Cas no 827614-64-2 (5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine)

5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine structure
827614-64-2 structure
Product Name:5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine
CAS No:827614-64-2
MF:C11H17BN2O2
MW:220.075882673264
MDL:MFCD05663837
CID:68889
PubChem ID:24883087
Update Time:2024-10-27

5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine Chemical and Physical Properties

Names and Identifiers

    • 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine
    • 2-Aminopyridine-5-boronic acid pinacol ester
    • 6-Aminopyridine-3-boronic acid pinacol ester
    • 2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
    • 5-(4,4,5,5-Tetramethyl-[1,3,2]dioxaborolan-2-yl)-pyridin-2-ylamine
    • 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl) yridine-2-amine
    • 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-pyridinylamine
    • 2-AMinopyridine-5-boronic acid
    • (2-Aminopyridin-5-yl)boronic acid pinacol ester
    • 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-Pyridinamine
    • 5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine
    • 2-aminopyridine-5-boronic acid, pinacol ester
    • 2-Pyridinamine, 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
    • C11H17BN2O2
    • 5-(4,4,5,5-tetramethy
    • 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2-pyridinamine (ACI)
    • 2-(6-Aminopyridin-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
    • 5-(3,3,4,4-Tetramethylborolan-1-yl)pyridin-2-amine
    • 6-Aminopyridin-3-ylboronic acid pinacol ester
    • [5-(4,4,5,5-Tetramethyl-[1,3,2]dioxaborolan-2-yl)pyridin-2-yl]amine
    • AKOS005259751
    • YFTAUNOLAHRUIE-UHFFFAOYSA-N
    • 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl) pyridin-2-amine
    • SCHEMBL183601
    • 5-(4,4,5,5-tetramethyl-[1,3,2]dioxa borolan-2-yl)-pyridin-2-ylamine
    • CS-W000973
    • PB24877
    • MFCD05663837
    • A15831
    • 6-Aminopyridine-3-boronic acid, pinacol ester
    • EN300-97678
    • SY005789
    • J-508073
    • BCP10062
    • 2-aminopyridine-5-boronic acid,pinacol ester
    • AM20120669
    • 5-(4,4,5,5-Tetramethyl-[1,3,2]dioxaborolan-2-yl)pyridin-2-ylamine
    • (6-AMINOPYRIDIN-3-YL)BORONIC ACID PINACOL ESTER
    • A840432
    • 2-Aminopyridine-5-boronic acid pinacol ester, 97%
    • AC-25638
    • Z1316857925
    • GS-6327
    • RB2038
    • 2-amino-pyridine-5-boronic acid pinacol ester
    • 2-amino-5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-pyridine
    • DTXSID20373420
    • 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-pyridin-2-amine
    • 827614-64-2
    • FT-0647397
    • 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-ylamine
    • ALBB-031296
    • 3-HYDROXY-2,3-DIMETHYLBUTAN-2-YL HYDROGEN 6-AMINOPYRIDIN-3-YLBORONATE
    • DTXCID20324452
    • MDL： MFCD05663837
    • Inchi： 1S/C11H17BN2O2/c1-10(2)11(3,4)16-12(15-10)8-5-6-9(13)14-7-8/h5-7H,1-4H3,(H2,13,14)
    • InChI Key： YFTAUNOLAHRUIE-UHFFFAOYSA-N
    • SMILES： N1C(N)=CC=C(B2OC(C)(C)C(C)(C)O2)C=1

Computed Properties

  • Exact Mass: 220.13800
  • Monoisotopic Mass: 220.138
  • Isotope Atom Count: 0
  • Hydrogen Bond Donor Count: 1
  • Hydrogen Bond Acceptor Count: 4
  • Heavy Atom Count: 16
  • Rotatable Bond Count: 1
  • Complexity: 255
  • Covalently-Bonded Unit Count: 1
  • Defined Atom Stereocenter Count: 0
  • Undefined Atom Stereocenter Count : 0
  • Defined Bond Stereocenter Count: 0
  • Undefined Bond Stereocenter Count: 0
  • Topological Polar Surface Area: 57.4
  • Surface Charge: 0
  • Tautomer Count: 2
  • XLogP3: nothing

Experimental Properties

  • Color/Form: solid
  • Density: 1.09
  • Melting Point: 131-135?°C (lit.)
  • Boiling Point: 352.9℃ at 760 mmHg
  • Flash Point: 167.3℃
  • Refractive Index: 1.516
  • Water Partition Coefficient: Insoluble in water.
  • PSA: 57.37000
  • LogP: 1.54420
  • Solubility: Not determined

5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine Security Information

  • Symbol: GHS07
  • Signal Word：Warning
  • Hazard Statement： H315-H319-H335
  • Warning Statement： P261-P305 + P351 + P338
  • Hazardous Material transportation number：NONH for all modes of transport
  • WGK Germany：3
  • Hazard Category Code： 36/37/38
  • Safety Instruction： S26-S36/37
  • Hazardous Material Identification： Xi
  • Risk Phrases：R36/37/38

5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine Pricemore >>

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NAN JING YAO SHI KE JI GU FEN Co., Ltd.
PB03090-1 G
5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine
 827614-64-2 97%
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5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine
 827614-64-2 97%
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PB03090-100 G
5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine
 827614-64-2 97%
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 ￥ 6,468.00 2021-05-07
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PB03090-250 G
5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine
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PB00616-1 G
5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine
 827614-64-2 97%
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NAN JING YAO SHI KE JI GU FEN Co., Ltd.
PB00616-5 G
5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine
 827614-64-2 97%
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NAN JING YAO SHI KE JI GU FEN Co., Ltd.
PB00616-10 G
5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine
 827614-64-2 97%
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5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine Production Method

Production Method 1

Reaction Conditions
1.1 Catalysts: Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium ,  2861929-14-6 Solvents: Tetrahydrofuran ;  2 min, rt
1.2 12 h, rt
Reference
Ligand- and Substrate-Controlled para C-H Borylation of Anilines at Room Temperature
Haldar, Chabush ; et al, Organic Letters, 2022, 24(44), 8147-8152

Production Method 2

Reaction Conditions
1.1 Catalysts: Bis(dimethylamino)methane Solvents: Acetone ,  Acetonitrile ,  Water ;  15 min, -5 °C
Reference
Efficient metal-free photochemical borylation of aryl halides under batch and continuous-flow conditions
Chen, Kai; et al, Chemical Science, 2016, 7(6), 3676-3680

5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine Raw materials

5-(tetramethyl-1,3,2-dioxaborolan-2-yl)pyridin-2-amine Preparation Products

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