Production Method 1

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: 4-Methoxyphenol Catalysts: Triethylamine Solvents: Trichloroethylene ;  pH 9.5, 50 °C; 4 h, 50 °C; 50 °C → 15 °C

Reference

Preparation of n-hydroxymethylacrylamide with trichloroethylene as solvent

, China, , ,

Production Method 2

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: Polyformaldehyde Catalysts: Sodium methoxide Solvents: Acetone ;  rt → 45 °C; pH 9 - 9.3, 42 - 45 °C
1.2 1 h, pH 8.5, 42 - 45 °C
1.3 Reagents: Phthalic acid ;  pH 7 - 8; 21 - 23 °C

Reference

Method for preparing n-hydroxymethyl acrylamide crystal

, China, , ,

Production Method 3

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: 4-Methoxyphenol Catalysts: Tetramethylammonium hydroxide Solvents: Water ;  60 °C; 3 h, 60 °C
1.2 Reagents: Sulfuric acid Solvents: Water ;  pH 7.5 - 8.0

Reference

Method for synthesizing and crystallizing high-purity N-hydroxymethyl acrylamide

, China, , ,

Production Method 4

79-06-1

924-42-5

Reaction Conditions

1.1 Solvents: Water ;  1 - 1.5 h, pH 7 - 9, 35 - 40 °C

Reference

Copolymerization of acrylic acid with acrylamide biuret derivatives

Sirekanyan, I. N.; Kalantaryan, A. V.; Akopyan, G. V.; Eripyan, M. L., Russian Journal of Applied Chemistry, 2014, 87(10), 1570-1574

Production Method 5

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: Citric acid ,  Hydroxyquinone Solvents: Water ;  rt → 90 °C; 3 h, 90 °C

Reference

Study of the Composition and Physicochemical Properties of a Modifying Additive to a Lignosulfonate Drilling Reagent

Badikova, A. D.; Kulyashova, I. N.; Mustafin, A. G.; Safina, A. R.; R. Kireeva, D.; et al, Chemistry and Technology of Fuels and Oils, 2023, 59(2), 249-254

Production Method 6

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: Sodium hydroxide Solvents: Water ;  2 h, pH 11.0, 45 °C
1.2 Reagents: Sulfuric acid ;  pH 3.6
1.3 Reagents: 4-Methoxyphenol Catalysts: Copper sulfate ;  45 °C → 25 °C

Reference

Preparation of functional monomer etherified N-methylolacrylamide

, China, , ,

Production Method 7

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: 4-Methoxyphenol Catalysts: Tetramethylammonium hydroxide Solvents: Water ;  60 °C; 3 h, 60 °C
1.2 Reagents: Sulfuric acid Solvents: Water ;  pH 7.5 - 8

Reference

Preparation of N-methylol acrylamide

, China, , ,

Production Method 8

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: Sodium hydroxide ;  3 h, pH 8, 45 °C

Reference

Method for preparation of textile finishing agents

, China, , ,

Production Method 9

79-06-1

924-42-5

Reaction Conditions

1.1 heated

Reference

Process for preparation of chelating group-containing monomer

, China, , ,

Production Method 10

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: Sodium hydroxide Solvents: Water ;  2 h, pH 8 - 9, 23 - 25 °C
1.2 Reagents: Formic acid ;  pH 5 - 6

Reference

Effect of different crosslinkers on properties of melamine formaldehyde-furfuryl alcohol copolymer/montmorillonite impregnated softwood (Ficus hispida)

Hazarika, Ankita; Maji, Tarun K., Polymer Engineering & Science, 2013, 53(7), 1394-1404

Production Method 11

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: 4-Methoxyphenol Catalysts: Triethylamine ;  rt → 45 °C; 2 h, pH 9.5, 45 °C
1.2 Reagents: Sulfuric acid Solvents: Water ;  pH 7

Reference

Research on synthesis of N-hydroxymethyl acrylamide

Chen, Weihong; Li, Daguang; Li, Shuquan, Guangdong Huagong, 2005, 32(10), 40-41

Production Method 12

79-06-1

924-42-5

Reaction Conditions

1.1 Catalysts: Sodium hydroxide ,  Molybdenum sodium oxide Solvents: Water

Reference

Method for producing N-methylacrylamide

, European Patent Organization, , ,

Production Method 13

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: Triphenyl phosphate Catalysts: Sodium hydroxide ,  Molybdenum sodium oxide Solvents: Water ;  50 °C → 65 °C; 3 h, 65 - 70 °C

Reference

Green preparation of N-methylolacrylamide powder and water product

, China, , ,

Production Method 14

79-06-1

924-42-5

Reaction Conditions

1.1 Solvents: Diethyl ether ;  4 - 5 h, 60 - 70 °C

Reference

High-strength double-wall corrugated pipe and preparation method thereof

, China, , ,

Production Method 15

9012-76-4

924-42-5

924-42-5

Reaction Conditions

1.1 Reagents: 4-Methoxyphenol ,  Ammonium chloride Solvents: Water ;  10 min, 130 °C

Reference

Preparation of novel chitosan derivatives and applications in functional finishing of textiles

Pan, Hong; Zhao, Tao; Xu, Lihui; Shen, Yong; Wang, Liming; et al, International Journal of Biological Macromolecules, 2020, 153, 971-976

Production Method 16

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: Sodium hydroxide Catalysts: 4-Methoxyphenol Solvents: Water ;  pH 8

Reference

New design of an inkjet printing press using curable water-based primers, coatings and inks

, World Intellectual Property Organization, , ,

Production Method 17

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: Oxalic acid ,  Hydrochloric acid ,  Urea-formaldehyde resin ,  Sodium chloride sulfate thiosulfate Solvents: Water ;  0.25 - 0.3 MPa; 0.7 - 1.6 h, 15 - 30 °C

Reference

Composition for polymer sorbent and method for producing sorbent from composition

, Russian Federation, , ,

Production Method 18

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: Sodium hydroxide Solvents: Water ;  pH 8.0 - 9.0, 23 - 25 °C; 2 h, 23 - 25 °C
1.2 Reagents: Formic acid ;  2 h, pH 5.0 - 6.0, 23 - 25 °C

Reference

Studies on Effects of Different Cross-Linkers on the Properties of Starch-Based Wood Composites

Baishya, Prasanta; Maji, Tarun K., ACS Sustainable Chemistry & Engineering, 2014, 2(7), 1760-1768

Production Method 19

79-06-1

924-42-5

Reaction Conditions

1.1 Reagents: 4-Methoxyphenol Solvents: Water ;  40 - 45 °C; 45 °C → 25 °C
1.2 Reagents: Sodium hydroxide Solvents: Water ;  15 - 25 °C; 2 h, pH 9.5 - 10, 15 - 25 °C

Reference

Method for preparation of N-hydroxymethylacrylamide

, China, , ,

Production Method 20

79-06-1

924-42-5

Reaction Conditions

1.1 Catalysts: Ethanolamine ;  4 - 6 h, pH 9.4 - 9.6, 50 °C
1.2 Reagents: Sulfuric acid Solvents: Water ;  neutralized, < 15 °C

Reference

Method for preparing N-hydroxymethyl acrylamide using Number 200 mineral solvent

, China, , ,

N-(Hydroxymethyl)acrylamide Raw materials

• Acrylamide
• Chitosan
• N-(Hydroxymethyl)acrylamide

N-(Hydroxymethyl)acrylamide Preparation Products

• N-(Hydroxymethyl)acrylamide (924-42-5)

• 1. Fe/S-Catalyzed synthesis of 2-benzoylbenzoxazoles and 2-quinolylbenzoxazoles via redox condensation of o-nitrophenols with acetophenones and methylquinolines?
  Thi Thu Tram Nguyen,Thanh Binh Nguyen Org. Biomol. Chem., 2021,19, 6015-6020
• 2. Dissociative dynamics of O2 on Ag(110)?
  Ivor Lon?ari? Phys. Chem. Chem. Phys., 2015,17, 9436-9445
• 3. Enantio- & chemo-selective preparation of enantiomerically enriched aliphatic nitro alcohols using Candida parapsilosis ATCC 7330
  Sowmyalakshmi Venkataraman RSC Adv., 2015,5, 73807-73813
• 4. Emergence of microfluidic wearable technologies
  Joo Chuan Yeo,Kenry Lab Chip, 2016,16, 4082-4090
• 5. Fatty acid positional distribution in colostrum and mature milk of women living in Inner Mongolia, North Jiangsu and Guangxi of China?
  Long Deng,Qian Zou,Biao Liu,Wenhui Ye,Chengfei Zhuo,Li Chen,Ze-Yuan Deng,Ya-Wei Fan,Jing Li Food Funct., 2018,9, 4234-4245

• Solvents and Organic Chemicals Organic Compounds Organic acids and derivatives Carboxylic acids and derivatives Acrylic acids and derivatives
• Solvents and Organic Chemicals Organic Compounds Organic Halides

• 26338-66-9(2-Propenamide, N-(hydroxymethyl)-, polymer with 2-propenamide 2-Propenamide,N-(hydroxymethyl)-,polymer with 2-propenamide)
• 16958-71-7(2-Propenamide,N,N'-[oxybis(methylene)]bis-)
• 68516-90-5(2-Propen-1-aminium, N,N-dimethyl-N-2-propenyl-, chloride, polymer with N-(hydroxymethyl)-2-propenamide)
• 3644-11-9(N-(methoxymethyl)acrylamide)
• 9045-71-0(Methylol acrylamide)
• 13036-41-4(2-Propenamide,N-(ethoxymethyl)-)
• 26603-98-5(buta-1,3-diene; N-(hydroxymethyl)prop-2-enamide; prop-2-enenitrile)
• 17557-99-2(2-Butenamide,N-(hydroxymethyl)-)
• 26374-25-4(2-Propenamide, N-(hydroxymethyl)-, homopolymer N-(Hydroxymethyl)-2-propenamide, homopolymer n-(hydroxymethyl)-2-propenamid homopolymer)
• 172640-58-3(2-Propenamide,N-formyl-N-(hydroxymethyl)-(9CI))