Production Method 1

365564-05-2

89641-21-4

Reaction Conditions

1.1 Reagents: Sodium periodate Solvents: Tetrahydrofuran ,  Water ;  overnight, rt
1.2 Reagents: Hydrochloric acid Solvents: Water ;  24 h, rt

Reference

Self-exfoliation of 2D covalent organic frameworks: morphology transformation induced by solvent polarity

Zhang, Na; Wang, Taisheng; Wu, Xing; Jiang, Chen; Chen, Fang; et al, RSC Advances, 2018, 8(7), 3803-3808

Production Method 2

197141-36-9

89641-21-4

Reaction Conditions

1.1 Reagents: Borane Solvents: Tetrahydrofuran ;  1 h, rt; 3 h, reflux

Reference

Three-step synthesis of arylpolyboronic acids from phenols via organotin compounds

Fidelibus, Pablo M.; Silbestri, Gustavo F.; Lockhart, Maria T.; Mandolesi, Sandra D.; Chopa, Alicia B.; et al, Applied Organometallic Chemistry, 2007, 21(8), 682-687

Production Method 3

5624-60-2

89641-21-4

Reaction Conditions

1.1 Reagents: Boron tribromide ;  4 h, 100 °C

Reference

A Photoresponsive Smart Covalent Organic Framework

Huang, Ning; Ding, Xuesong; Kim, Jangbae; Ihee, Hyotcherl; Jiang, Donglin, Angewandte Chemie, 2015, 54(30), 8704-8707

Production Method 4

5624-60-2

89641-21-4

Reaction Conditions

1.1 Reagents: Boron tribromide ;  4 h, 100 °C; cooled
1.2 Solvents: Hexane ,  Water ;  0 °C

Reference

Facile Synthesis of a Highly Crystalline, Covalently Linked Porous Boronate Network

Tilford, R. William; Gemmill, William R.; zur Loye, Hans-Conrad; Lavigne, John J., Chemistry of Materials, 2006, 18(22), 5296-5301

Production Method 5

365564-05-2

89641-21-4

Reaction Conditions

1.1 Reagents: Sodium periodate Solvents: Tetrahydrofuran ,  Water ;  overnight, rt
1.2 Reagents: Hydrochloric acid Solvents: Water ;  24 h, rt

Reference

A Permanent Mesoporous Organic Cage with an Exceptionally High Surface Area

Zhang, Gang; Presly, Oliver; White, Fraser; Oppel, Iris M.; Mastalerz, Michael, Angewandte Chemie, 2014, 53(6), 1516-1520

Production Method 6

365564-05-2

89641-21-4

Reaction Conditions

1.1 Reagents: Sodium periodate Solvents: Tetrahydrofuran ,  Water ;  overnight, rt
1.2 Reagents: Hydrochloric acid Solvents: Water ;  24 h, rt
1.3 Reagents: Hydrochloric acid Solvents: Water ;  2 h, rt

Reference

Inflating face-capped Pd6L8 coordination cages

Jansze, Suzanne M.; Ortiz, Daniel; Fadaei Tirani, Farzaneh; Scopelliti, Rosario; Menin, Laure; et al, Chemical Communications (Cambridge, 2018, 54(68), 9529-9532

BTBA Raw materials

• 1,3,5-Tris(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzene
• Stannane, 1,3,5-benzenetriyltris[trimethyl-
• Benzene,1,3,5-tris(trimethylsilyl)-

BTBA Preparation Products

• BTBA (89641-21-4)

• 1. Dissociation of aryl sulfonyl phthalimide radical anions: relevance to the biological activity of arylsulfonyl amides?
  Abdelaziz Houmam,Emad M. Hamed Chem. Commun., 2012,48, 11328-11330
• 2. Dissociative dynamics of O2 on Ag(110)?
  Ivor Lon?ari? Phys. Chem. Chem. Phys., 2015,17, 9436-9445
• 3. Ester-directed orthogonal dual C–H activation and ortho aryl C–H alkenylation via distal weak coordination?
  Manickam Bakthadoss,Tadiparthi Thirupathi Reddy,Vishal Agarwal,Duddu S. Sharada Chem. Commun., 2022,58, 1406-1409
• 4. Establishing new scaling relations on two-dimensional MXenes for CO2 electroreduction?
  Albertus D. Handoko,Khoong Hong Khoo,Teck Leong Tan,Hongmei Jin,Zhi Wei Seh J. Mater. Chem. A, 2018,6, 21885-21890
• 5. Evolutionary approaches in protein engineering towards biomaterial construction
  Brindha J.,Balamurali M. M.,Kaushik Chanda RSC Adv., 2019,9, 34720-34734

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzene and substituted derivatives
• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives

• 98-80-6(Phenylboronic acid)
• 100622-34-2(9-Anthraceneboronic acid)
• 164461-18-1(Pyren-1-ylboronic Acid)
• 4612-28-6(1,3-benzenediboronicacid)
• 13922-41-3(1-Naphthylboronic acid)
• 4612-26-4(1,4-Phenylenediboronic acid)
• 68572-87-2(9-Phenanthreneboronic Acid)
• 52542-80-0(Sodium (Trihydroxy)phenylborate)
• 141981-64-8(2-Anthraceneboronic Acid)
• 32316-92-0(2-Naphthylboronic acid)