- Silver nitrate-catalyzed oxidation of aldehydes to carboxylic acids by H2O2Chakraborty, Debashis; et al, Tetrahedron Letters, 2009, 50(47), 6553-6556
Cas no 91-52-1 (2,4-Dimethoxybenzoic acid)
2,4-Dimethoxybenzoic acid structure
Product Name:2,4-Dimethoxybenzoic acid
CAS No:91-52-1
MF:C9H10O4
MW:182.173303127289
MDL:MFCD00002434
CID:34604
PubChem ID:7052
Update Time:2024-10-26
2,4-Dimethoxybenzoic acid Chemical and Physical Properties
Names and Identifiers
-
- 2,4-Dimethoxybenzoic acid
- 2.4-Dimethoxybenzoicacid
- DIMETHOXYBENZOIC ACID,2,4-(RG)
- 2,4-Dimethoxy-benzoesaeure
- 2,4-dimethoxylbenzoic acid
- 4-methoxy-2-methoxy benzoic acid
- Benzoic acid,2,4-dimethoxy
- O,O-dimethylresorcilic acid
- veratric acid
- NSC 6316
- 2,4-Dimethoxybenzoicacid
- Benzoic acid, 2,4-dimethoxy-
- 2,4-dimethoxy-benzoic acid
- 2,4-Dimethoxy benzoic acid
- GPVDHNVGGIAOQT-UHFFFAOYSA-N
- Q63393546
- NSC6316
- PubChem4949
- 2.4-dimethoxybenzoic acid
- 2,4 dimethoxybenzoic acid
- 2, 4-dimethoxybenzoic acid
- 2,4-di-methoxybenzoic acid
- KSC487C1L
- 2, 4-dimethoxy benzoic acid
- Benzoicacid, 2,4-dimethoxy-
- 4-methoxy-2-meth
- MFCD00002434
- SY006197
- A843962
- NSC-6316
- CHEMBL463921
- F0850-6813
- 91-52-1
- Z104476538
- BBL027381
- 2,4-dimethoxybenzoesyre
- AKOS000119531
- AC-23686
- AM20060752
- 5699CY3NQJ
- DTXSID1059026
- EINECS 202-074-1
- AC7813
- 2,4-Dimethoxybenzoic acid, 98%
- BS-3990
- UNII-5699CY3NQJ
- EN300-20039
- InChI=1/C9H10O4/c1-12-6-3-4-7(9(10)11)8(5-6)13-2/h3-5H,1-2H3,(H,10,11
- AI3-27498
- W-100307
- STL169141
- D1675
- FT-0610136
- CS-W019954
- SCHEMBL154613
- 2,4-Dimethoxybenzoic acid (ACI)
- NS00039400
- DTXCID5048718
- 2,4-dimethoxybenzoate
- DB-019964
- 24-Dimethoxybenzoate
- 24-Dimethoxybenzoic acid
-
- MDL： MFCD00002434
- Inchi： 1S/C9H10O4/c1-12-6-3-4-7(9(10)11)8(5-6)13-2/h3-5H,1-2H3,(H,10,11)
- InChI Key： GPVDHNVGGIAOQT-UHFFFAOYSA-N
- SMILES： O=C(C1C(OC)=CC(OC)=CC=1)O
- BRN： 2210860
Computed Properties
- Exact Mass: 182.05800
- Monoisotopic Mass: 182.058
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 1
- Hydrogen Bond Acceptor Count: 4
- Heavy Atom Count: 13
- Rotatable Bond Count: 3
- Complexity: 181
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- XLogP3: 1.6
- Topological Polar Surface Area: 55.8
Experimental Properties
- Color/Form: White or off white crystalline powder.
- Density: 1.2481 (rough estimate)
- Melting Point: 108.0 to 112.0 deg-C
- Boiling Point: 275.56°C (rough estimate)
- Flash Point: 125.8℃
- Refractive Index: 1.4500 (estimate)
- Water Partition Coefficient: Slightly soluble
- PSA: 55.76000
- LogP: 1.40200
- Solubility: Not determined
2,4-Dimethoxybenzoic acid Security Information
-
Symbol:
- Prompt：warning
- Signal Word：Warning
- Hazard Statement： H315-H319
- Warning Statement： P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
- Hazardous Material transportation number：NONH for all modes of transport
- WGK Germany：3
- Hazard Category Code： 36/37/38
- Safety Instruction： S26-S37/39
-
Hazardous Material Identification：
- Risk Phrases：R36/37/38
- TSCA：Yes
- Storage Condition：Sealed in dry,Room Temperature
2,4-Dimethoxybenzoic acid Customs Data
- HS CODE：29189090
- Customs Data：
China Customs Code:
2918990090Overview:
2918990090. Other additional oxy carboxylic acids(Including anhydrides\Acyl halide\Peroxides, peroxyacids and derivatives of this tax number). VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:6.5%. general tariff:30.0%
Declaration elements:
Product Name, component content, use to
Summary:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%
2,4-Dimethoxybenzoic acid Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | D1675-25g |
2,4-Dimethoxybenzoic acid |
91-52-1 | 99.0%(T) | 25g |
￥260.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | DH964-100g |
2,4-Dimethoxybenzoic acid |
91-52-1 | 98% | 100g |
￥338.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | DH964-500g |
2,4-Dimethoxybenzoic acid |
91-52-1 | 98% | 500g |
￥1393.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | DH964-25g |
2,4-Dimethoxybenzoic acid |
91-52-1 | 98% | 25g |
￥109.0 | 2022-05-30 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | D1675-5g |
2,4-Dimethoxybenzoic acid |
91-52-1 | 99.0%(T) | 5g |
￥150.0 | 2022-05-30 | |
| Chemenu | CM157324-500g |
2,4-Dimethoxybenzoic acid |
91-52-1 | 95+% | 500g |
$184 | 2021-06-17 | |
| Chemenu | CM157324-1000g |
2,4-Dimethoxybenzoic acid |
91-52-1 | 95+% | 1000g |
$304 | 2021-06-17 | |
| Alichem | A015001183-250mg |
2,4-Dimethoxybenzoic acid |
91-52-1 | 97% | 250mg |
$475.20 | 2023-08-31 | |
| Alichem | A015001183-500mg |
2,4-Dimethoxybenzoic acid |
91-52-1 | 97% | 500mg |
$863.90 | 2023-08-31 | |
| Alichem | A015001183-1g |
2,4-Dimethoxybenzoic acid |
91-52-1 | 97% | 1g |
$1519.80 | 2023-08-31 |
2,4-Dimethoxybenzoic acid Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Hydrogen peroxide Catalysts: Silver nitrate Solvents: Acetonitrile ; rt → 50 °C; 1.5 h, 50 °C
1.2 Reagents: Sodium thiosulfate Solvents: Water
1.2 Reagents: Sodium thiosulfate Solvents: Water
Reference
Production Method 2
Reaction Conditions
1.1 Reagents: Hydrogen peroxide Catalysts: 1-Hexadecanaminium, N,N,N-trimethyl-, (PB-7-34-111′1′2)-oxodiperoxy(2-pyridineca… Solvents: Water ; 24 h, 80 °C
Reference
- Controlled and Predictably Selective Oxidation of Activated and Unactivated C(sp3)-H Bonds Catalyzed by a Molybdenum-Based Metallomicellar Catalyst in WaterThiruvengetam, Prabaharan; et al, Journal of Organic Chemistry, 2022, 87(6), 4061-4077
Production Method 3
Reaction Conditions
1.1 Reagents: Potassium hydroxide
Reference
- Alternatives to N,N-Diethyl-2,4-dimethoxybenzamide as a Precursor for the Synthesis of 6,8-Dimethoxy-3-methyl-3,4-dihydro-1-isochromenoneVan Otterlo, Willem A. L.; et al, Synthetic Communications, 2007, 37(20), 3611-3621
Production Method 4
Reaction Conditions
1.1 Reagents: Potassium hydroxide Solvents: Ethanol , Water ; reflux; cooled
1.2 Reagents: Hydrochloric acid Solvents: Water ; acidified
1.2 Reagents: Hydrochloric acid Solvents: Water ; acidified
Reference
- Rational Design of Rod-Like Liquid Crystals Exhibiting Two Nematic PhasesMandle, Richard J. ; et al, Chemistry - A European Journal, 2017, 23(58), 14554-14562
Production Method 5
Reaction Conditions
1.1 Reagents: Pyridine , 1-Ethyl-3-(3′-dimethylaminopropyl)carbodiimide hydrochloride Solvents: Dichloromethane ; 30 min, rt
1.2 Reagents: Hydroxyamine hydrochloride Catalysts: 4-(Dimethylamino)pyridine ; 4 h, rt
1.3 Reagents: Hydrochloric acid Solvents: Water ; pH 2
2.1 Reagents: Hydrogen peroxide Catalysts: Tetrabutylammonium iodide Solvents: Tetrahydrofuran , Water ; 24 h, rt
2.2 Reagents: Sodium carbonate Solvents: Water
1.2 Reagents: Hydroxyamine hydrochloride Catalysts: 4-(Dimethylamino)pyridine ; 4 h, rt
1.3 Reagents: Hydrochloric acid Solvents: Water ; pH 2
2.1 Reagents: Hydrogen peroxide Catalysts: Tetrabutylammonium iodide Solvents: Tetrahydrofuran , Water ; 24 h, rt
2.2 Reagents: Sodium carbonate Solvents: Water
Reference
- n-Bu4NI/H2O2-catalyzed mild conversion of hydroxamic acids to carboxylic acidsNakamura, Akira ; et al, Tetrahedron Letters, 2023, 126,
Production Method 6
Reaction Conditions
1.1 Reagents: Hydroxyamine hydrochloride , Hydrochloric acid , Hydrogen peroxide Solvents: Acetonitrile , Water ; 1.5 h, 80 °C
1.2 Reagents: Sodium thiosulfate Solvents: Water
1.2 Reagents: Sodium thiosulfate Solvents: Water
Reference
- Selective and efficient oxidation of aldehydes to their corresponding carboxylic acids using H2O2/HCl in the presence of hydroxylamine hydrochlorideBahrami, Kiumars; et al, Chinese Journal of Chemistry, 2008, 26(6), 1119-1121
Production Method 7
Reaction Conditions
1.1 Reagents: Hydrogen peroxide Catalysts: Tin oxide Solvents: Acetonitrile , Water ; 90 min, 60 °C
Reference
- SnO2 nanoparticles: Preparation and evaluation of their catalytic activity in the oxidation of aldehyde derivatives to their carboxylic acid and sulfides to sulfoxide analogsDehbashi, Mohsen; et al, Phosphorus, 2013, 188(7), 864-872
2,4-Dimethoxybenzoic acid Raw materials
2,4-Dimethoxybenzoic acid Preparation Products
2,4-Dimethoxybenzoic acid Suppliers
Amadis Chemical Company Limited
Gold Member
Audited Supplier
(CAS:91-52-1)2,4-Dimethoxybenzoic acid
Order Number:A843962
Stock Status:in Stock
Quantity:500g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 07:01
Price ($):207.0
Email:[email protected]
2,4-Dimethoxybenzoic acid Related Literature
-
Siquan Zhang,Shengyao Wang,Liping Guo,Hao Chen,Bien Tan,Shangbin Jin J. Mater. Chem. C, 2020,8, 192-200
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Yang Chen,Di Zhou,Zheyi Meng,Jin Zhai Chem. Commun., 2016,52, 10020-10023
-
Karl Crowley,Eimer O'Malley,Aoife Morrin,Malcolm R. Smyth,Anthony J. Killard Analyst, 2008,133, 391-399
-
4. An investigation of the electrochemical delithiation process of carbon coated α-Fe2O3nanoparticlesAdrian Brandt,Florian Winter,Sebastian Klamor,Frank Berkemeier,Jatinkumar Rana,Rainer P?ttgen,Andrea Balducci J. Mater. Chem. A, 2013,1, 11229-11236
-
Jialiang Yuan,Ran Dong,Yuan Li,Yang Liu,Zhuo Zheng,Yuxia Liu,Yan Sun,Benhe Zhong,Zhenguo Wu,Xiaodong Guo Chem. Commun., 2021,57, 13004-13007
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Recommended suppliers
Amadis Chemical Company Limited
(CAS:91-52-1)2,4-Dimethoxybenzoic acid
Purity:99%
Quantity:500g
Price ($):207.0