Production Method 1

928048-21-9

928048-12-8

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Diethyl ether ;  15 min, -78 °C
1.2 Reagents: Triethyl borate ;  30 min, -78 °C → -50 °C
1.3 Reagents: Hydrochloric acid Solvents: Water ;  rt

Reference

A tautomeric equilibrium between functionalized 2-formylphenylboronic acids and corresponding 1,3-dihydro-1,3-dihydroxybenzo[c][2,1]oxaboroles

Lulinski, Sergiusz; Madura, Izabela; Serwatowski, Janusz; Szatylowicz, Halina; Zachara, Janusz, New Journal of Chemistry, 2007, 31(1), 144-154

Production Method 2

937377-92-9

928048-12-8

Reaction Conditions

1.1 Reagents: Chloro(1-methylethyl)magnesium Solvents: Tetrahydrofuran ;  -5 - 0 °C; 1 h, -5 - 0 °C
1.2 Reagents: Trimethyl borate ;  -10 - -5 °C; 1 h, -10 - -5 °C
1.3 Reagents: Hydrochloric acid Solvents: Water ;  pH 4 - 5, 5 - 25 °C; 1 h, rt

Reference

Method for synthesizing 2-bromo-6-hydroxybenzaldehyde

, China, , ,

(3-Bromo-2-formylphenyl)boronic acid Raw materials

• Benzene, 1,3-dibromo-2-(dimethoxymethyl)-
• 1,3-Dioxane, 2-(2,6-dibromophenyl)-

(3-Bromo-2-formylphenyl)boronic acid Preparation Products

• (3-Bromo-2-formylphenyl)boronic acid (928048-12-8)

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• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzoyl derivatives

• 1451393-33-1(4-Bromo-3-formylphenylboronic acid)
• 1259318-83-6((3-Bromo-2,5-dimethylphenyl)boronic acid)
• 849062-19-7(3-Bromo-2,4,6-trimethylphenylboronic acid)
• 2170041-79-7(4-Bromo-2-formylphenylboronic acid)
• 854662-84-3(5-Brom-2,4-dimethylphenylboronic acid)
• 130870-00-7(4-Bromo-2,5-dimethylphenylboronic acid)
• 1184298-27-8((3-bromo-2-methyl-phenyl)boronic acid)
• 1032231-32-5(3-Bromo-2-cyanophenylboronic Acid)
• 774608-13-8(5-Bromo-2-methylphenylboronic acid)
• 2239323-55-6((3-Bromo-4-formylphenyl)boronic acid)