Production Method 1

18368-64-4

1765-93-1

85237-65-6

Reaction Conditions

1.1 Reagents: Potassium carbonate Catalysts: Tetrakis(triphenylphosphine)palladium Solvents: Ethanol ,  Toluene ,  Water ;  48 h, reflux

Reference

Synthesis of facial cyclometalated iridium(III) complexes triggered by tripodal ligands

Moriuchi, Toshiyuki; Mao, Lisheng; Wu, Hsyueh-Liang; Ohmura, Satoshi D.; Watanabe, Masami; et al, Dalton Transactions, 2012, 41(31), 9519-9525

Production Method 2

26031-63-0

85237-65-6

Reaction Conditions

1.1 Reagents: Ammonium acetate Solvents: Methanol ;  12 h, 60 °C

Reference

Accelerated luminophor discovery through combinatorial synthesis

Lowry, Michael S.; Hudson, William R.; Pascal, Robert A. Jr.; Bernhard, Stefan, Journal of the American Chemical Society, 2004, 126(43), 14129-14135

Production Method 3

26031-63-0

85237-65-6

Reaction Conditions

1.1 Reagents: Ammonium acetate Solvents: Methanol ;  rt → 65 °C; overnight, 65 °C

Reference

Highly Fluorinated Ir(III)-2,2':6',2''-Terpyridine-Phenylpyridine-X Complexes via Selective C-F Activation: Robust Photocatalysts for Solar Fuel Generation and Photoredox Catalysis

Porras, Jonathan A.; Mills, Isaac N.; Transue, Wesley J.; Bernhard, Stefan, Journal of the American Chemical Society, 2016, 138(30), 9460-9472

Production Method 4

26031-63-0

85237-65-6

Reaction Conditions

1.1 Reagents: Methacrolein ,  Ammonium acetate Solvents: Methanol ;  18 h, reflux

Reference

Heteroleptic cyclometalated iridium(III) complexes

Tinker, Leonard L.; McDaniel, Neal D.; Cline, Eric D.; Bernhard, Stefan; Putman, Ross D.; et al, Inorganic Syntheses, 2010, 35, 168-173

Production Method 5

370878-58-3

85237-65-6

27012-22-2

Reaction Conditions

1.1 Reagents: Lithium aluminum hydride Catalysts: Niobium pentachloride Solvents: 1,2-Dimethoxyethane ;  rt → reflux; 6.5 h, reflux; reflux → 0 °C
1.2 Reagents: Water ;  0 °C

Reference

Hydrodefluorinations by low-valent niobium catalyst

Fuchibe, Kohei; Ohshima, Yoshitaka; Mitomi, Ken; Akiyama, Takahiko, Journal of Fluorine Chemistry, 2007, 128(10), 1158-1167

2-(4-Fluorophenyl)-5-methylpyridine Raw materials

• 2-(4-Fluorophenyl)-5-(trifluoromethyl)pyridine
• 2-Chloro-5-methylpyridine
• 4-Fluorobenzeneboronic acid

2-(4-Fluorophenyl)-5-methylpyridine Preparation Products

• 2-(4-Fluorophenyl)-5-methylpyridine (85237-65-6)
• 5-Methyl-2-phenylpyridine (27012-22-2)

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• 5. Empowering microfluidics by micro-3D printing and solution-based mineral coating?
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• Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Pyridines and derivatives Phenylpyridines

• 101419-76-5(Pyridine,2-(4-fluorophenyl)-3-methyl-)
• 58861-54-4(Pyridine, 2-(3-fluorophenyl)-)
• 58861-53-3(2-(4-Fluorophenyl)pyridine)
• 222551-24-8(2-(4-Fluorophenyl)-4-methylpyridine)
• 106793-22-0(Pyridine, 5-ethyl-2-(4-fluorophenyl)-)
• 33777-85-4(Pyridine, 2,6-bis(4-fluorophenyl)-)
• 862201-39-6(1H-Pyrrole,2-(4-fluorophenyl)-4-phenyl-)
• 387827-69-2(Pyridine,2-(4-fluorophenyl)-6-methyl-)
• 1498-83-5(Pyridine,4-(4-fluorophenyl)-2,6-diphenyl-)
• 173960-43-5(2,2'-Bipyridine, 5-(4-fluorophenyl)-)