Cas no 864943-22-6 (864943-22-6)

864943-22-6 structure

Product Name:864943-22-6

CAS No:864943-22-6

MF:C₄₈H₂₉O₄P

MW:700.715233564377

MDL:MFCD12546016

CID:1851942

PubChem ID:329762222

Update Time:2025-09-27

864943-22-6 Chemical and Physical Properties

Names and Identifiers

- (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide
- (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
- 1043567-32-3
- (11bS)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-oxide
- D97768
- CS-0084541
- (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-oxide
- 4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
- DTXSID70470690
- 10.14272/BVICVEIKBNVROI-UHFFFAOYSA-N.1
- (11bS)-4-Hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
- 13-hydroxy-10,16-bis(phenanthren-9-yl)-12,14-dioxa-13??-phosphapentacyclo[13.8.0.0(2),(1)(1).0(3),?.0(1)?,(2)(3)]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-one
- (S)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
- 13-hydroxy-10,16-di(phenanthren-9-yl)-12,14-dioxa-13lambda5-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
- doi:10.14272/BVICVEIKBNVROI-UHFFFAOYSA-N.1
- (11bR)-4-hydroxy-2,6-di(phenanthren-9-yl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide
- (11bS)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
- 864943-22-6
- (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
- CS-0030474
- (R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate
- 13-hydroxy-10,16-di(phenanthren-9-yl)-12,14-dioxa-13$l^{5-phosphapentacyclo[13.8.0.0^{2,11.0^{3,8.0^{18,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
- D72570
- MFCD12546016
- (11Br)-2,6-di-9-phenanthrenyl-4-hydroxy
- (R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate
- 4-Hydroxy-2,6-di(phenanthren-9-yl)-4H-4lambda~5~-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-one
- SCHEMBL4753115
- MDL： MFCD12546016
- Inchi： 1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
- InChI Key： BVICVEIKBNVROI-UHFFFAOYSA-N
- SMILES： O=P1(OC2C(C3C4C(=CC=CC=4)C4C(=CC=CC=4)C=3)=CC3C(C=2C2C(=C(C4C5C(=CC=CC=5)C5C(=CC=CC=5)C=4)C=C4C=2C=CC=C4)O1)=CC=CC=3)O

Computed Properties

Exact Mass: 700.18034640g/mol
Monoisotopic Mass: 700.18034640g/mol
Isotope Atom Count: 0
Hydrogen Bond Donor Count: 1
Hydrogen Bond Acceptor Count: 4
Heavy Atom Count: 53
Rotatable Bond Count: 2
Complexity: 1250
Covalently-Bonded Unit Count: 1
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count : 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
XLogP3: 13.1
Topological Polar Surface Area: 55.8?2

Experimental Properties

Melting Point: 390-400?°C
Optical Activity: [α]22/D ?44.0°, c =?1 in DMSO

864943-22-6 Security Information

Hazardous Material transportation number：NONH for all modes of transport
WGK Germany：3
Storage Condition：?20°C

864943-22-6 Pricemore >>

Related Categories	No.	Product Name	Cas No.	Purity	Specification	Price	update time
XI GE MA AO DE LI QI （ SHANG HAI ） MAO YI Co., Ltd.	700665-100MG	864943-22-6	864943-22-6		100MG	￥2883.43	2022-02-24
Apollo Scientific	OR52282-1g	(R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate	864943-22-6	98%	1g	￡517.00	2025-02-20
abcr	AB496729-50 mg	(R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate; .	864943-22-6		50mg	€279.00	2023-07-10
SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd.	lj0238-100mg	864943-22-6	864943-22-6	98%,99%e.e.	100mg	￥1860.0	2024-07-19
SU ZHOU XIN JIA YUAN HUA XUE Technology Co., Ltd.	lj0238-50mg	864943-22-6	864943-22-6	98%,99%e.e.	50mg	￥1100.0	2024-07-19
SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd.	B12955-100mg	(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin	864943-22-6	98%	100mg	￥648.0	2022-04-28
SHANG HAI JI ZHI SHENG HUA Technology Co., Ltd.	B12955-50mg	(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin	864943-22-6	98%	50mg	￥1768.0	2022-04-28
Apollo Scientific	OR52282-100mg	(R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate	864943-22-6	98%	100mg	￡57.00	2025-02-20
Apollo Scientific	OR52282-250mg	(R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate	864943-22-6	98%	250mg	￡141.00	2025-02-20
Apollo Scientific	OR52282-5g	(R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate	864943-22-6	98%	5g	￡1587.00	2025-02-20

864943-22-6 Production Method

Production Method 1

1058734-56-7

864943-22-6

Reaction Conditions

1.1 Reagents: Phosphorus oxychloride Solvents: Pyridine ; 80 °C; 12 h, rt
1.2 Reagents: Hydrochloric acid Solvents: Water ; 3 h, reflux

Reference

Hypercrosslinking chiral Bronsted acids into porous organic polymers for efficient heterogeneous asymmetric organosynthesis

Zhang, Yuwei; et al, Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2021, 9(45), 25369-25373

Production Method 2

18531-94-7

864943-22-6

Reaction Conditions

Reference

Palladium(0)-catalyzed asymmetric C(sp3)-H arylation using a chiral binol-derived phosphate and an achiral ligand

Yang, Lei; et al, Chemical Science, 2017, 8(2), 1344-1349

Production Method 3

864943-22-6

Reaction Conditions

1.1 Reagents: Hydrochloric acid Solvents: 1,4-Dioxane , Water ; rt → 98 °C; 12 h, 98 - 100 °C; 100 °C → rt
1.2 Reagents: Sodium bicarbonate Solvents: Water ; neutralized, rt
2.1 Reagents: Phosphorus oxychloride Solvents: Pyridine ; 15 min, rt; 12 h, 60 °C; 60 °C → rt
2.2 Reagents: Water ; rt; 5 h, rt
2.3 Reagents: Hydrochloric acid Solvents: Water ; rt; 30 min, rt

Reference

(R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate

Hu, Wenhao; et al, Organic Syntheses, 2011, 88, 406-417

Production Method 4

68572-87-2

189518-78-3

864943-22-6

Reaction Conditions

1.1 Reagents: Barium hydroxide Catalysts: Tetrakis(triphenylphosphine)palladium Solvents: 1,4-Dioxane , Water ; rt → 75 °C; 24 h, 75 - 80 °C
2.1 Reagents: Hydrochloric acid Solvents: 1,4-Dioxane , Water ; rt → 98 °C; 12 h, 98 - 100 °C; 100 °C → rt
2.2 Reagents: Sodium bicarbonate Solvents: Water ; neutralized, rt
3.1 Reagents: Phosphorus oxychloride Solvents: Pyridine ; 15 min, rt; 12 h, 60 °C; 60 °C → rt
3.2 Reagents: Water ; rt; 5 h, rt
3.3 Reagents: Hydrochloric acid Solvents: Water ; rt; 30 min, rt

Reference

(R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate

Hu, Wenhao; et al, Organic Syntheses, 2011, 88, 406-417

Production Method 5

173831-50-0

864943-22-6

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ; 30 min, 2 - 3 °C; 3 h, rt; cooled
1.2 Reagents: Iodine Solvents: Tetrahydrofuran ; 3 min, cooled; 20 h, rt
1.3 Reagents: Sodium thiosulfate , Ammonium chloride Solvents: Water ; rt
2.1 Reagents: Barium hydroxide Catalysts: Tetrakis(triphenylphosphine)palladium Solvents: 1,4-Dioxane , Water ; rt → 75 °C; 24 h, 75 - 80 °C
3.1 Reagents: Hydrochloric acid Solvents: 1,4-Dioxane , Water ; rt → 98 °C; 12 h, 98 - 100 °C; 100 °C → rt
3.2 Reagents: Sodium bicarbonate Solvents: Water ; neutralized, rt
4.1 Reagents: Phosphorus oxychloride Solvents: Pyridine ; 15 min, rt; 12 h, 60 °C; 60 °C → rt
4.2 Reagents: Water ; rt; 5 h, rt
4.3 Reagents: Hydrochloric acid Solvents: Water ; rt; 30 min, rt

Reference

(R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate

Hu, Wenhao; et al, Organic Syntheses, 2011, 88, 406-417

Production Method 6

1058734-56-7

864943-22-6

Reaction Conditions

1.1 Reagents: Phosphorus oxychloride Solvents: Pyridine ; 15 min, rt; 12 h, 60 °C; 60 °C → rt
1.2 Reagents: Water ; rt; 5 h, rt
1.3 Reagents: Hydrochloric acid Solvents: Water ; rt; 30 min, rt

Reference

(R)-3,3'-Bis(9-phenanthryl)-1,1'-binaphthalene-2,2'-diyl hydrogen phosphate

Hu, Wenhao; et al, Organic Syntheses, 2011, 88, 406-417

Production Method 7

864943-22-6

Reaction Conditions

1.1 Reagents: Hydrochloric acid Solvents: 1,4-Dioxane ; 12 h, rt → 60 °C; 60 °C → rt
1.2 Reagents: Sodium bicarbonate Solvents: Water
2.1 Reagents: Phosphorus oxychloride Solvents: Pyridine ; 80 °C; 12 h, rt
2.2 Reagents: Hydrochloric acid Solvents: Water ; 3 h, reflux

Reference

Hypercrosslinking chiral Bronsted acids into porous organic polymers for efficient heterogeneous asymmetric organosynthesis

Zhang, Yuwei; et al, Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2021, 9(45), 25369-25373

Production Method 8

68572-87-2

189518-78-3

864943-22-6

Reaction Conditions

1.1 Reagents: Sodium carbonate Catalysts: Tetrakis(triphenylphosphine)palladium Solvents: 1,2-Dimethoxyethane , Water ; 10 h, rt → reflux
2.1 Reagents: Hydrochloric acid Solvents: 1,4-Dioxane ; 12 h, rt → 60 °C; 60 °C → rt
2.2 Reagents: Sodium bicarbonate Solvents: Water
3.1 Reagents: Phosphorus oxychloride Solvents: Pyridine ; 80 °C; 12 h, rt
3.2 Reagents: Hydrochloric acid Solvents: Water ; 3 h, reflux

Reference

Hypercrosslinking chiral Bronsted acids into porous organic polymers for efficient heterogeneous asymmetric organosynthesis

Zhang, Yuwei; et al, Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2021, 9(45), 25369-25373

Production Method 9

142128-92-5

864943-22-6

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Diethyl ether ; 4 h, rt; rt → -78 °C
1.2 Reagents: Iodine Solvents: Tetrahydrofuran ; -78 °C → rt; overnight, rt
1.3 Reagents: Ammonium chloride Solvents: Water
2.1 Reagents: Sodium carbonate Catalysts: Tetrakis(triphenylphosphine)palladium Solvents: 1,2-Dimethoxyethane , Water ; 10 h, rt → reflux
3.1 Reagents: Hydrochloric acid Solvents: 1,4-Dioxane ; 12 h, rt → 60 °C; 60 °C → rt
3.2 Reagents: Sodium bicarbonate Solvents: Water
4.1 Reagents: Phosphorus oxychloride Solvents: Pyridine ; 80 °C; 12 h, rt
4.2 Reagents: Hydrochloric acid Solvents: Water ; 3 h, reflux

Reference

Hypercrosslinking chiral Bronsted acids into porous organic polymers for efficient heterogeneous asymmetric organosynthesis

Zhang, Yuwei; et al, Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2021, 9(45), 25369-25373

Production Method 10

18531-94-7

864943-22-6

Reaction Conditions

1.1 Reagents: Sodium hydride Solvents: Tetrahydrofuran ; 1 h, 0 °C
1.2 0 °C; 10 min, 0 °C
1.3 Reagents: Ammonium chloride Solvents: Water
2.1 Reagents: Butyllithium Solvents: Diethyl ether ; 4 h, rt; rt → -78 °C
2.2 Reagents: Iodine Solvents: Tetrahydrofuran ; -78 °C → rt; overnight, rt
2.3 Reagents: Ammonium chloride Solvents: Water
3.1 Reagents: Sodium carbonate Catalysts: Tetrakis(triphenylphosphine)palladium Solvents: 1,2-Dimethoxyethane , Water ; 10 h, rt → reflux
4.1 Reagents: Hydrochloric acid Solvents: 1,4-Dioxane ; 12 h, rt → 60 °C; 60 °C → rt
4.2 Reagents: Sodium bicarbonate Solvents: Water
5.1 Reagents: Phosphorus oxychloride Solvents: Pyridine ; 80 °C; 12 h, rt
5.2 Reagents: Hydrochloric acid Solvents: Water ; 3 h, reflux

Reference

Hypercrosslinking chiral Bronsted acids into porous organic polymers for efficient heterogeneous asymmetric organosynthesis

Zhang, Yuwei; et al, Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2021, 9(45), 25369-25373

864943-22-6 Raw materials

864943-22-6 Preparation Products

864943-22-6 (864943-22-6)

864943-22-6 Related Literature

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Cas no 864943-22-6 (864943-22-6)

864943-22-6 Chemical and Physical Properties

Names and Identifiers

Computed Properties

Experimental Properties

864943-22-6 Security Information

864943-22-6 Pricemore >>

864943-22-6 Production Method

Production Method 1

Production Method 2

Production Method 3

Production Method 4

Production Method 5

Production Method 6

Production Method 7

Production Method 8

Production Method 9

Production Method 10

864943-22-6 Raw materials

864943-22-6 Preparation Products

864943-22-6 Related Literature

Related Categories

864943-22-6 (864943-22-6) Related Products