , ,

Production Method 12

498-60-2

930-27-8

Reaction Conditions

Reference

Orientation in the furan nucleus. VI. β-Substituted furans

Gilman, Henry; Burtner, Robert R., Journal of the American Chemical Society, 1933, 55, 2903-9

Production Method 13

4412-96-8

930-27-8

Reaction Conditions

1.1 Reagents: Quinoline Catalysts: Copper ;  2.5 h, 165 - 180 °C

Reference

[4+3] Cycloaddition of C-3 substituted furans. Stereoselectivity induced by coordination effects

Montana, Angel M.; Grima, Pedro M.; Castellvi, Maria; Batalla, Consuelo; Font-Bardia, Merce, Tetrahedron, 2012, 68(48), 9982-9998

Production Method 14

57535-94-1

930-27-8

Reaction Conditions

1.1 Reagents: Sulfuric acid

Reference

Short synthesis of 3-methylfuran

Cornforth, J. W., Journal of the Chemical Society, 1958, 1310,

Production Method 15

22037-28-1

930-27-8

Reaction Conditions

1.1 rt

Reference

Preparation of 3-aminomethyltetrahydrofuran with furan as raw material

, China, , ,

Production Method 16

13423-15-9

930-27-8

Reaction Conditions

1.1 Reagents: Ethanol ,  Hydrogen Catalysts: Alumina ;  1250 h, 1 MPa, 450 °C

Reference

Method for producing aromatic hydrocarbon via aromatization

, China, , ,

Production Method 17

4412-96-8

930-27-8

Reaction Conditions

1.1 Catalysts: Quinoline ,  Copper ;  250 °C

Reference

Quinoline

Sherman, Angela R., e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001, ,

Production Method 18

930-27-8

Reaction Conditions

1.1 Reagents: Ethyl nitrite ,  Nitric oxide

Reference

Formation of 3-methylfuran from the gas-phase reaction of OH radicals with isoprene and the rate constant for its reaction with the OH radical

Atkinson, Roger; Aschmann, Sara M.; Tuazon, Ernesto C.; Arey, Janet; Zielinska, Barbara, International Journal of Chemical Kinetics, 1989, 21(7), 593-604

Production Method 19

35392-66-6

930-27-8

Reaction Conditions

1.1 Reagents: Chlorine

Reference

Products at the reaction of amino acids in aqueous solution with chlorine

Ishikawa, Seiichi; Fujino, Hiroshi; Yasuda, Kazuhiko; Shigemori, Nobuyasu, Suishitsu Odaku Kenkyu (1978-1991), 1986, 9(12), 786-92

Production Method 20

930-27-8

Reaction Conditions

Reference

Preparation of 3-methylfuran

, Japan, , ,

3-Methylfuran Raw materials

• 3-Furaldehyde
• 2-Methylfuran
• 3-Bromofuran
• 3-Methyltetrahydrofuran
• 2-ethynyl-2-methyloxirane
• Oxirane, 2-(2,2-diethoxyethyl)-2-methyl-
• Benzoic acid, 4-(3,6-dihydro-5-methyl-2H-1,2-oxazin-2-yl)-, methyl ester
• 2,5-Dihydro-3-methyl-2-furanol
• 3-Methyl-2-furoic Acid
• (E)-2-methyl but-2-ene-1,4-diol
• 5-methoxy-2-methylpyridin-1-ium-1-olate
• 3-Furanmethanol
• Furan, 2,3-dihydro-3-methylene-

3-Methylfuran Preparation Products

• 3-Methylfuran (930-27-8)

• 1. Quantification of selected volatile organic compounds in human urine by gas chromatography selective reagent ionization time of flight mass spectrometry (GC-SRI-TOF-MS) coupled with head-space solid-phase microextraction (HS-SPME)
  Pawe? Mochalski,Karl Unterkofler Analyst 2016 141 4796
• 2. Photochemical transformations. Part VI. The photorearrangement of 2-nitrofuran and 2-nitropyrrole
  R. Hunt,S. T. Reid J. Chem. Soc. Perkin Trans. 1 1972 2527
• 3. Joint impact of atmospheric SO2 and NH3 on the formation of nanoparticles from photo-oxidation of a typical biomass burning compound
  Xiaotong Jiang,Chen Lv,Bo You,Zhiyi Liu,Xinfeng Wang,Lin Du Environ. Sci.: Nano 2020 7 2532
• 4. 506. Furans. Part II. Friedel–Crafts acylation of furan, 2-methylfuran, and 3-methylfuran
  P. A. Finan,G. A. Fothergill J. Chem. Soc. 1963 2723
• 5. 506. Furans. Part II. Friedel–Crafts acylation of furan, 2-methylfuran, and 3-methylfuran
  P. A. Finan,G. A. Fothergill J. Chem. Soc. 1963 2723

• Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Heteroaromatic compounds Heteroaromatic compounds
• Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Heteroaromatic compounds

• 498-60-2(3-Furaldehyde)
• 19059-83-7(Pyrylium, 3-methyl-)
• 63762-41-4(Lithium, (4-methyl-2-furanyl)-)
• 20843-07-6(3,4-Dimethylfuran)
• 105855-05-8(3-Methylfuran-d3)
• 67363-95-5(3-ethylfuran)
• 51061-85-9(3-ethynyl-furan)
• 52556-92-0(Lithium 3-methylfuran-2-ide)
• 140463-91-8(Lithium, (3,4-dimethyl-2-furanyl)-)
• 67364-02-7(Furan,3-ethenyl-)