- Metal free [4+1] and [5+1] annulation reactions to prepare heterocycles using DMF and its derivatives as one-carbon sourceXu, Yiwen; Shen, Bei; Liu, Lingfeng; Qiao, Chunhua, Tetrahedron Letters, 2020, 61(19),
Cas no 89570-83-2 (2-Hydrazinyl-3-(trifluoromethyl)pyridine)
89570-83-2 structure
Product Name:2-Hydrazinyl-3-(trifluoromethyl)pyridine
CAS No:89570-83-2
MF:C6H6F3N3
MW:177.127151012421
MDL:MFCD01320804
CID:61287
PubChem ID:2777776
Update Time:2024-12-09
2-Hydrazinyl-3-(trifluoromethyl)pyridine Chemical and Physical Properties
Names and Identifiers
-
- 2-Hydrazinyl-3-(trifluoromethyl)pyridine
- (3-TRIFLUOROMETHYLPYRID-2-YL)HYDRAZINE
- [3-(trifluoromethyl)pyridin-2-yl]hydrazine
- 2-HYDRAZINO-3-(TRIFLUOROMETHYL)PYRIDINE
- (3-trifluoromethylpyridin-2-yl)-hydrazine
- 1-(3-(trifluoromethyl)pyridin-2-yl)hydrazine
- 2-hydrazino-3-trifluoromethylpyridine
- 3-(trifluoromethyl)-2-pyridylhydrazine
- 3-(Trifluoromethyl)pyrid-2-ylhydrazine
- 3-trifluoromethyl-2-hydrazinopyridine
- Pyridine,2-hydrazinyl-3-(trifluoromethyl)
- 3-(Trifluoromethyl)pyridine-2-hydrazine
- Pyridine,2-hydrazinyl-3-(trifluoromethyl)-
- (3-Trifluoromethylpyrid-2-yl) Hydrazine
- PubChem20816
- (3-Trifluoromethyl-pyridin-2-yl)-hydrazine
- SC
- 2(1H)-Pyridinone, 3-(trifluoromethyl)-, hydrazone (9CI)
- 2-Hydrazinyl-3-(trifluoromethyl)pyridine (ACI)
- 12P-663
- DTXSID70380649
- 2(1H)-Pyridinone, 3-(trifluoromethyl)-, hydrazone
- BP-13307
- AKOS000148658
- BL010283
- DB-017983
- DTXCID10331675
- CS-0094721
- SCHEMBL358590
- 89570-83-2
- EN300-36763
- AC-29125
- MFCD01320804
- J-509578
- SY062577
- DB-261197
- SB52406
- F2173-0092
-
- MDL: MFCD01320804
- Inchi: 1S/C6H6F3N3/c7-6(8,9)4-2-1-3-11-5(4)12-10/h1-3H,10H2,(H,11,12)
- InChI Key: TWPMJXZSKBAITM-UHFFFAOYSA-N
- SMILES: FC(C1C(=NN)NC=CC=1)(F)F
Computed Properties
- Exact Mass: 177.05100
- Monoisotopic Mass: 177.051
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 2
- Hydrogen Bond Acceptor Count: 6
- Heavy Atom Count: 12
- Rotatable Bond Count: 1
- Complexity: 148
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: 2
- XLogP3: 1.3
- Topological Polar Surface Area: 50.9
Experimental Properties
- Density: 1.442
- Boiling Point: 250.1°C at 760 mmHg
- Flash Point: 105°C
- Refractive Index: 1.528
- PSA: 50.94000
- LogP: 2.15930
2-Hydrazinyl-3-(trifluoromethyl)pyridine Security Information
- Hazard Category Code: R36/37/38: irritating to eyes, respiratory tract and skin
- Safety Instruction: S26-S36/37/39
-
Hazardous Material Identification:
- HazardClass:IRRITANT
- Risk Phrases:R36/37/38
2-Hydrazinyl-3-(trifluoromethyl)pyridine Customs Data
- HS CODE:2933990090
- Customs Data:
China Customs Code:
2933990090Overview:
2933990090. Other heterocyclic compounds containing only nitrogen heteroatoms. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:nothing. MFN tariff:6.5%. general tariff:20.0%
Declaration elements:
Product Name, component content, use to, Please indicate the appearance of Urotropine, 6- caprolactam please indicate the appearance, Signing date
Summary:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
2-Hydrazinyl-3-(trifluoromethyl)pyridine Pricemore >>
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89570-83-2 | 95% | 250mg |
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89570-83-2 | 95% | 25g |
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| Chemenu | CM175894-25g |
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| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-KU875-200mg |
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2165.0CNY | 2021-08-03 |
2-Hydrazinyl-3-(trifluoromethyl)pyridine Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Hydrazine hydrate (1:1) Solvents: Ethanol ; rt; reflux
Reference
Production Method 2
Reaction Conditions
Reference
- Preparation of [(aminoalkyl)thio]-1,2,4-triazolo[4,3-a]pyridines and -quinolines as analgesics, European Patent Organization, , ,
Production Method 3
Reaction Conditions
1.1 Reagents: Hydrazine
Reference
- Preparation of triazolopyridines as herbicides, European Patent Organization, , ,
Production Method 4
Reaction Conditions
1.1 Reagents: Hydrazine hydrate (1:1) Solvents: Ethanol ; 29 h, 105 °C
Reference
- Tetrahydroindazole inhibitors of CDK2/cyclin complexesLee, Jae Chul ; Hong, Kwon Ho ; Becker, Andreas ; Tash, Joseph S.; Schonbrunn, Ernst; et al, European Journal of Medicinal Chemistry, 2021, 214,
2-Hydrazinyl-3-(trifluoromethyl)pyridine Raw materials
2-Hydrazinyl-3-(trifluoromethyl)pyridine Preparation Products
2-Hydrazinyl-3-(trifluoromethyl)pyridine Related Literature
-
Partha Laskar,Christine Dufès Nanoscale Adv., 2021,3, 6007-6026
-
Xinhuan Wang,Shuangfei Cai,Cui Qi Analyst, 2017,142, 2500-2506
-
Gang Pan,Yi-jie Bao,Jie Xu,Tao Liu,Cheng Liu,Yan-yan Qiu,Xiao-jing Shi,Hui Yu,Ting-ting Jia,Xia Yuan,Ze-ting Yuan,Yi-jun Cao RSC Adv., 2016,6, 42109-42119
-
Tao Wang,Yangyang Liu,Yue Deng,Hongbo Fu,Jianmin Chen Environ. Sci.: Nano, 2018,5, 1821-1833
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