Cas no 83379-40-2 (D-Ribose-2-13C)

D-Ribose-2-13C structure
D-Ribose-2-13C structure
Product Name:D-Ribose-2-13C
CAS No:83379-40-2
MF:C5H10O5
MW:151.122557163239
CID:719546
PubChem ID:24858820
Update Time:2024-10-26

D-Ribose-2-13C Chemical and Physical Properties

Names and Identifiers

    • D-Ribose-2-13C(9CI)
    • D-Ribose-2-13C
    • 83379-40-2
    • D-(2-~13~C)Ribofuranose
    • DTXSID50583535
    • (3R,4S,5R)-5-(Hydroxymethyl)(313C)oxolane-2,3,4-triol
    • D-Ribose-2-13C, 99 atom % 13C
    • [2-13C]-D-Ribose
    • MDL: MFCD00064326
    • Inchi: 1S/C5H10O5/c6-1-3(8)5(10)4(9)2-7/h1,3-5,7-10H,2H2/t3-,4+,5-/m0/s1/i3+1
    • InChI Key: PYMYPHUHKUWMLA-QWUQOAQISA-N
    • SMILES: [C@H](O)([13C@@H](O)C=O)[C@H](O)CO

Computed Properties

  • Exact Mass: 151.05617825g/mol
  • Monoisotopic Mass: 151.05617825g/mol
  • Isotope Atom Count: 1
  • Hydrogen Bond Donor Count: 4
  • Hydrogen Bond Acceptor Count: 5
  • Heavy Atom Count: 10
  • Rotatable Bond Count: 1
  • Complexity: 117
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 3
  • Undefined Atom Stereocenter Count : 1
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • XLogP3: -2
  • Topological Polar Surface Area: 90.2?2

Experimental Properties

  • Density: 1.7±0.1 g/cm3
  • Melting Point: 88-92?°C (dec.) (lit.)
  • PSA: 90.15000
  • LogP: -2.58230
  • Optical Activity: [α]20/D -20, c =?4 in H2O

D-Ribose-2-13C Security Information

D-Ribose-2-13C Pricemore >>

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D-Ribose-2-13C Production Method

Production Method 1

Reaction Conditions
1.1 Reagents: Nickel chloride hexahydrate ,  Amberlite IR 120 Solvents: Methanol ;  60 °C; 60 °C → rt
1.2 Reagents: Sulfuric acid Solvents: Methanol ;  30 min, pH 6.5, rt
1.3 Reagents: Dowex 50W-X8 ;  1.3 h, rt
1.4 Reagents: Dowex 50W-X8
Reference
The economical synthesis of [2'-13C, 1,3-15N2]uridine; preliminary conformational studies by solid state NMR
Patching, Simon G.; et al, Organic & Biomolecular Chemistry, 2003, 1(12), 2057-2062

Production Method 2

Reaction Conditions
1.1 Reagents: Acetic acid ,  Sodium hydroxide Solvents: Water ;  1.5 h, pH 7.2, rt
1.2 Reagents: Acetic acid Solvents: Water ;  pH 4.7; 1 h, 4 °C
1.3 Reagents: Acetic acid Solvents: Water ;  pH 4.2, 4 °C
1.4 Reagents: Hydrogen Catalysts: Palladium ,  Barium sulfate Solvents: Water ;  1.5 h, pH 4.2, rt
1.5 Reagents: Dowex 50W-X8 Solvents: Water
1.6 Reagents: Samarium trichloride hexahydrate Solvents: Water
2.1 Reagents: Nickel chloride hexahydrate ,  Amberlite IR 120 Solvents: Methanol ;  60 °C; 60 °C → rt
2.2 Reagents: Sulfuric acid Solvents: Methanol ;  30 min, pH 6.5, rt
2.3 Reagents: Dowex 50W-X8 ;  1.3 h, rt
2.4 Reagents: Dowex 50W-X8
Reference
The economical synthesis of [2'-13C, 1,3-15N2]uridine; preliminary conformational studies by solid state NMR
Patching, Simon G.; et al, Organic & Biomolecular Chemistry, 2003, 1(12), 2057-2062

D-Ribose-2-13C Raw materials

D-Ribose-2-13C Preparation Products

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