- Enantiodivergent Atroposelective Synthesis of Chiral Biaryls by Asymmetric Transfer Hydrogenation: Chiral Phosphoric Acid Catalyzed Dynamic Kinetic ResolutionMori, Keiji; Itakura, Tsubasa; Akiyama, Takahiko, Angewandte Chemie, 2016, 55(38), 11642-11646
Cas no 89488-25-5 (5-chloro-2-hydroxyphenylboronicacid)
5-chloro-2-hydroxyphenylboronic acid is a versatile boronic acid derivative with a distinct chloro substituent at the 5-position and a hydroxyl group at the 2-position. This compound exhibits high reactivity in various organic transformations, particularly in Suzuki coupling reactions, due to its ability to facilitate carbon-carbon bond formation. Its structural features contribute to its selectivity and efficiency, making it a valuable reagent in synthetic chemistry.
89488-25-5 structure
Product Name:5-chloro-2-hydroxyphenylboronicacid
CAS No:89488-25-5
MF:C6H6BClO3
MW:172.374041080475
MDL:MFCD06659863
CID:720628
PubChem ID:23005362
Update Time:2025-06-20
5-chloro-2-hydroxyphenylboronicacid Chemical and Physical Properties
Names and Identifiers
-
- 5-Chloro-2-hydroxyphenylboronic acid
- 5-Chloro-2-hydroxybenzeneboronic acid
- (5-chloro-2-hydroxyphenyl)boronic acid
- Boronic acid,B-(5-chloro-2-hydroxyphenyl)-
- 2-Hydroxy-5-chlorophenylboronic acid
- Boronic acid, (5-chloro-2-hydroxyphenyl)-
- 2-Borono-4-chlorophenol
- 5-Chloro-2-Hydroxyphenyl-Boronic Acid
- PubChem19653
- GGZASRFCRAZNPO-UHFFFAOYSA-N
- 2-(Dihydroxyboryl)-4-chlorophenol
- OR4250
- FCH919439
- LS11049
- AB26500
- (5-Chloro-2-hydroxyphenyl
- B-(5-Chloro-2-hydroxyphenyl)boronic acid (ACI)
- Benzeneboronic acid, 5-chloro-2-hydroxy- (7CI)
- Boronic acid, (5-chloro-2-hydroxyphenyl)- (9CI)
- 5-chloro-2-hydroxyphenylboronicacid
- SY026155
- 89488-25-5
- PS-9506
- CS-0008642
- 5-Chloro-2-hydroxyphenylboronic acid, AldrichCPR
- N12081
- MFCD06659863
- AKOS004113800
- (5-Chloro-2-hydroxyphenyl) boronic acid
- DB-031955
- DTXSID20629636
- C3026
- EN300-257465
- J-517312
- SCHEMBL320185
- (5-Chloro-2-hydroxyphenyl)boronic Acid (contains varying amounts of Anhydride)
-
- MDL： MFCD06659863
- Inchi： 1S/C6H6BClO3/c8-4-1-2-6(9)5(3-4)7(10)11/h1-3,9-11H
- InChI Key： GGZASRFCRAZNPO-UHFFFAOYSA-N
- SMILES： ClC1C=C(B(O)O)C(O)=CC=1
Computed Properties
- Exact Mass: 172.01000
- Monoisotopic Mass: 172.01
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 3
- Hydrogen Bond Acceptor Count: 3
- Heavy Atom Count: 11
- Rotatable Bond Count: 1
- Complexity: 133
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 60.7
- Surface Charge: 0
- Tautomer Count: 3
- XLogP3: nothing
Experimental Properties
- Density: 1.49±0.1 g/cm3 (20 oC 760 Torr),
- Melting Point: 241-242 oC (benzene )
- Boiling Point: 369.275℃/760mmHg
- Flash Point: 177.131°C
- Refractive Index: 1.602
- Solubility: Slightly soluble (3.4 g/l) (25 o C),
- PSA: 60.69000
- LogP: -0.27460
5-chloro-2-hydroxyphenylboronicacid Customs Data
- HS CODE：2931900090
- Customs Data：
China Customs Code:
2931900090Overview:
2931900090. Other organic-Inorganic compound. VAT:17.0%. Tax refund rate:13.0%. Regulatory conditions:AB(Customs clearance form for Inbound Goods,Customs clearance form for outbound goods). MFN tariff:6.5%. general tariff:30.0%
Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
5-chloro-2-hydroxyphenylboronicacid Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| Fluorochem | 045264-1g |
5-Chloro-2-hydroxyphenylboronic acid |
89488-25-5 | 97% | 1g |
￡76.00 | 2022-02-28 | |
| Fluorochem | 045264-5g |
5-Chloro-2-hydroxyphenylboronic acid |
89488-25-5 | 97% | 5g |
￡157.00 | 2022-02-28 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | C13563-1g |
5-chloro-2-hydroxyphenylboronicacid |
89488-25-5 | 98% | 1g |
179.0CNY | 2021-08-04 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | C13563-5g |
5-chloro-2-hydroxyphenylboronicacid |
89488-25-5 | 98% | 5g |
526.0CNY | 2021-08-04 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-QJ653-200mg |
5-chloro-2-hydroxyphenylboronicacid |
89488-25-5 | 98% | 200mg |
129.0CNY | 2021-08-04 | |
| SHANG HAI XIAN DING Biotechnology Co., Ltd. | B-QJ653-1g |
5-chloro-2-hydroxyphenylboronicacid |
89488-25-5 | 98% | 1g |
423.0CNY | 2021-08-04 | |
| TRC | C421978-100mg |
5-Chloro-2-hydroxyphenylboronic acid |
89488-25-5 | 100mg |
$64.00 | 2023-05-18 | ||
| TRC | C421978-250mg |
5-Chloro-2-hydroxyphenylboronic acid |
89488-25-5 | 250mg |
$75.00 | 2023-05-18 | ||
| TRC | C421978-500mg |
5-Chloro-2-hydroxyphenylboronic acid |
89488-25-5 | 500mg |
$87.00 | 2023-05-18 | ||
| TRC | C421978-1g |
5-Chloro-2-hydroxyphenylboronic acid |
89488-25-5 | 1g |
$98.00 | 2023-05-18 |
5-chloro-2-hydroxyphenylboronicacid Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Chloromethyl methyl ether , Sodium hydride Solvents: Dimethylformamide ; 0 °C; 2 h, rt
1.2 Reagents: Hydrochloric acid Solvents: Water ; 0 °C
1.3 Reagents: Butyllithium Solvents: Tetrahydrofuran , Hexane ; 0 °C; 2 h, rt
1.4 Reagents: Trimethyl borate ; 0 °C; 1 h, rt
1.5 Reagents: Hydrochloric acid Solvents: Water ; rt; 24 h, rt
1.2 Reagents: Hydrochloric acid Solvents: Water ; 0 °C
1.3 Reagents: Butyllithium Solvents: Tetrahydrofuran , Hexane ; 0 °C; 2 h, rt
1.4 Reagents: Trimethyl borate ; 0 °C; 1 h, rt
1.5 Reagents: Hydrochloric acid Solvents: Water ; rt; 24 h, rt
Reference
5-chloro-2-hydroxyphenylboronicacid Preparation Products
5-chloro-2-hydroxyphenylboronicacid Suppliers
Amadis Chemical Company Limited
Gold Member
Audited Supplier
(CAS:89488-25-5)5-chloro-2-hydroxyphenylboronicacid
Order Number:A22632
Stock Status:in Stock
Quantity:100g/25g
Purity:99%
Pricing Information Last Updated:Friday, 30 August 2024 04:13
Price ($):1194.0/362.0
Email:[email protected]
5-chloro-2-hydroxyphenylboronicacid Related Literature
-
Huading Zhang,Lee R. Moore,Maciej Zborowski,P. Stephen Williams,Shlomo Margel,Jeffrey J. Chalmers Analyst, 2005,130, 514-527
-
2. Estimating and correcting interference fringes in infrared spectra in infrared hyperspectral imagingGhazal Azarfar,Ebrahim Aboualizadeh,Nicholas M. Walter,Simona Ratti,Camilla Olivieri,Alessandra Norici,Michael Nasse,Achim Kohler,Mario Giordano Analyst, 2018,143, 4674-4683
-
Joo Chuan Yeo,Kenry Lab Chip, 2016,16, 4082-4090
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Recommended suppliers
Amadis Chemical Company Limited
(CAS:89488-25-5)5-chloro-2-hydroxyphenylboronicacid
Purity:99%/99%
Quantity:100g/25g
Price ($):1194.0/362.0