Production Method 1

148-53-8

86232-54-4

Reaction Conditions

1.1 Reagents: Hydrogen Catalysts: Palladium Solvents: Ethyl acetate
2.1 Reagents: N-Bromosuccinimide Solvents: Acetic acid

Reference

Intermolecular Diels-Alder Reactions of Brominated Masked o-Benzoquinones with Electron-Deficient Dienophiles. A Detour Method to Synthesize Bicyclo[2.2.2]octenones from 2-Methoxyphenols

Lai, Chien-Hsun; et al, Journal of Organic Chemistry, 2002, 67(18), 6493-6502

Production Method 2

2896-67-5

86232-54-4

Reaction Conditions

1.1 Reagents: N-Bromosuccinimide Solvents: Acetic acid ;  24 h, 23 °C

Reference

The Discovery of a Novel Route to Highly Substituted α-Tropolones Enables Expedient Entry to the Core of the Gukulenins

Kats-Kagan, Roman; et al, Organic Letters, 2015, 17(8), 2030-2033

Production Method 3

2896-67-5

86232-54-4

Reaction Conditions

1.1 Reagents: N-Bromosuccinimide Solvents: Acetic acid

Reference

Intermolecular Diels-Alder Reactions of Brominated Masked o-Benzoquinones with Electron-Deficient Dienophiles. A Detour Method to Synthesize Bicyclo[2.2.2]octenones from 2-Methoxyphenols

Lai, Chien-Hsun; et al, Journal of Organic Chemistry, 2002, 67(18), 6493-6502

Production Method 4

148-53-8

86232-54-4

Reaction Conditions

1.1 Reagents: Hydrogen ,  Hydrochloric acid Catalysts: Palladium Solvents: Methanol ,  Water ;  24 h, 23 °C
2.1 Reagents: N-Bromosuccinimide Solvents: Acetic acid ;  24 h, 23 °C

Reference

The Discovery of a Novel Route to Highly Substituted α-Tropolones Enables Expedient Entry to the Core of the Gukulenins

Kats-Kagan, Roman; et al, Organic Letters, 2015, 17(8), 2030-2033

4-Bromo-2-methoxy-6-methylphenol Raw materials

• 2-Methoxy-6-methylphenol
• 2-Hydroxy-3-methoxybenzaldehyde

4-Bromo-2-methoxy-6-methylphenol Preparation Products

• 4-Bromo-2-methoxy-6-methylphenol (86232-54-4)

• 1. Dissociative electron attachment to HGaF4 Lewis–Br?nsted superacid
  Marcin Czapla,Jack Simons Phys. Chem. Chem. Phys., 2018,20, 21739-21745
• 2. Exciplex emission from the mixed dimer of naphthalene and 2-cyanonaphthalene in a supersonic jet
  Aloke Das,K. K. Mahato,Chayan K. Nandi,Tapas Chakraborty,Shridhar R. Gadre,Nikhil A. Gokhale Phys. Chem. Chem. Phys., 2002,4, 2162-2168
• 3. Establishing new scaling relations on two-dimensional MXenes for CO2 electroreduction?
  Albertus D. Handoko,Khoong Hong Khoo,Teck Leong Tan,Hongmei Jin,Zhi Wei Seh J. Mater. Chem. A, 2018,6, 21885-21890
• 4. Evolution in surface coverage of CH3NH3PbI3?XClXvia heat assisted solvent vapour treatment and their effects on photovoltaic performance of devices
  Dhirendra K. Chaudhary,Pramendra Kumar,Lokendra Kumar RSC Adv., 2016,6, 94731-94738
• 5. Evidence of rutile-to-anatase photo-induced electron transfer in mixed-phase TiO2 by solid-state NMR spectroscopy?
  Weili Dai,Guangjun Wu,Michael Hunger Chem. Commun., 2015,51, 13779-13782

• Solvents and Organic Chemicals Organic Compounds Benzenoids Phenols Methoxyphenols

• 5034-74-2(5-Bromo-2-hydroxy-3-methoxybenzaldehyde)
• 35090-64-3(4-Bromo-2-(hydroxymethyl)-6-methoxyphenol)
• 68278-85-3(Benzene, 1-bromo-2,3-dimethoxy-5-methyl-)
• 887582-87-8(2-(aminomethyl)-4-bromo-6-methoxyphenol)
• 86232-34-0((5-Bromo-2,3-dimethoxyphenyl)methanol)
• 105103-87-5(Phenol, 5-bromo-2,4-dimethoxy-3-methyl-)
• 201471-78-5(Benzene, 1-bromo-2,3-dimethoxy-4-methyl-)
• 58005-60-0(Benzene, 5-bromo-1,2-dimethoxy-3-methyl-)
• 1262003-53-1(3-Bromo-5-(3,4-dimethoxyphenyl)phenol)
• 74866-17-4(1-Bromo-3,4-dimethoxy-2-methylbenzene)