Production Method 1

503417-51-4

873779-78-3

Reaction Conditions

1.1 Reagents: Cuprous chloride ;  1 h, rt

Reference

Mechanochemistry for facilitated access to N,N-diaryl NHC metal complexes

Beillard, Audrey; et al, New Journal of Chemistry, 2017, 41(3), 1057-1063

Production Method 2

503417-51-4

873779-78-3

Reaction Conditions

1.1 Reagents: Benzenethiol, copper(1+) salt (1:1) Solvents: Dichloromethane ;  2 h, reflux

Reference

Copper(I) thiophenolate in copper N-heterocyclic carbene preparation

Cisnetti, Federico; et al, Tetrahedron Letters, 2010, 51(40), 5226-5229

Production Method 3

141556-42-5

873779-78-3

Reaction Conditions

1.1 Reagents: Cuprous chloride Solvents: Tetrahydrofuran ;  1 h, rt

Reference

Chemistry Surrounding Monomeric Copper(I) Methyl, Phenyl, Anilido, Ethoxide, and Phenoxide Complexes Supported by N-Heterocyclic Carbene Ligands: Reactivity Consistent with Both Early and Late Transition Metal Systems

Goj, Laurel A.; et al, Inorganic Chemistry, 2006, 45(22), 9032-9045

Production Method 4

141556-45-8

873779-78-3

Reaction Conditions

1.1 Reagents: Copper oxide (Cu2O) Solvents: Dichloromethane ;  24 h, reflux

Reference

Mechanistic Elucidation of the Arylation of Non-Spectator N-Heterocyclic Carbenes at Copper Using a Combined Experimental and Computational Approach

Williams, Thomas J.; et al, Organometallics, 2015, 34(14), 3497-3507

Production Method 5

141556-45-8

873779-78-3

Reaction Conditions

1.1 Reagents: Copper oxide (Cu2O) Solvents: Dichloromethane

Reference

N-Propargylation and Copper(I)-Catalyzed Azide-Alkyne Cycloaddition as a Convenient Strategy for Directed Post-Synthetic Modification of 4-Oxo-1,4-Dihydrocinnoline Derivatives

Mikhaylov, Vladimir N.; et al, Chemistry of Heterocyclic Compounds (New York, 2020, 56(7), 915-922

Production Method 6

141556-42-5

873779-78-3

Reaction Conditions

1.1 Reagents: Copper oxide (Cu2O) Solvents: Water ;  24 h, reflux

Reference

Simple and versatile synthesis of copper and silver N-heterocyclic carbene complexes in water or organic solvents

Citadelle, Cecilia A.; et al, Dalton Transactions, 2010, 39(19), 4489-4491

Production Method 7

141556-42-5

873779-78-3

Reaction Conditions

1.1 Reagents: Cuprous chloride

Reference

Stereoselective Traceless Borylation-Allenation of Propargylic Epoxides: Dual Role of the Copper Catalyst

Jarava-Barrera, Carlos; et al, Chemistry - A European Journal, 2017, 23(69), 17478-17481

Chloro(1,3-dimesitylimidazol-2-ylidene)copper(I) Raw materials

• Silver, chloro[1,3-dihydro-1,3-bis(2,4,6-trimethylphenyl)-2H-imidazol-2-ylidene]-
• 1,3-Dimesitylimidazolium chloride
• 1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene

Chloro(1,3-dimesitylimidazol-2-ylidene)copper(I) Preparation Products

• Chloro(1,3-dimesitylimidazol-2-ylidene)copper(I) (873779-78-3)

• 1. Fe/S-Catalyzed synthesis of 2-benzoylbenzoxazoles and 2-quinolylbenzoxazoles via redox condensation of o-nitrophenols with acetophenones and methylquinolines?
  Thi Thu Tram Nguyen,Thanh Binh Nguyen Org. Biomol. Chem., 2021,19, 6015-6020
• 2. Embedding heteroatoms: an effective approach to create porphyrin-based functional materials
  Norihito Fukui,Keisuke Fujimoto,Hideki Yorimitsu,Atsuhiro Osuka Dalton Trans., 2017,46, 13322-13341
• 3. Excited state potential energy surfaces and their interactions in FeIVO active sites
  Shaun D. Wong,Edward I. Solomon Dalton Trans., 2014,43, 17567-17577
• 4. Emerging 2D hybrid nanomaterials: towards enhanced sensitive and selective conductometric gas sensors at room temperature
  Hanie Hashtroudi,Ian D. R. Mackinnon J. Mater. Chem. C, 2020,8, 13108-13126
• 5. Elusive 2-aminofuran Diels–Alder substrates for a straightforward synthesis of polysubstituted anilines?
  Ana G. Neo,Ana Bornadiego,Jesús Díaz,Stefano Marcaccini,Carlos F. Marcos Org. Biomol. Chem., 2013,11, 6546-6555

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Aniline and substituted anilines
• Other Chemical Reagents

• 744208-43-3(Copper,[1,3-bis(2,6-dimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene]chloro-)
• 1337921-07-9(Copper, [1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]-1,3-dihydro-2H-imidazol-2-ylidene]chloro-)
• 578743-87-0([1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]-chloro-copper)
• 332062-08-5(Fmoc-S-3-amino-4,4-diphenyl-butyric acid)
• 1270529-38-8(1,2,3,4,5,6-Hexahydro-[2,3]bipyridinyl-6-ol)
• 2680771-01-9(4-cyclopentyl-3-{(prop-2-en-1-yloxy)carbonylamino}butanoic acid)
• 2098070-20-1(2-(3-(Pyridin-3-yl)-1H-pyrazol-1-yl)acetimidamide)
• 1444113-98-7(N-(3-cyanothiolan-3-yl)-2-[(2,2,2-trifluoroethyl)sulfanyl]pyridine-4-carboxamide)
• 941977-17-9(N'-(3-chloro-2-methylphenyl)-N-2-(dimethylamino)-2-(naphthalen-1-yl)ethylethanediamide)
• 2138166-62-6(2,2-Difluoro-3-[methyl(2-methylbutyl)amino]propanoic acid)