Production Method 1

851615-07-1

Reaction Conditions

1.1 Reagents: Boron tribromide Solvents: Dichloromethane ;  0 °C

Reference

Axially Chiral N,N-Ligand-Promoted Pd-Catalyzed Enantioselective Allylic Amination and Alkylation

Liu, Miaomiao; Zhang, Xiaotao; Bao, Rongrong; Xiao, Fangtao; Cen, Shouyi; et al, Organic Letters, 2023, 25(32), 5946-5950

Production Method 2

851615-07-1

Reaction Conditions

1.1 Reagents: Hydrochloric acid Solvents: 1,4-Dioxane ,  Water

Reference

Synthesis and Structural Aspects of N-Triflylphosphoramides and Their Calcium Salts-Highly Acidic and Effective Bronsted Acids

Rueping, Magnus; Nachtsheim, Boris J.; Koenigs, Rene M.; Ieawsuwan, Winai, Chemistry - A European Journal, 2010, 16(44), 13116-13126

Production Method 3

851615-07-1

Reaction Conditions

1.1 Reagents: Boron tribromide Solvents: Dichloromethane ;  0 °C

Reference

Novel Axially Chiral Ligand-Enabled Copper-Catalyzed Asymmetric Oxidative Coupling of 2-Naphthols for the Synthesis of 6,6'-Disubstituted BINOLs

Wang, Pengyang; Cen, Shouyi; Gao, Jun; Shen, Ahui; Zhang, Zhipeng, Organic Letters, 2022, 24(12), 2321-2326

Production Method 4

18531-94-7

90-11-9

851615-07-1

Reaction Conditions

1.1 Reagents: Triethylamine ,  Chlorobis(1-methylethyl)silane Catalysts: 4-(Dimethylamino)pyridine Solvents: Dichloromethane ;  2 h, rt
1.2 Reagents: Bis(pinacolato)diborane Catalysts: Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium ,  Pinacolborane ,  4,4′-Dinonyl-2,2′-bipyridine Solvents: Tetrahydrofuran ;  4 - 5 h, 80 °C; 80 °C → rt
1.3 Reagents: Hexanal ;  1 h, 60 - 75 °C; 75 °C → rt
1.4 Reagents: Potassium carbonate Catalysts: Palladium, tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-one]]di-, … ,  2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl Solvents: Tetrahydrofuran ,  Water ;  15 h, 70 - 75 °C

Reference

Rapid Synthesis of 3,3' Bis-Arylated BINOL Derivatives Using a C-H Borylation in Situ Suzuki-Miyaura Coupling Sequence

Ahmed, Ijaz; Clark, Daniel A., Organic Letters, 2014, 16(16), 4332-4335

(S)-[1,3':1',1'':3'',1'''-Quaternaphthalene]-2',2''-diol Raw materials

• (1R)-[1,1'-Binaphthalene]-2,2'-diol
• 1-Bromonaphthalene

(S)-[1,3':1',1'':3'',1'''-Quaternaphthalene]-2',2''-diol Preparation Products

• (S)-[1,3':1',1'':3'',1'''-Quaternaphthalene]-2',2''-diol (851615-07-1)

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• Solvents and Organic Chemicals Organic Compounds Benzenoids Naphthalenes Naphthols and derivatives
• Catalysts and Inorganic Chemicals Catalysts

• 332062-08-5(Fmoc-S-3-amino-4,4-diphenyl-butyric acid)
• 1270529-38-8(1,2,3,4,5,6-Hexahydro-[2,3]bipyridinyl-6-ol)
• 2680771-01-9(4-cyclopentyl-3-{(prop-2-en-1-yloxy)carbonylamino}butanoic acid)
• 2098070-20-1(2-(3-(Pyridin-3-yl)-1H-pyrazol-1-yl)acetimidamide)
• 1444113-98-7(N-(3-cyanothiolan-3-yl)-2-[(2,2,2-trifluoroethyl)sulfanyl]pyridine-4-carboxamide)
• 941977-17-9(N'-(3-chloro-2-methylphenyl)-N-2-(dimethylamino)-2-(naphthalen-1-yl)ethylethanediamide)
• 2138166-62-6(2,2-Difluoro-3-[methyl(2-methylbutyl)amino]propanoic acid)
• 89640-58-4(2-Iodo-4-nitrophenylhydrazine)
• 1449132-38-0(3-Fluoro-5-(2-fluoro-5-methylbenzylcarbamoyl)benzeneboronic acid)
• 2034271-14-0(2-(1H-indol-3-yl)-N-{[6-(thiophen-2-yl)-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]methyl}acetamide)