- Deoxofluorination of (Hetero)aromatic AcidsTrofymchuk, Serhii; Bugera, Maksym Ya.; Klipkov, Anton A.; Razhyk, Bohdan; Semenov, Sergey; et al, Journal of Organic Chemistry, 2020, 85(5), 3110-3124
Cas no 929000-62-4 (1-Bromo-2-methyl-4-(trifluoromethyl)benzene)
929000-62-4 structure
Product Name:1-Bromo-2-methyl-4-(trifluoromethyl)benzene
CAS No:929000-62-4
MF:C8H6BrF3
MW:239.032452106476
MDL:MFCD09258773
CID:857668
PubChem ID:22754141
Update Time:2024-10-26
1-Bromo-2-methyl-4-(trifluoromethyl)benzene Chemical and Physical Properties
Names and Identifiers
-
- 1-Bromo-2-methyl-4-(trifluoromethyl)benzene
- 1-Bromo-2-methyl-4-trifluoromethylbenzene
- 4-Bromo-3-methylbenzotrifluoride
- 1-Bromo-2-methyl-4-(trifluoromethyl)benzene (ACI)
- 1-Bromo-2-methyl-4-(trifluoromethyl)benzene, 4-Bromo-alpha,alpha,alpha-trifluoro-m-xylene
- MFCD09258773
- SY064687
- AKOS005255454
- 1-bromo-2-methyl-4-trifluoromethyl-benzene
- DA-00708
- CS-0153204
- 2-Methyl-4-(trifluoromethyl)bromobenzene
- AB49766
- DTXSID50628096
- FS-4398
- 929000-62-4
- EN300-141127
- 2-Bromo-5-(trifluoromethyl)toluene
- Z1269167994
- 2-bromo-5-trifluoromethyltoluene
- SCHEMBL624000
-
- MDL： MFCD09258773
- Inchi： 1S/C8H6BrF3/c1-5-4-6(8(10,11)12)2-3-7(5)9/h2-4H,1H3
- InChI Key： NXHNLJDFFBZSKJ-UHFFFAOYSA-N
- SMILES： FC(C1C=C(C)C(Br)=CC=1)(F)F
Computed Properties
- Exact Mass: 237.96000
- Monoisotopic Mass: 237.96050g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 12
- Rotatable Bond Count: 1
- Complexity: 155
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- XLogP3: 3.9
- Topological Polar Surface Area: 0?2
Experimental Properties
- PSA: 0.00000
- LogP: 3.77630
1-Bromo-2-methyl-4-(trifluoromethyl)benzene Security Information
-
Hazardous Material Identification：
- HazardClass：IRRITANT
1-Bromo-2-methyl-4-(trifluoromethyl)benzene Customs Data
- HS CODE：2903999090
- Customs Data：
China Customs Code:
2903999090Overview:
2903999090 Other aromatic halogenated derivatives. VAT:17.0% Tax refund rate:9.0% Regulatory conditions:nothing MFN tariff:5.5% general tariff:30.0%
Declaration elements:
Product Name, component content, use to
Summary:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
1-Bromo-2-methyl-4-(trifluoromethyl)benzene Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| Fluorochem | 045016-1g |
4-Bromo-3-methylbenzotrifluoride |
929000-62-4 | 97% | 1g |
￡14.00 | 2022-02-28 | |
| Fluorochem | 045016-5g |
4-Bromo-3-methylbenzotrifluoride |
929000-62-4 | 97% | 5g |
￡49.00 | 2022-02-28 | |
| Fluorochem | 045016-25g |
4-Bromo-3-methylbenzotrifluoride |
929000-62-4 | 97% | 25g |
￡181.00 | 2022-02-28 | |
| TRC | B697868-100mg |
1-Bromo-2-methyl-4-trifluoromethylbenzene |
929000-62-4 | 100mg |
$ 64.00 | 2023-04-18 | ||
| TRC | B697868-250mg |
1-Bromo-2-methyl-4-trifluoromethylbenzene |
929000-62-4 | 250mg |
$ 75.00 | 2023-04-18 | ||
| TRC | B697868-500mg |
1-Bromo-2-methyl-4-trifluoromethylbenzene |
929000-62-4 | 500mg |
$ 87.00 | 2023-04-18 | ||
| TRC | B697868-1g |
1-Bromo-2-methyl-4-trifluoromethylbenzene |
929000-62-4 | 1g |
$ 80.00 | 2022-06-06 | ||
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-OH004-5g |
1-Bromo-2-methyl-4-(trifluoromethyl)benzene |
929000-62-4 | 97% | 5g |
603.0CNY | 2021-08-04 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-OH004-1g |
1-Bromo-2-methyl-4-(trifluoromethyl)benzene |
929000-62-4 | 97% | 1g |
169.0CNY | 2021-08-04 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B10076-1g |
1-Bromo-2-methyl-4-(trifluoromethyl)benzene |
929000-62-4 | 98% | 1g |
346.0CNY | 2021-08-04 |
1-Bromo-2-methyl-4-(trifluoromethyl)benzene Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Hydrofluoric acid , Sulfur tetrafluoride ; -196 °C → rt; 24 h, 85 °C; 85 °C → rt
1.2 Reagents: Sodium bicarbonate Solvents: Water ; 0 °C
1.2 Reagents: Sodium bicarbonate Solvents: Water ; 0 °C
Reference
Production Method 2
Reaction Conditions
1.1 Reagents: Hydrofluoric acid, homopolymer, compd. with pyridine , (T-4)-[4-(1,1-Dimethylethyl)-2,6-dimethylphenyl]trifluorosulfur ; 24 h, 70 °C; 70 °C → rt
1.2 Reagents: Ethanol ; 30 min, rt
1.2 Reagents: Ethanol ; 30 min, rt
Reference
- Deoxyfluorination of acyl fluorides to trifluoromethyl compounds by FLUOLEAD/Olah's reagent under solvent-free conditionsLiang, Yumeng ; Taya, Akihito; Zhao, Zhengyu; Saito, Norimichi; Shibata, Norio, Beilstein Journal of Organic Chemistry, 2020, 16, 3052-3058
1-Bromo-2-methyl-4-(trifluoromethyl)benzene Raw materials
1-Bromo-2-methyl-4-(trifluoromethyl)benzene Preparation Products
1-Bromo-2-methyl-4-(trifluoromethyl)benzene Related Literature
-
Sowmyalakshmi Venkataraman RSC Adv., 2015,5, 73807-73813
-
Nan Fu,Naphaporn Chiewchan,Xiao Dong Chen Food Funct., 2020,11, 211-220
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Dhirendra K. Chaudhary,Pramendra Kumar,Lokendra Kumar RSC Adv., 2016,6, 94731-94738
-
Bo Wei,Zhenyu Liu,Chen Xie,Shu Yang,Wentao Tang,Aiwei Gu,Wing-Tak Wong,Ka-Leung Wong J. Mater. Chem. C, 2015,3, 12322-12327
-
5. Excimer emission and magnetoluminescence of radical-based zinc(ii) complexes doped in host crystals?Shojiro Kimura,Tetsuro Kusamoto Chem. Commun., 2020,56, 11195-11198
929000-62-4 (1-Bromo-2-methyl-4-(trifluoromethyl)benzene) Related Products
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