Production Method 1

61676-62-8

926653-52-3

863992-56-7

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ,  Hexane ;  1 h, -78 °C; 1 h, -78 °C; -78 °C → rt; 1 h, rt
1.2 Reagents: Sodium bicarbonate Solvents: Water ;  rt

Reference

Diborylated Magnesium Anthracene as Precursor for B2H5--Bridged 9,10-Dihydroanthracene

Pospiech, Steffen; et al, Chemistry - A European Journal, 2015, 21(22), 8229-8236

Production Method 2

523-27-3

73183-34-3

863992-56-7

Reaction Conditions

1.1 Reagents: Potassium acetate Catalysts: Palladium diacetate Solvents: Dimethylformamide ;  overnight, 80 °C

Reference

B-N Lewis Pair Functionalization of Anthracene: Structural Dynamics, Optoelectronic Properties, and O2 Sensitization

Liu, Kanglei; et al, Journal of the American Chemical Society, 2017, 139(50), 18170-18173

Production Method 3

605-48-1

73183-34-3

863992-56-7

Reaction Conditions

1.1 Reagents: Lithium tert-butoxide Catalysts: Iron(III) acetylacetonate Solvents: Toluene ,  Tetrahydrofuran ;  16 h, 130 °C; 130 °C → rt
1.2 Reagents: Ammonium chloride Solvents: Water ;  rt

Reference

Iron-catalyzed borylation of aryl chlorides in the presence of potassium t-butoxide

Yoshida, Takumi; et al, ACS Catalysis, 2017, 7(5), 3199-3203

Production Method 4

523-27-3

76-09-5

863992-56-7

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ,  Hexane ;  30 min, -78 °C; 2 h, -78 °C
1.2 Reagents: Triethyl borate ;  10 min, -78 °C; 19 h, -78 °C
1.3 Reagents: Hydrochloric acid Solvents: Water ;  -78 °C; 4 h, rt
1.4 Reagents: Sodium sulfate Catalysts: Acetic acid Solvents: Tetrahydrofuran ;  2 d, rt

Reference

Multipoint Recognition of Ditopic Aromatic Guest Molecules via Ag-π Interactions within a Dimetal Macrocycle

Omoto, Kenichiro; et al, Journal of the American Chemical Society, 2014, 136(52), 17946-17949

Production Method 5

863992-56-7

Reaction Conditions

1.1 Reagents: Bromine Solvents: Chloroform ;  25 °C; 5 h, 25 °C
2.1 Reagents: Potassium acetate Catalysts: Palladium diacetate Solvents: Dimethylformamide ;  12 h, 80 °C

Reference

Copolymers of 4-thieno[3,2-b]thiophen-3-ylbenzonitrile with anthracene and biphenyl; synthesis, characterization, electronic, optical, and thermal properties

Isci, Recep ; et al, Journal of Polymer Science (Hoboken, 2021, 59(1), 117-123

Production Method 6

863992-56-7

Reaction Conditions

1.1 Reagents: Bromine Solvents: Chloroform ;  5 h, rt
2.1 Reagents: Potassium acetate Catalysts: Palladium(2+) Solvents: Dimethylformamide ;  80 °C

Reference

Polymers of 4-thieno[3,2-b]thiophen-3-ylbenzonitrile with anthracene and biphenyl: their electronic and optoelectronic properties

Isci, Recep; et al, International Electronic Conference on Synthetic Organic Chemistry, 2019, 1, 1-9

Production Method 7

863992-56-7

Reaction Conditions

1.1 Reagents: Bromine Solvents: Chloroform ;  rt; 4 h, rt
2.1 Reagents: Potassium acetate Catalysts: Palladium diacetate Solvents: Dimethylformamide ;  7 h, 80 °C

Reference

Synthesis of monodisperse oligocarbazoles-functionalized anthracenes with intense blue-emitting

Zhan, Yong; et al, Tetrahedron Letters, 2013, 54(6), 594-599

Anthracene-9,10-diboronic acid bis(pinacol) ester Raw materials

• 9,10-Dibromoanthracene
• 2,3-Dimethylbutane-2,3-diol
• 9,10-Dichloroanthracene
• 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Bis(pinacolato)diborane
• 1,3,2-Dioxaborolane, 2-(10-bromo-9-anthracenyl)-4,4,5,5-tetramethyl-

Anthracene-9,10-diboronic acid bis(pinacol) ester Preparation Products

• Anthracene-9,10-diboronic acid bis(pinacol) ester (863992-56-7)

• 1. Embedding heteroatoms: an effective approach to create porphyrin-based functional materials
  Norihito Fukui,Keisuke Fujimoto,Hideki Yorimitsu,Atsuhiro Osuka Dalton Trans., 2017,46, 13322-13341
• 2. Fast synthesis of copper nanoclusters through the use of hydrogen peroxide additive and their application for the fluorescence detection of Hg2+ in water samples?
  Liao Xiaoqing,Li Ruiyi,Li Zaijun,Sun Xiulan,Wang Zhouping,Liu Junkang New J. Chem., 2015,39, 5240-5248
• 3. Excellent peroxidase mimicking property of CuO/Pt nanocomposites and their application as an ascorbic acid sensor?
  Xinhuan Wang,Shuangfei Cai,Cui Qi Analyst, 2017,142, 2500-2506
• 4. Evidence of rutile-to-anatase photo-induced electron transfer in mixed-phase TiO2 by solid-state NMR spectroscopy?
  Weili Dai,Guangjun Wu,Michael Hunger Chem. Commun., 2015,51, 13779-13782
• 5. Fate of single walled carbon nanotubes in wetland ecosystems?
  Joseph H. Bisesi,Tara Sabo-Attwood Environ. Sci.: Nano, 2014,1, 574-583

• Solvents and Organic Chemicals Organic Compounds Benzenoids Anthracenes Anthracenes
• Solvents and Organic Chemicals Organic Compounds Benzenoids Anthracenes
• Other Chemical Reagents Derivatization Reagents
• Solvents and Organic Chemicals Organic Compounds Acids/Esters

• 256652-04-7(2-Naphthaleneboronic Acid Pinacol Ester)
• 888950-09-2(4,4,5,5-Tetramethyl-2-(4-pyrenyl)-1,3,2-dioxaborolane)
• 709022-63-9(9-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)anthracene)
• 676578-20-4(1,3,2-Dioxaborolane, 2-(2-anthracenyl)-4,4,5,5-tetramethyl-)
• 68716-52-9(Naphthalene-1-boronic Acid Pinacol Ester)
• 853377-11-4(1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(2-pyrenyl)-)
• 688756-58-3(pyrene-2,7-(Bpin)2)
• 349666-24-6(4,4,5,5-Tetramethyl-2-(pyren-1-yl)-1,3,2-dioxaborolane)
• 68572-88-3(1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(9-phenanthrenyl)-)
• 950761-81-6(4,4,5,5-Tetramethyl-2-(perylen-3-yl)-1,3,2-dioxaborolane)