Production Method 1

1461-22-9

69249-61-2

851853-51-5

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ,  Hexane ;  -78 °C; 0.5 h, -78 °C
1.2 -78 °C; 12 h, rt
1.3 Reagents: Potassium fluoride Solvents: Water ;  rt

Reference

Planar and Twisted Molecular Structure Leads to the High Brightness of Semiconducting Polymer Nanoparticles for NIR-IIa Fluorescence Imaging

Liu, Shunjie ; Ou, Hanlin; Li, Yuanyuan ; Zhang, Haoke ; Liu, Junkai; et al, Journal of the American Chemical Society, 2020, 142(35), 15146-15156

Production Method 2

1461-22-9

1693-86-3

851853-51-5

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Diethyl ether ,  Hexane ;  0 °C; 1 h, 0 °C; 0 °C → -78 °C
1.2 -78 °C → rt; 12 h, rt

Reference

Random copolymers consisting of dithienylcyclopentadienone, thiophene and benzothiadiazole for bulk heterojunction solar cells

Ranjith, K.; Swathi, S. K.; Malavika, A.; Ramamurthy, Praveen C., Solar Energy Materials & Solar Cells, 2012, 105, 263-271

Production Method 3

1461-22-9

69249-61-2

851853-51-5

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ,  Hexane ;  -78 °C; 30 min, -78 °C; 30 min, -78 °C → rt
1.2 16 h, rt
1.3 Reagents: Ammonium chloride Solvents: Water

Reference

4H-1,2,6-Thiadiazin-4-one-containing small molecule donors and additive effects on their performance in solution-processed organic solar cells

Hermerschmidt, Felix; Kalogirou, Andreas S.; Min, Jie; Zissimou, Georgia A.; Tuladhar, Sachetan M.; et al, Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 2015, 3(10), 2358-2365

Production Method 4

1461-22-9

69249-61-2

851853-51-5

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ,  Hexane ;  -78 °C; 0.5 h, -78 °C
1.2 12 h, rt
1.3 Reagents: Potassium fluoride Solvents: Water ;  rt

Reference

Constitutional Isomerization Enables Bright NIR-II AIEgen for Brain-Inflammation Imaging

Liu, Shunjie; Chen, Chao; Li, Yuanyuan; Zhang, Haoke; Liu, Junkai; et al, Advanced Functional Materials, 2020, 30(7),

Production Method 5

1461-22-9

69249-61-2

851853-51-5

Reaction Conditions

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ;  -78 °C; 1 h, -78 °C
1.2 12 h, rt
1.3 Reagents: Potassium fluoride Solvents: Water

Reference

Constitutional isomerization enables ultrabright NIR-II AIEgen for brain-inflammation imaging

Liu, Shunjie; Chen, Chao; Li, Yuanyuan; Zhang, Haoke; Liu, Junkai; et al, ChemRxiv, 2019, 1, 1-10

Stannane, tributyl(3-hexyl-2-thienyl)- Raw materials

• tributyl(chloro)stannane
• 2-Bromo-3-hexylthiophene
• 3-Hexylthiophene

Stannane, tributyl(3-hexyl-2-thienyl)- Preparation Products

• Stannane, tributyl(3-hexyl-2-thienyl)- (851853-51-5)

• 1. Esterase-responsive polymeric prodrug-based tumor targeting nanoparticles for improved anti-tumor performance against colon cancer?
  Gang Pan,Yi-jie Bao,Jie Xu,Tao Liu,Cheng Liu,Yan-yan Qiu,Xiao-jing Shi,Hui Yu,Ting-ting Jia,Xia Yuan,Ze-ting Yuan,Yi-jun Cao RSC Adv., 2016,6, 42109-42119
• 2. Evolution of calcium phosphate precipitation in hanging drop vapor diffusion by in situRaman microspectroscopy
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• 4. Fe3O4 nanoclusters highly dispersed on a porous graphene support as an additive for improving the hydrogen storage properties of LiBH4?
  Guang Xu,Wei Zhang,Ying Zhang,Xiaoxia Zhao,Ping Wen,Di Ma RSC Adv., 2018,8, 19353-19361
• 5. Establishing empirical design rules of nucleic acid templates for the synthesis of silver nanoclusters with tunable photoluminescence and functionalities towards targeted bioimaging applications?
  Jason Y. C. Lim,Yong Yu,Guorui Jin,Kai Li,Yi Lu,Jianping Xie Nanoscale Adv., 2020,2, 3921-3932

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