Cas no 836-42-0 (1-(benzyloxy)-4-(chloromethyl)benzene)

1-(benzyloxy)-4-(chloromethyl)benzene structure
836-42-0 structure
Product Name:1-(benzyloxy)-4-(chloromethyl)benzene
CAS No:836-42-0
MF:C14H13ClO
MW:232.705423116684
MDL:MFCD00000916
CID:40047
PubChem ID:70042
Update Time:2024-10-26

1-(benzyloxy)-4-(chloromethyl)benzene Chemical and Physical Properties

Names and Identifiers

    • 4-(Benzyloxy)benzyl chloride
    • 4-Chloromethyl-alpha-phenylanisole
    • 1-(chloromethyl)-4-phenylmethoxybenzene
    • 4-Benzyloxy Benzyl Chloride
    • Benzyl 4-(Chloromethyl)phenyl Ether
    • 1-(Benzyloxy)-4-(chloromethyl)benzene
    • 1-(Chloromethyl)-4-(phenylmethoxy)benzene (ACI)
    • Ether, benzyl α-chloro-p-tolyl (6CI, 7CI, 8CI)
    • 1-(Chloromethyl)-4-(benzyloxy)benzene
    • 4-Benzyloxybenzyl chloride
    • NSC 131670
    • p-(Benzyloxy)benzyl chloride
    • 1-(Benzyloxy)-4-(chloromethyl)benzene #
    • EINECS 212-648-3
    • A-phenylanisole
    • 1-chloromethyl-4-benzoxy-benzene
    • DTXSID40232449
    • AKOS000262128
    • 1-benzyloxy-4-chloromethyl-benzene
    • A840619
    • 4-(Benzyloxy)benzyl chloride, 97%
    • BS-43779
    • 4-(Benzyloxy)benzylchloride
    • MFCD00000916
    • AB10241
    • 1-(CHLOROMETHYL)-4-(PHENYLMETHOXY)BENZENE
    • 1-(benzyloxy)-4-(chloromethyl) benzene
    • NSC131670
    • Benzene, 1-(chloromethyl)-4-(phenylmethoxy)-
    • EN300-235634
    • 4-benzyloxy-benzyl chloride
    • S2XM7MMW4S
    • 1-chloromethyl-4-benzyloxy-benzene
    • [1-amino-2-(1H-indol-3-yl)ethyl]phosphonic acid;4-(Benzyloxy)benzyl chloride
    • Ether, benzyl .alpha.-chloro-p-tolyl
    • 4-Chloromethyl-.alpha.-phenylanisole
    • BaccatinIII
    • B5121
    • FT-0659568
    • 4-benzyloxy-1-chloromethylbenzene
    • 836-42-0
    • UNII-S2XM7MMW4S
    • SCHEMBL703
    • NS00038265
    • F2158-0083
    • 4-chloromethyl-
    • CS-0058760
    • J-015321
    • NSC-131670
    • 4-Benzyloxybenzylchloride
    • DB-075954
    • 4-Chloromethyl-alpha-phenylanisole; 1-(benzyloxy)-4-(chloromethyl)benzene; 1-(chloromethyl)-4-phenoxybenzene
    • 1-(benzyloxy)-4-(chloromethyl)benzene
    • MDL： MFCD00000916
    • Inchi： 1S/C14H13ClO/c15-10-12-6-8-14(9-7-12)16-11-13-4-2-1-3-5-13/h1-9H,10-11H2
    • InChI Key： UYQPSKUPEXAQRJ-UHFFFAOYSA-N
    • SMILES： ClCC1C=CC(OCC2C=CC=CC=2)=CC=1

Computed Properties

  • Exact Mass: 232.06500
  • Monoisotopic Mass: 232.0654927g/mol
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 0
  • Hydrogen Bond Acceptor Count: 1
  • Heavy Atom Count: 16
  • Rotatable Bond Count: 4
  • Complexity: 181
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Surface Charge: 0
  • Tautomer Count: nothing
  • XLogP3: nothing
  • Topological Polar Surface Area: 9.2?2

Experimental Properties

  • Color/Form: Not determined
  • Density: 1.2±0.1 g/cm3
  • Melting Point: 77.0 to 81.0 deg-C
  • Boiling Point: 355.7±22.0 °C at 760 mmHg
  • Flash Point: 168.5±16.4 °C
  • PSA: 9.23000
  • LogP: 4.00440
  • Solubility: Not determined
  • Vapor Pressure: 0.0±0.8 mmHg at 25°C

1-(benzyloxy)-4-(chloromethyl)benzene Security Information

1-(benzyloxy)-4-(chloromethyl)benzene Customs Data

  • HS CODE：2909309090
  • Customs Data：

    China Customs Code:

    2909309090

    Overview:

    2909309090 Other aromatic ethers and their halogenated derivatives\sulfonation\Nitrated derivative(Including nitrosative derivatives).Regulatory conditions:nothing.VAT:17.0%.Tax refund rate:9.0%.MFN tariff:5.5%.general tariff:30.0%

    Declaration elements:

    Product Name, component content, use to

    Summary:

    2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

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1-(benzyloxy)-4-(chloromethyl)benzene Production Method

Production Method 1

Reaction Conditions
1.1 Reagents: Thionyl chloride Solvents: Dichloromethane ;  3 h, 0 °C
Reference
2-Benzyl and 2-phenyl-3-hydroxypropyl pivalates as protein kinase C ligands
Lee, Jeewoo; et al, Bioorganic & Medicinal Chemistry, 2006, 14(6), 2022-2031

Production Method 2

Reaction Conditions
1.1 Reagents: Sodium borohydride Solvents: Methanol ;  1 h, rt
1.2 Reagents: Thionyl chloride Solvents: Dichloromethane ;  10 min, rt; 3 h, rt
Reference
Topochemical polymerization of assembled diacetylene macrocycle bearing dibenzylphosphine oxide in solid state
Zhang, Xiaoning; et al, Supramolecular Chemistry, 2017, 29(2), 94-101

Production Method 3

Reaction Conditions
1.1 Reagents: Potassium carbonate Solvents: Dimethylformamide ;  30 min, rt
1.2 20 h, rt
2.1 Reagents: Cyanuric chloride Solvents: Dimethylformamide ;  30 min, rt
2.2 Solvents: Dichloromethane ;  4 h, rt
Reference
Strategies for large-scale synthesis of coelenterazine for in vivo applications
Shrestha, Tej B.; et al, Synthesis, 2014, 46(5), 646-652

Production Method 4

Reaction Conditions
Reference
(p-Hydroxyphenyl)acetic acid
, Japan, , ,

Production Method 5

Reaction Conditions
1.1 Reagents: Thionyl chloride Solvents: Dichloromethane ;  0 °C; 0 °C → rt; 1 h, rt
Reference
Stereocontrolled Total Synthesis of (-)-Ephedradine A (Orantine)
Kurosawa, Wataru; et al, Journal of the American Chemical Society, 2003, 125(27), 8112-8113

Production Method 6

Reaction Conditions
1.1 -
2.1 Reagents: Thionyl chloride
Reference
Methanolysis (solvolysis) and synthesis of 4'-substituted 4-benzyloxybenzyl chlorides and some related compounds: comparisons with the corresponding benzoyl compounds
Jorge, Jorge Armando Luis; et al, Journal of the Chemical Society, 1981, (1), 100-3

Production Method 7

Reaction Conditions
1.1 Reagents: Carbon tetrachloride ,  Triphenylphosphine Solvents: Dichloromethane
Reference
Peptide synthesis by a combination of solid-phase and solution methods. III. Resin derivatives allowing minimum-racemization coupling of Nα-protected amino acids
Mergler, M.; et al, Tetrahedron Letters, 1989, 30(48), 6741-4

Production Method 8

Reaction Conditions
1.1 Reagents: Sodium borohydride Solvents: Methanol ;  1 h, rt
1.2 Reagents: Thionyl chloride Solvents: Dichloromethane ;  rt; 20 h, rt
Reference
P=O functional group-containing cryptands: from supramolecular complexes to poly[2]pseudorotaxanes
Wang, Qi; et al, Chemical Communications (Cambridge, 2015, 51(13), 2667-2670

Production Method 9

Reaction Conditions
1.1 Reagents: Lithium aluminum hydride
2.1 Reagents: Thionyl chloride
Reference
Methanolysis (solvolysis) and synthesis of 4'-substituted 4-benzyloxybenzyl chlorides and some related compounds: comparisons with the corresponding benzoyl compounds
Jorge, Jorge Armando Luis; et al, Journal of the Chemical Society, 1981, (1), 100-3

Production Method 10

Reaction Conditions
1.1 Reagents: Potassium carbonate Solvents: Dimethylformamide ;  70 min, 60 °C
2.1 Reagents: Sodium borohydride Solvents: Tetrahydrofuran ,  Water ;  40 min, 0 °C
2.2 Reagents: Acetone
3.1 Reagents: Thionyl chloride Solvents: Dichloromethane ;  0 °C; 0 °C → rt; 1 h, rt
Reference
Stereocontrolled Total Synthesis of (-)-Ephedradine A (Orantine)
Kurosawa, Wataru; et al, Journal of the American Chemical Society, 2003, 125(27), 8112-8113

1-(benzyloxy)-4-(chloromethyl)benzene Raw materials

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1-(benzyloxy)-4-(chloromethyl)benzene Suppliers

Suzhou Senfeida Chemical Co., Ltd
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(CAS:836-42-0)4-(Benzyloxy)benzyl chloride
Order Number:1635167
Stock Status:in Stock
Quantity:Company Customization
Purity:98%
Pricing Information Last Updated:Monday, 14 April 2025 21:49
Price ($):discuss personally
Tiancheng Chemical (Jiangsu) Co., Ltd
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(CAS:836-42-0)4-(芐氧基)氯芐
Order Number:LE1635167
Stock Status:in Stock
Quantity:25KG,200KG,1000KG
Purity:99%
Pricing Information Last Updated:Friday, 20 June 2025 12:30
Price ($):discuss personally

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Suzhou Senfeida Chemical Co., Ltd
(CAS:836-42-0)4-(Benzyloxy)benzyl chloride
1635167
Purity:98%
Quantity:Company Customization
Price ($):Inquiry
Email
Tiancheng Chemical (Jiangsu) Co., Ltd
(CAS:836-42-0)4-(芐氧基)氯芐
LE1635167
Purity:99%
Quantity:25KG,200KG,1000KG
Price ($):Inquiry
Email