Production Method 1

6168-72-5

61588-19-0

87905-97-3

Reaction Conditions

1.1 Solvents: Dichloromethane

Reference

S-acyl derivatives of benzothiazole-2-thiol: a convenient method for the synthesis of amides and carbamates

Lee, Joung Hee; et al, Bulletin of the Korean Chemical Society, 1997, 18(4), 442-444

Production Method 2

2749-11-3

87905-97-3

Reaction Conditions

1.1 Reagents: Pyridine Solvents: Tetrahydrofuran ;  cooled; overnight, rt
1.2 Reagents: Sodium hydroxide Solvents: Water ;  0.5 h, rt
1.3 Solvents: Water ;  pH 1
2.1 rt

Reference

Carbamate derivatives of felbamate as potential anticonvulsant agents

Kung, Ching-Hsin; et al, Medicinal Chemistry Research, 2010, 19(5), 498-513

Production Method 3

4132-86-9

87905-97-3

Reaction Conditions

1.1 Reagents: 1,1′-Carbonyldiimidazole Solvents: Dichloromethane ;  60 min, 0 °C; 15 min, 0 °C → -78 °C
1.2 Reagents: Diisobutylaluminum hydride Solvents: Toluene ;  110 min, 0 °C; 30 - 60 min, -78 °C
1.3 Reagents: Ethyl acetate ;  -78 °C

Reference

A rapid and efficient one-pot method for the reduction of N-protected α-amino acids to chiral α-amino aldehydes using CDI/DIBAL-H

Ivkovic, Jakov; et al, Organic & Biomolecular Chemistry, 2015, 13(42), 10456-10460

Production Method 4

61425-27-2

66674-16-6

87905-97-3

Reaction Conditions

1.1 rt

Reference

Carbamate derivatives of felbamate as potential anticonvulsant agents

Kung, Ching-Hsin; et al, Medicinal Chemistry Research, 2010, 19(5), 498-513

Production Method 5

149-30-4

87905-97-3

Reaction Conditions

1.1 Reagents: Triethylamine Solvents: Dichloromethane
1.2 -
2.1 Solvents: Dichloromethane

Reference

S-acyl derivatives of benzothiazole-2-thiol: a convenient method for the synthesis of amides and carbamates

Lee, Joung Hee; et al, Bulletin of the Korean Chemical Society, 1997, 18(4), 442-444

Production Method 6

35320-23-1

87905-97-3

Reaction Conditions

1.1 Reagents: Pyridine Solvents: Tetrahydrofuran ;  cooled; overnight, rt
1.2 Reagents: Sodium hydroxide Solvents: Water ;  0.5 h, rt
1.3 Solvents: Water ;  pH 1
2.1 rt

Reference

Carbamate derivatives of felbamate as potential anticonvulsant agents

Kung, Ching-Hsin; et al, Medicinal Chemistry Research, 2010, 19(5), 498-513

Cbz-DL-alaninol Raw materials

• Benzyl (1R)-2-Hydroxy-1-methylethylcarbamate
• 1,3-benzothiazole-2-thiol
• (2S)-2-aminopropan-1-ol
• d-Alaninol
• 2-aminopropan-1-ol
• 2-(((Benzyloxy)carbonyl)amino)propanoic acid
• (S)-Benzyl (1-Hydroxypropan-2-yl)carbamate
• Carbonothioic acid, S-2-benzothiazolyl O-(phenylmethyl) ester

Cbz-DL-alaninol Preparation Products

• Cbz-DL-alaninol (87905-97-3)

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• 61425-27-2(Benzyl (1R)-2-Hydroxy-1-methylethylcarbamate)
• 62471-40-3(2-(Cbz-amino)-2-methyl-1-propanol)
• 71819-51-7(N-Cbz-2-amino-1,3-propanediol)
• 137160-74-8(benzyl N-(1-hydroxybutan-2-yl)carbamate)
• 71812-11-8(N-Cbz-2-amino-1,3-propanediol)
• 66674-16-6((S)-Benzyl (1-Hydroxypropan-2-yl)carbamate)
• 102522-48-5(N-2-Hydroxy-1,1-bis(hydroxymethyl)ethylcarbamic Acid Phenylmethyl Ester)
• 149636-26-0(2-Oxazolidinone, 4-[(phenylmethoxy)methyl]-, (4R)-)
• 71811-26-2(Benzyl 1,3-Dihydroxypropan-2-ylcarbamate)
• 77987-49-6(N-(Benzyloxycarbonyl)ethanolamine)