Production Method 1

139669-96-8

918164-43-9

Reaction Conditions

1.1 Reagents: Sulfuric acid Solvents: Methanol ,  Water ;  4 h, 80 °C
1.2 Reagents: Sodium hydroxide Solvents: Water ;  neutralized

Reference

Insights into the mechanism of the site-selective sequential palladium-catalyzed cross-coupling reactions of dibromothiophenes/dibromothiazoles and arylboronic acids. Synthesis of PPARβ/δ agonists

Pereira, Raquel; Furst, Audrey; Iglesias, Beatriz; Germain, Pierre; Gronemeyer, Hinrich; et al, Organic & Biomolecular Chemistry, 2006, 4(24), 4514-4525

methyl 2,4-dibromothiazole-5-carboxylate Raw materials

• 2,4-Dibromo-5-thiazolecarboxylic acid

methyl 2,4-dibromothiazole-5-carboxylate Preparation Products

• methyl 2,4-dibromothiazole-5-carboxylate (918164-43-9)

• 1. Exceptionally high temperature spin crossover in amide-functionalised 2,6-bis(pyrazol-1-yl)pyridine iron(ii) complex revealed by variable temperature Raman spectroscopy and single crystal X-ray diffraction?
  Max Attwood,Hiroki Akutsu,Lee Martin,Toby J. Blundell,Pierre Le Maguere,Scott S. Turner Dalton Trans., 2021,50, 11843-11851
• 2. Evolved polymerases facilitate selection of fully 2′-OMe-modified aptamers?
  Zhixia Liu,Tingjian Chen,Floyd E. Romesberg Chem. Sci., 2017,8, 8179-8182
• 3. Examination of the hydrogen-bonding networks in small water clusters (n = 2–5, 13, 17) using absolutely localized molecular orbital energy decomposition analysis?
  Erika A. Cobar,Paul R. Horn,Robert G. Bergman,Martin Head-Gordon Phys. Chem. Chem. Phys., 2012,14, 15328-15339
• 4. Enantiomorphic symmetry breaking in crystallization of molten sodium chlorate?
  Martin R. Ward,Gary W. Copeland,Andrew J. Alexander Chem. Commun., 2010,46, 7634-7636
• 5. Evidence of pre-micellar aggregates in aqueous solution of amphiphilic PDMS–PEO block copolymer?
  Domenico Lombardo,Gianmarco Munaò,Pietro Calandra,Luigi Pasqua,Maria Teresa Caccamo Phys. Chem. Chem. Phys., 2019,21, 11983-11991

• Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Azoles Thiazolecarboxylic acids and derivatives
• Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Azoles Thiazoles Thiazolecarboxylic acids and derivatives

• 1000575-16-5(Methyl 4-Bromo-2-chlorothiazole-5-carboxylate)
• 1353100-73-8(Methyl 4-bromothiazole-5-carboxylate)
• 54045-74-8(Methyl 2-bromothiazole-5-carboxylate)
• 848500-45-8(Ethyl 2,4-dibromothiazole-5-carboxylate)
• 2091043-87-5(5-Thiazolecarboxylic acid, 4-bromo-2-methyl-, ethyl ester)
• 1244949-48-1(4-Bromothiazole-5-carboxylic acid)
• 139669-96-8(2,4-Dibromo-5-thiazolecarboxylic acid)
• 41731-83-3(Ethyl 2-bromothiazole-5-carboxylate)
• 152300-60-2(4-Bromo-5-thiazolecarboxylic acid ethyl ester)
• 332062-08-5(Fmoc-S-3-amino-4,4-diphenyl-butyric acid)