Production Method 1

100-51-6

19165-29-8

82185-41-9

Reaction Conditions

1.1 Reagents: Dicyclohexylcarbodiimide Catalysts: 4-(Dimethylamino)pyridine Solvents: Acetonitrile ;  24 h, 40 °C
1.2 Reagents: Sodium borohydride Solvents: Ethanol ;  2 h, rt
1.3 Reagents: Water

Reference

Synthesis of simple analogues of methyllycaconitine-an efficient method for the preparation of the N-substituted anthranilate pharmacophore

Barker, David; et al, Tetrahedron, 2004, 60(28), 5953-5963

Production Method 2

100-51-6

118-48-9

82185-41-9

Reaction Conditions

1.1 Catalysts: 4-(Dimethylamino)pyridine Solvents: Dimethylformamide ;  16 h, 80 °C

Reference

The multicomponent approach to N-methyl peptides: total synthesis of antibacterial (-)-viridic acid and analogues

Neves Filho, Ricardo A. W.; et al, Beilstein Journal of Organic Chemistry, 2012, 8, 2085-2090

Production Method 3

7579-38-6

82185-41-9

Reaction Conditions

1.1 Reagents: Acetic acid ,  Sodium borohydride Catalysts: Palladium Solvents: Benzene ;  rt; 14 h, rt

Reference

Hydrogenation of alkenes with NaBH4, CH2CO2H, Pd/C in the presence of O- and N-benzyl functions

Al Soom, Nuha; et al, International Journal of Organic Chemistry, 2016, 6(1), 1-11

Production Method 4

82185-41-9

Reaction Conditions

1.1 15 min; 1 h; rt → 0 °C
1.2 Reagents: Water
2.1 Reagents: Dicyclohexylcarbodiimide Catalysts: 4-(Dimethylamino)pyridine Solvents: Acetonitrile ;  24 h, 40 °C
2.2 Reagents: Sodium borohydride Solvents: Ethanol ;  2 h, rt
2.3 Reagents: Water

Reference

Synthesis of simple analogues of methyllycaconitine-an efficient method for the preparation of the N-substituted anthranilate pharmacophore

Barker, David; et al, Tetrahedron, 2004, 60(28), 5953-5963

Production Method 5

100-51-6

84379-71-5

82185-41-9

22767-96-0

Reaction Conditions

1.1 Reagents: 1,8-Diazabicyclo[5.4.0]undec-7-ene Solvents: Dichloromethane ;  24 h, rt
1.2 Reagents: Acetic acid Solvents: Water ;  pH 7, rt

Reference

Lossen-type rearrangement products in the reaction of N-(phthalimidoyloxy)-3-phenylpropionate and - tosylate with benzyl alcohol

Takagi, Shunsuke; et al, Heterocycles, 2009, 78(6), 1433-1438

Production Method 6

127-19-5

118-48-9

82185-41-9

1679362-39-0

98326-21-7

16512-78-0

100-94-7

147611-22-1

Reaction Conditions

1.1 Reagents: Sodium hydride Solvents: Dimethylacetamide ;  12 h, 30 °C

Reference

Convenient Novel Method to Access N-Benzylated Isatoic Anhydride: Reaction Behavior of Isatoic Anhydride with 4-Chlorobenzyl Chloride in the Presence of Bases

Verma, Ekta; et al, ACS Omega, 2021, 6(12), 8346-8355

Production Method 7

100-51-6

19165-29-8

82185-41-9

Reaction Conditions

1.1 Reagents: Dicyclohexylcarbodiimide Catalysts: 4-(Dimethylamino)pyridine Solvents: Acetonitrile
1.2 Reagents: Sodium borohydride Solvents: Ethanol

Reference

A high yielding synthesis of anthranilate esters from sterically hindered alcohols

Barker, D.; et al, Tetrahedron Letters, 2001, 42(9), 1785-1788

Production Method 8

100-51-6

552-16-9

82185-41-9

Reaction Conditions

1.1 Reagents: Bromotrichloromethane ,  Triphenylphosphine Solvents: Dichloromethane
2.1 Reagents: Acetic acid ,  Sodium borohydride Catalysts: Palladium Solvents: Benzene ;  rt; 14 h, rt

Reference

Hydrogenation of alkenes with NaBH4, CH2CO2H, Pd/C in the presence of O- and N-benzyl functions

Al Soom, Nuha; et al, International Journal of Organic Chemistry, 2016, 6(1), 1-11

Production Method 9

37960-65-9

82185-41-9

98326-21-7

Reaction Conditions

1.1 Catalysts: Tetrabutylammonium bromide

Reference

Convenient synthesis of esters of 2-pyrrolecarboxylic acid and of pyridinecarboxylic acids by solid-liquid phase transfer catalysis without added solvent

Barry, Jean; et al, Heterocycles, 1985, 23(4), 875-80

Production Method 10

37960-65-9

82185-41-9

98326-21-7

Reaction Conditions

1.1 Catalysts: Tetrabutylammonium bromide

Reference

Convenient synthesis of esters of 2-pyrrolecarboxylic acid and of pyridinecarboxylic acids by solid-liquid phase transfer catalysis without added solvent

Barry, Jean; et al, Heterocycles, 1985, 23(4), 875-80

Production Method 11

100-51-6

84379-71-5

82185-41-9

22767-96-0

Reaction Conditions

1.1 Reagents: 1,8-Diazabicyclo[5.4.0]undec-7-ene Solvents: Dichloromethane ;  3 h, rt

Reference

Studies on the Lossen-type rearrangement of N-(3-phenylpropionyloxy) phthalimide and N-tosyloxy derivatives with several nucleophiles

Sheikh, Chanmiya Md.; et al, Tetrahedron, 2010, 66(12), 2132-2140

Production Method 12

501-52-0

524-38-9

82185-41-9

22767-96-0

Reaction Conditions

1.1 Reagents: Dicyclohexylcarbodiimide Solvents: Dichloromethane ;  3 h, 0 °C
2.1 Reagents: 1,8-Diazabicyclo[5.4.0]undec-7-ene Solvents: Dichloromethane ;  3 h, rt

Reference

Studies on the Lossen-type rearrangement of N-(3-phenylpropionyloxy) phthalimide and N-tosyloxy derivatives with several nucleophiles

Sheikh, Chanmiya Md.; et al, Tetrahedron, 2010, 66(12), 2132-2140

Benzyl 2-Aminobenzoate Raw materials

• 3-Phenylpropionic acid
• N,N-Dimethylacetamide
• Benzyl alcohol
• N-Hydroxyphthalimide
• 2-Nitrobenzoic acid
• Isatoic anhydride
• 2-(trifluoroacetamido)benzoic acid
• Benzoic acid, 2-nitro-, phenylmethyl ester
• Benzoic acid, 2-amino-, potassium salt (1:1)
• 1H-Isoindole-1,3(2H)-dione, 2-(1-oxo-3-phenylpropoxy)-

Benzyl 2-Aminobenzoate Preparation Products

• Benzoic acid, 2-isocyanato-, sodium salt (1:1) (1679362-39-0)
• Benzoic acid, 2-[(phenylmethyl)amino]-, phenylmethyl ester (98326-21-7)
• 1-[(4-chlorophenyl)methyl]-2,4-dihydro-1H-3,1-benzoxazine-2,4-dione (16512-78-0)
• Dibenzyl dimethylammonium chloride (100-94-7)
• benzyl 3-phenylpropanoate (22767-96-0)
• Benzaldehyde, 2-[(phenylmethyl)amino]- (147611-22-1)
• Benzyl 2-Aminobenzoate (82185-41-9)

• 1. Excess electrons in lithium–ethylamine solutions—density, electrical conductivity and EPR studies
  Phys. Chem. Chem. Phys., 1999,1, 3561-3565
• 2. Excellent mechanical performance and enhanced dielectric properties of OBC/SiO2 elastomeric nanocomposites: effect of dispersion of the SiO2 nanoparticles?
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• 3. Essential effect of the electrolyte on the mechanical and chemical degradation of LiNi0.8Co0.15Al0.05O2 cathodes upon long-term cycling??
  Xiaoming Liu,Zachary D. Hood,Wangda Li,Donovan N. Leonard,Arumugam Manthiram,Miaofang Chi J. Mater. Chem. A, 2021,9, 2111-2119
• 4. Dissociative dynamics of O2 on Ag(110)?
  Ivor Lon?ari? Phys. Chem. Chem. Phys., 2015,17, 9436-9445
• 5. Emerging investigator series: first-principles and thermodynamics comparison of compositionally-tuned delafossites: cation release from the (001) surface of complex metal oxides?
  Joseph W. Bennett,Diamond T. Jones,Blake G. Hudson,Joshua Melendez-Rivera,Robert J. Hamers,Sara E. Mason Environ. Sci.: Nano, 2020,7, 1642-1651

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzoic acid esters
• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Benzoic acids and derivatives Benzoic acid esters

• 87-25-2(Ethyl anthranilate)
• 32045-49-1(Benzoic acid, 2-amino-,ethyl ester, hydrochloride (1:1))
• 1333-08-0(Benzoic acid, amino-, ethyl ester)
• 179115-20-9(Benzoic acid,2-amino-3,5-dimethyl-, ethyl ester)
• 18189-02-1(Isopropyl anthranilate)
• 37-25-2(ETHYL ANTHRANILATE)
• 30954-98-4(Benzoic acid, 2-amino-,propyl ester)
• 15403-46-0(Diethyl 2,5-diaminoterephthalate)
• 218590-80-8(1,4-Benzenedicarboxylicacid,2-amino-,4-ethylester(9CI))
• 218590-81-9(3-Amino-4-(ethoxycarbonyl)benzoic acid)