Production Method 1

1461-22-9

121134-38-1

886746-54-9

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran

Reference

Effects of incorporated pyrazine on the interchain packing and photovoltaic properties of wide-bandgap D-A polymers for non-fullerene polymer solar cells

Kini, Gururaj P.; Choi, Jun Young; Jeon, Sung Jae; Suh, Il Soon; Moon, Doo Kyung, Polymer Chemistry, 2019, 10(32), 4459-4468

Production Method 2

1461-22-9

121134-38-1

886746-54-9

Reaction Conditions

1.1 Reagents: Butyllithium ,  N,N,N′,N′-Tetramethylethylenediamine Solvents: Tetrahydrofuran ;  0 °C
1.2 0 °C → rt

Reference

Synthesis and Photovoltaic Performance of a [1,2,3]Triazolo[4,5-g]quinoxaline-Based Low-Bandgap Polymer

Hai, Jiefeng; Zhao, Baofeng; Zhu, Enwei; Bian, Linyi; Wu, Hongbin; et al, Macromolecular Chemistry and Physics, 2013, 214(21), 2473-2479

Production Method 3

1461-22-9

121134-38-1

886746-54-9

Reaction Conditions

1.1 Reagents: Butyllithium ,  N,N,N′,N′-Tetramethylethylenediamine Solvents: Tetrahydrofuran ,  Hexane ;  30 min, 0 °C; 30 min, 0 °C; 0 °C → rt
1.2 Solvents: Tetrahydrofuran ;  rt → 0 °C; 30 min, 0 °C; 30 min, 0 °C; 0 °C → rt; 1 h, rt

Reference

Dynamics of Photoinduced Electron Transfer in a Molecular Donor-Acceptor Quartet

Chen, Lin X.; Xiao, Shengqiang; Yu, Luping, Journal of Physical Chemistry B, 2006, 110(24), 11730-11738

Production Method 4

1461-22-9

121134-38-1

886746-54-9

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ,  Hexane ;  -78 °C; overnight, rt

Reference

Benzodithiophene-Dithienylbenzothiadiazole Copolymers for Efficient Polymer Solar Cells: Side-Chain Effect on Photovoltaic Performance

Huang, Lanqi; Zhang, Guangjun; Zhang, Kai; Peng, Qiang ; Wong, Man Shing, ACS Applied Materials & Interfaces, 2018, 10(40), 34355-34362

Production Method 5

1461-22-9

121134-38-1

886746-54-9

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ,  Hexane ;  30 min, -78 °C; 3 h, -78 °C
1.2 1 h, -78 °C; -78 °C → rt; overnight, rt
1.3 Reagents: Sodium bicarbonate Solvents: Water ;  rt

Reference

Tuning Energy Levels of Low Bandgap Semi-Random Two Acceptor Copolymers

Zhou, Jinjun; Xie, Sibai; Amond, Emily F.; Becker, Matthew L., Macromolecules (Washington, 2013, 46(9), 3391-3394

Production Method 6

1461-22-9

121134-38-1

886746-54-9

Reaction Conditions

1.1 Reagents: Lithium diisopropylamide Solvents: Benzene ,  Tetrahydrofuran ,  Hexane ;  rt → -78 °C; 3 h, -78 °C → 0 °C; 0 °C → -78 °C
1.2 -78 °C → -40 °C

Reference

Low-Band-Gap Conjugated Polymers Based on Thiophene, Benzothiadiazole, and Benzobis(thiadiazole)

Bundgaard, Eva; Krebs, Frederik C., Macromolecules, 2006, 39(8), 2823-2831

Production Method 7

872-31-1

1461-22-9

18908-66-2

886746-54-9

Reaction Conditions

1.1 Reagents: Magnesium Solvents: Tetrahydrofuran
1.2 Catalysts: Dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]nickel
1.3 Reagents: Lithium diisopropylamide Solvents: Tetrahydrofuran
1.4 -

Reference

Two wide-bandgap fluorine-substituted benzotriazole based terpolymers for efficient polymer solar cells

Qi, Feng; Song, Jiali; Xiong, Wentao; Huo, Lijun ; Sun, Xiaobo; et al, Dyes and Pigments, 2018, 155, 126-134

STANNANE, TRIBUTYL[4-(2-ETHYLHEXYL)-2-THIENYL]- Raw materials

• 3-Bromothiophene
• tributyl(chloro)stannane
• 2-Ethylhexyl bromide
• 3-(2-Ethylhexyl)thiophene

STANNANE, TRIBUTYL[4-(2-ETHYLHEXYL)-2-THIENYL]- Preparation Products

• STANNANE, TRIBUTYL[4-(2-ETHYLHEXYL)-2-THIENYL]- (886746-54-9)

• 1. Emerging enantiomeric resolution materials with homochiral nano-fabrications
  Ji-Ping Wei Nanoscale, 2015,7, 11815-11832
• 2. Dissociative electron attachment to HGaF4 Lewis–Br?nsted superacid
  Marcin Czapla,Jack Simons Phys. Chem. Chem. Phys., 2018,20, 21739-21745
• 3. Emulsion soft templating of carbide-derived carbon nanospheres with controllable porosity for capacitive electrochemical energy storage?
  M. Zeiger,N. J?ckel,P. Strubel,L. Borchardt,R. Reinhold,W. Nickel,J. Eckert,V. Presser,S. Kaskel J. Mater. Chem. A, 2015,3, 17983-17990
• 4. Evolved polymerases facilitate selection of fully 2′-OMe-modified aptamers?
  Zhixia Liu,Tingjian Chen,Floyd E. Romesberg Chem. Sci., 2017,8, 8179-8182
• 5. Establishing empirical design rules of nucleic acid templates for the synthesis of silver nanoclusters with tunable photoluminescence and functionalities towards targeted bioimaging applications?
  Jason Y. C. Lim,Yong Yu,Guorui Jin,Kai Li,Yi Lu,Jianping Xie Nanoscale Adv., 2020,2, 3921-3932

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