Cas no 83947-59-5 (4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane)

4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane structure
83947-59-5 structure
Product Name:4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane
CAS No:83947-59-5
MF:C9H17BO2
MW:168.041083097458
MDL:MFCD18910701
CID:1061218
Update Time:2025-04-20

4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane Chemical and Physical Properties

Names and Identifiers

    • cis-1-Propenylboronic Acid Pinacol Ester
    • (Z)-4,4,5,5-tetramethyl-2-(prop-1-enyl)-1,3,2-dioxaborolane
    • 4,4,5,5-Tetramethyl-2-[(1Z)-1-propen-1-yl]-1,3,2-dioxaborolane
    • cis-1-Propenylboroni
    • 4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane
    • MDL： MFCD18910701
    • Inchi： 1S/C9H17BO2/c1-6-7-10-11-8(2,3)9(4,5)12-10/h6-7H,1-5H3/b7-6-
    • InChI Key： COPMASWDWLENMV-SREVYHEPSA-N
    • SMILES： O1B(/C=C\C)OC(C)(C)C1(C)C

Experimental Properties

  • Density: 0.89±0.1 g/cm3 (20 oC 760 Torr),
  • Boiling Point: 157.2±23.0 oC (760 Torr),
  • Flash Point: 48.9±22.6 oC,

4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane Security Information

  • Hazard Category Code： 10

4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane Pricemore >>

Related Categories No. Product Name Cas No. Purity Specification Price update time Inquiry
Chemenu
CM137382-1g
(Z)-4,4,5,5-Tetramethyl-2-(prop-1-en-1-yl)-1,3,2-dioxaborolane
 83947-59-5 95% mix TBC as stabilizer
1g
 $282 2021-08-05
Chemenu
CM137382-1g
(Z)-4,4,5,5-Tetramethyl-2-(prop-1-en-1-yl)-1,3,2-dioxaborolane
 83947-59-5 95%+
1g
 $313 2023-02-01
TRC
P768650-100mg
cis-1-Propenylboronic Acid Pinacol Ester
 83947-59-5
100mg
 $207.00 2023-05-17
TRC
P768650-1g
cis-1-Propenylboronic Acid Pinacol Ester
 83947-59-5
1g
 $ 1200.00 2023-09-06
SHANG HAI HAO HONG Biomedical Technology Co., Ltd.
1382531-100mg
(Z)-4,4,5,5-Tetramethyl-2-(prop-1-en-1-yl)-1,3,2-dioxaborolane
 83947-59-5 95% mix TBC as stabilizer
100mg
 ￥409.00 2024-07-28
SHANG HAI HAO HONG Biomedical Technology Co., Ltd.
1382531-250mg
(Z)-4,4,5,5-Tetramethyl-2-(prop-1-en-1-yl)-1,3,2-dioxaborolane
 83947-59-5 95% mix TBC as stabilizer
250mg
 ￥648.00 2024-07-28
SHANG HAI HAO HONG Biomedical Technology Co., Ltd.
1382531-1g
(Z)-4,4,5,5-Tetramethyl-2-(prop-1-en-1-yl)-1,3,2-dioxaborolane
 83947-59-5 95% mix TBC as stabilizer
1g
 ￥1344.00 2024-07-28
SHANG HAI HAO HONG Biomedical Technology Co., Ltd.
1382531-5g
(Z)-4,4,5,5-Tetramethyl-2-(prop-1-en-1-yl)-1,3,2-dioxaborolane
 83947-59-5 95% mix TBC as stabilizer
5g
 ￥4036.00 2024-07-28
SHANG HAI HAO HONG Biomedical Technology Co., Ltd.
1382531-10g
(Z)-4,4,5,5-Tetramethyl-2-(prop-1-en-1-yl)-1,3,2-dioxaborolane
 83947-59-5 95% mix TBC as stabilizer
10g
 ￥6820.00 2024-07-28
SHANG HAI HAO HONG Biomedical Technology Co., Ltd.
1382531-25g
(Z)-4,4,5,5-Tetramethyl-2-(prop-1-en-1-yl)-1,3,2-dioxaborolane
 83947-59-5 95% mix TBC as stabilizer
25g
 ￥12912.00 2024-07-28

4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane Production Method

Production Method 1

Reaction Conditions
1.1 Catalysts: 2924535-40-8 Solvents: Benzene-d6 ,  Toluene-d8 ;  15 min, rt
Reference
Part per million levels of an anionic iron hydride complex catalyzes selective alkene isomerization via two-state reactivity
Garhwal, Subhash ; et al, Chem Catalysis, 2021, 1(3), 631-647

Production Method 2

Reaction Conditions
1.1 Catalysts: Bis(1,5-cyclooctadiene)nickel ,  Phosphine, tricyclohexyl-, tetrafluoroborate(1-) (1:1) Solvents: Dimethylacetamide ;  overnight, 55 °C
Reference
Stereodivergent, kinetically controlled isomerization of terminal alkenes via nickel catalysis
Rubel, Camille Z.; et al, ChemRxiv, 2022, 1, 1-10

Production Method 3

Reaction Conditions
1.1 Catalysts: (OC-6-22)-Carbonylchlorohydrotris(triphenylphosphine)ruthenium Solvents: Tetrahydrofuran ;  16 h, 60 °C
Reference
Ru-catalyzed isomerization of ω-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequent in situ functionalization
Ho, Guo-Ming; et al, Chemical Science, 2020, 11(23), 5944-5949

Production Method 4

Reaction Conditions
1.1 Catalysts: 1H-Imidazo[1,2-a]imidazole, 2,6-bis(1,1-dimethylethyl)-2,3,5,6-tetrahydro-, hydr… Solvents: Hexane ;  5 min, 0 °C
1.2 Reagents: Potassium carbonate Catalysts: Cupric nitrate Solvents: Water ;  5 min, 0 °C
1.3 5 h, 0 °C
1.4 Reagents: Water
Reference
Guanidine-Copper Complex Catalyzed Allylic Borylation for the Enantioconvergent Synthesis of Tertiary Cyclic Allylboronates
Ge, Yicen; et al, Angewandte Chemie, 2019, 58(8), 2382-2386

4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane Raw materials

4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane Preparation Products

4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane Related Literature

Related Categories

83947-59-5 (4,4,5,5-tetramethyl-2-[(Z)-prop-1-enyl]-1,3,2-dioxaborolane) Related Products

Recommended suppliers
上海帛亦醫(yī)藥科技有限公司
Gold Member
Audited Supplier Audited Supplier
CN Supplier
Reagent
Hebei Liye chemical Co.,Ltd
Gold Member
Audited Supplier Audited Supplier
CN Supplier
Bulk
Hebei Liye chemical Co.,Ltd
Shenzhen Jianxing Pharmaceutical Technology Co., Ltd.
Gold Member
Audited Supplier Audited Supplier
CN Supplier
Reagent
Shenzhen Jianxing Pharmaceutical Technology Co., Ltd.
Beyond Pharmaceutical Co., Ltd
Gold Member
Audited Supplier Audited Supplier
CN Supplier
Reagent
Suzhou Genelee Bio-Technology Co., Ltd.
Gold Member
Audited Supplier Audited Supplier
CN Supplier
Bulk
Suzhou Genelee Bio-Technology Co., Ltd.