- Oxidative dimerization of primary alcohols to esters catalyzed by iridium complexesIzumi, Aki; et al, Tetrahedron Letters, 2006, 47(52), 9199-9201
Cas no 90397-38-9 (2-Methylpentyl 2-methylvalerate)
90397-38-9 structure
Product Name:2-Methylpentyl 2-methylvalerate
CAS No:90397-38-9
MF:C12H24O2
MW:200.317764282227
CID:61414
Update Time:2023-11-06
2-Methylpentyl 2-methylvalerate Chemical and Physical Properties
Names and Identifiers
-
- 2-Methylpentyl 2-methylvalerate
- 2-Methylpentyl 2-methylpentanoate
- ARABINOXYLAN
- Pentanoic acid,2-methyl-,2-methylpentyl ester
- 2-Methylpentyl 2-methylpentanoate (ACI)
- Peranat
-
- Inchi: 1S/C12H24O2/c1-5-7-10(3)9-14-12(13)11(4)8-6-2/h10-11H,5-9H2,1-4H3
- InChI Key: UMFWRNLJDQMTFR-UHFFFAOYSA-N
- SMILES: O=C(C(CCC)C)OCC(CCC)C
Computed Properties
- Exact Mass: 200.17800
Experimental Properties
- PSA: 26.30000
- LogP: 3.40200
2-Methylpentyl 2-methylvalerate Production Method
Production Method 1
Reaction Conditions
1.1 Catalysts: Di-μ-chlorotetrakis[(1,2-η)-cyclooctene]diiridium ; 20 h, 95 °C
Reference
Production Method 2
Reaction Conditions
1.1 Reagents: Hydrogen peroxide Catalysts: Bromine Solvents: Dichloromethane , Water ; 6 h, rt
Reference
- Catalytic Processes of Oxidation by Hydrogen Peroxide in the Presence of Br2 or HBr. Mechanism and Synthetic ApplicationsAmati, Alessandro; et al, Organic Process Research & Development, 1998, 2(4), 261-269
Production Method 3
Reaction Conditions
1.1 Reagents: Cesium carbonate Catalysts: 2305295-37-6 Solvents: Toluene ; 96 h, 110 °C
Reference
- Synthesis of Unsymmetrical N-Heterocyclic Carbene-Nitrogen-Phosphine Chelated Ruthenium(II) Complexes and Their Reactivity in Acceptorless Dehydrogenative Coupling of Alcohols to EstersHe, Xiaochun; et al, Organometallics, 2019, 38(8), 1750-1760
Production Method 4
Reaction Conditions
1.1 Catalysts: [μ-[1,2-Benzenediolato(2-)-κO:κO′]]tetrakis(2-propanolato)dialuminum Solvents: Dichloromethane , Toluene
1.2 Reagents: Hydrochloric acid Solvents: Water
1.2 Reagents: Hydrochloric acid Solvents: Water
Reference
- Symmetric esters by Tischtschenko reaction of aldehydes catalyzed by bi- and tridentate catalysts derived from catechol or gallol, trimethylaluminum and isopropanolSimpura, Ilkka; et al, Tetrahedron, 2001, 57(49), 9867-9872
2-Methylpentyl 2-methylvalerate Preparation Products
2-Methylpentyl 2-methylvalerate Related Literature
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R. M. Pemberton,J. P. Hart,T. T. Mottram Analyst, 2001,126, 1866-1871
-
Xixi Li,Nanwei Zhu,Ruohan Li,Qinpu Zhang Anal. Methods, 2020,12, 3376-3381
-
Huifang Yang,Haoran Guo,Peidong Fan,Xinpan Li,Wenlu Ren,Rui Song Nanoscale, 2020,12, 7024-7034
-
Chandran Rajendran,Govindaswamy Satishkumar,Charlotte Lang,Eric M. Gaigneaux Catal. Sci. Technol., 2020,10, 2583-2592
-
Bidou Wang,Xifeng Chen Analyst, 2014,139, 5695-5699
90397-38-9 (2-Methylpentyl 2-methylvalerate) Related Products
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- 105-79-3(isobutyl caproate)
- 2094-73-7(1-Adamantylcarboxylic Acid Ethyl Ester)
- 85-42-7(octahydro-2-benzofuran-1,3-dione)
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- 2163-48-6(Diethyl propylmalonate)
- 94-28-0(Tri(ethylenglycol)bis-2-ethylhexanoate)
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