Cas no 90151-10-3 (4-Methoxypicolinamide)

4-Methoxypicolinamide structure
4-Methoxypicolinamide structure
Product Name:4-Methoxypicolinamide
CAS No:90151-10-3
MF:C7H8N2O2
MW:152.150621414185
MDL:MFCD00955999
CID:810435
PubChem ID:5214209
Update Time:2024-10-26

4-Methoxypicolinamide Chemical and Physical Properties

Names and Identifiers

    • 4-Methoxypicolinamide
    • 2-Pyridinecarboxamide,4-methoxy-
    • 4-Methoxypyridine-2-carboxamide
    • 4-Methoxy-Pyridine-2-Carboxylic Acid Amide
    • 2-Pyridinecarboxamide,4-methoxy-(9CI)
    • 4-Methoxy-2-Pyridinecarboxamide
    • 4-Methoxy-picolinamid
    • 4-Methoxy-picolinsaeureamid
    • 4-Methoxy-2-pyridinecarboxamide (ACI)
    • Picolinamide, 4-methoxy- (7CI)
    • AB07772
    • 4-Methoxypyridine-2-carboxylic acid amide
    • CHEMBL4517269
    • Z1201620706
    • 4-Methoxy-pyridine-2-carboxylic acid amide, AldrichCPR
    • Nonyl nonoxynol-5
    • D74452
    • SCHEMBL2624147
    • CS-0082331
    • DYHMIVKBJSIOCH-UHFFFAOYSA-N
    • DB-057185
    • 9014-93-1
    • 90151-10-3
    • SY143623
    • EN300-120989
    • MFCD00955999
    • AKOS006343714
    • MDL: MFCD00955999
    • Inchi: 1S/C7H8N2O2/c1-11-5-2-3-9-6(4-5)7(8)10/h2-4H,1H3,(H2,8,10)
    • InChI Key: DYHMIVKBJSIOCH-UHFFFAOYSA-N
    • SMILES: O=C(C1C=C(OC)C=CN=1)N

Computed Properties

  • Exact Mass: 152.05900
  • Monoisotopic Mass: 152.059
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 1
  • Hydrogen Bond Acceptor Count: 4
  • Heavy Atom Count: 11
  • Rotatable Bond Count: 2
  • Complexity: 149
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Topological Polar Surface Area: 65.2A^2
  • XLogP3: 0

Experimental Properties

  • Density: 1.152
  • Melting Point: 149.3°C
  • Boiling Point: 280.6°Cat760mmHg
  • Flash Point: 123.5°C
  • Refractive Index: 1.55
  • PSA: 65.21000
  • LogP: 0.88940
  • Vapor Pressure: 0.0±0.7 mmHg at 25°C

4-Methoxypicolinamide Security Information

  • Signal Word:warning
  • Hazard Statement: Irritant
  • Warning Statement: P264+P280+P305+P351+P338+P337+P313
  • Hazardous Material transportation number:NONH for all modes of transport
  • Hazard Category Code: 22-36
  • Safety Instruction: 26
  • Hazardous Material Identification: Xi
  • HazardClass:IRRITANT
  • Storage Condition:storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)

4-Methoxypicolinamide Customs Data

  • HS CODE:2933399090
  • Customs Data:

    China Customs Code:

    2933399090

    Overview:

    2933399090. Other compounds with non fused pyridine rings in structure. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:6.5%. general tariff:20.0%

    Declaration elements:

    Product Name, component content, use to, Please indicate the appearance of Urotropine, 6- caprolactam please indicate the appearance, Signing date

    Summary:

    2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

4-Methoxypicolinamide Pricemore >>

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4-Methoxypicolinamide Production Method

Production Method 1

Reaction Conditions
1.1 Reagents: Sodium methoxide Solvents: Methanol ;  25 °C
Reference
New ligands for nickel catalysis from diverse pharmaceutical heterocycle libraries
Hansen, Eric C.; Pedro, Dylan J.; Wotal, Alexander C.; Gower, Nicholas J.; Nelson, Jade D.; et al, Nature Chemistry, 2016, 8(12), 1126-1130

Production Method 2

Reaction Conditions
1.1 Reagents: Sodium formate ,  Potassium persulfate ,  Oxygen Catalysts: Silver nitrate Solvents: Water ;  4 h, 80 °C
Reference
Acid-Free Silver-Catalyzed Cross-Dehydrogenative Carbamoylation of Pyridines with Formamides
Han, Wei; Jin, Fengli; Zhao, Qian; Du, Hongyan; Yao, Lifang, Synlett, 2016, 27(12), 1854-1859

Production Method 3

Reaction Conditions
1.1 Reagents: Ammonia Solvents: Methanol
Reference
Synthetic approaches towards the marine natural products typified by variolin B. A novel fused pyrimidino-7-azaindole
Meigh, Jon-Paul K., 2000, , ,

Production Method 4

Reaction Conditions
1.1 Reagents: Ammonia Solvents: Methanol
Reference
Cyclic ureas as ortho directing substituents
Meigh, Jon-Paul; Alvarez, Mercedes; Joule, John A., Journal of the Chemical Society, 2001, (17), 2012-2021

4-Methoxypicolinamide Raw materials

4-Methoxypicolinamide Preparation Products

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