Production Method 1

1038-95-5

797-70-6

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Solvents: Dichloromethane ,  Water ;  10 min, rt
1.2 Reagents: Water ;  rt

Reference

Conversion from Heterometallic to Homometallic Metal-Organic Frameworks

Song, Jeong Hwa; et al, Chemistry - A European Journal, 2020, 26(51), 11767-11775

Production Method 2

1038-95-5

797-70-6

Reaction Conditions

1.1 Catalysts: Au3+ (compound with nanofibrous phosphosilicate, supported on cellulose) ,  Silicon phosphide (compound with gold(III), supported on cellulose) Solvents: Dimethyl carbonate ;  rt

Reference

Photooxidation of triarylphosphines under aerobic conditions in the presence of a gold(III) complex on cellulose extracted from Carthamus tinctorius immobilized on nanofibrous phosphosilicate

Sadeghzadeh, Seyed Mohsen; et al, RSC Advances, 2019, 9(3), 1509-1516

Production Method 3

6224-65-3

797-70-6

Reaction Conditions

1.1 Reagents: 3-Fluoro-3-(1,1,2,2,3,3,3-heptafluoropropyl)-2-(1,1,2,2,3,3,4,4,4-nonafluorobuty…

Reference

Oxaziridine, 3-fluoro-3-(heptafluoropropyl)-2-(nonafluorobutyl)

Metrangolo, Pierangelo; et al, e-EROS Encyclopedia of Reagents for Organic Synthesis, 2005, 1, 1-7

Production Method 4

93131-73-8

2409-61-2

797-70-6

Reaction Conditions

1.1 Reagents: Triethylamine ,  Sodium iodide Catalysts: Palladium diacetate Solvents: Dimethylformamide ;  rt → 120 °C; 4 h, 120 °C

Reference

Palladium-Catalyzed C-P Bond-Forming Reactions of Aryl Nonaflates Accelerated by Iodide

McErlain, Holly; et al, Journal of Organic Chemistry, 2021, 86(23), 17036-17049

Production Method 5

375-72-4

797-70-6

Reaction Conditions

1.1 Reagents: Triethylamine Solvents: Dichloromethane ;  0 °C → rt; 2 h, rt
2.1 Reagents: Triethylamine ,  Sodium iodide Catalysts: Palladium diacetate Solvents: Dimethylformamide ;  rt → 120 °C; 4 h, 120 °C

Reference

Palladium-Catalyzed C-P Bond-Forming Reactions of Aryl Nonaflates Accelerated by Iodide

McErlain, Holly; et al, Journal of Organic Chemistry, 2021, 86(23), 17036-17049

Production Method 6

797-70-6

Reaction Conditions

1.1 Reagents: Sodium amide Solvents: Toluene ;  24 h, reflux

Reference

New reactions and reactive intermediates in the pyrolysis of cyclic phosphonium ylides

Aitken, R. Alan; et al, ARKIVOC (Gainesville, 2017, (3), 293-301

Production Method 7

1038-95-5

797-70-6

Reaction Conditions

1.1 Reagents: Oxygen ;  180 min

Reference

Dramatic effect of atmosphere on product distribution from steady-state photolysis of triarylphosphines

Yasui, Shinro; et al, Bulletin of the Chemical Society of Japan, 2014, 87(9), 988-996

Production Method 8

1038-95-5

797-70-6

Reaction Conditions

1.1 Solvents: Benzene-d6 ;  16 h, rt

Reference

Gold peroxide complexes and the conversion of hydroperoxides into gold hydrides by successive oxygen-transfer reactions

Rpsca, Dragos-Adrian; et al, Nature Communications, 2013, 4, 3167/1-3167/7

Production Method 9

1038-95-5

797-70-6

Reaction Conditions

1.1 Solvents: Dichloromethane-d2

Reference

Gold peroxide complexes and the conversion of hydroperoxides into gold hydrides by successive oxygen-transfer reactions

Rpsca, Dragos-Adrian; et al, Nature Communications, 2013, 4, 3167/1-3167/7

Production Method 10

2904-57-6

797-70-6

Reaction Conditions

1.1 Solvents: Toluene ;  12 h, rt

Reference

N-heterocyclic carbene complexes of palladium in oxygen atom transfer reactions involving the making and breaking of N-O bonds

Cai, Xiaochen; et al, Inorganica Chimica Acta, 2017, 468, 285-293

Production Method 11

797-70-6

Reaction Conditions

1.1 Solvents: Acetone ;  16 h, 60 °C
2.1 Solvents: Dichloromethane-d2 ;  16 h, rt

Reference

Gold peroxide complexes and the conversion of hydroperoxides into gold hydrides by successive oxygen-transfer reactions

Rpsca, Dragos-Adrian; et al, Nature Communications, 2013, 4, 3167/1-3167/7

Production Method 12

1038-95-5

797-70-6

Reaction Conditions

1.1 Reagents: Oxygen Catalysts: 4-Phenyl-9H-thioxanthen-9-one Solvents: Methanol ;  1 h, 1 atm, rt

Reference

Visible light-induced 4-phenylthioxanthone-catalyzed aerobic oxidation of triarylphosphines

Ding, Aishun; et al, Tetrahedron Letters, 2018, 59(43), 3880-3883

Production Method 13

6224-65-3

797-70-6

Reaction Conditions

1.1 Catalysts: 3-Fluoro-3-(1,1,2,2,3,3,3-heptafluoropropyl)-2-(1,1,2,2,3,3,4,4,4-nonafluorobuty…

Reference

Oxaziridine, 3-fluoro-3-(heptafluoropropyl)-2-(nonafluorobutyl)-

Metrangolo, Pierangelo; et al, e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001, ,

Production Method 14

2409-61-2

797-70-6

Reaction Conditions

1.1 Reagents: Cesium carbonate Catalysts: 2971721-62-5 Solvents: Ethanol ;  1 h, 90 °C

Reference

Highly efficient and well-defined phosphinous acid-ligated Pd(II) precatalysts for Hirao cross-coupling reaction

Hong, Li-Hui; et al, Dalton Transactions, 2023, 52(16), 5101-5109

Production Method 15

797-70-6

Reaction Conditions

1.1 Reagents: Magnesium Solvents: Tetrahydrofuran ;  0 °C; 1 h, reflux
1.2 Reagents: Phosphorus oxychloride ;  0 °C; 1 h, reflux

Reference

Synthesis, derivatization and structural characterization of a new macrobicyclic phosphane oxide cryptand

Daebritz, Frank; et al, European Journal of Organic Chemistry, 2008, (33), 5571-5576

Production Method 16

797-70-6

Reaction Conditions

1.1 Reagents: Magnesium ,  Iodine Solvents: Tetrahydrofuran ;  0 °C; 1 h, 0 °C → reflux; reflux → 0 °C
1.2 Reagents: Phosphorus oxychloride ;  0 °C; 1 h, reflux

Reference

One-pot cascade ring enlargement of isatin-3-oximes to 2,4-dichloroquinazolines mediated by bis(trichloromethyl)carbonate and triarylphosphine oxide

Qin, Jinjing; et al, Phosphorus, 2020, 195(12), 1007-1012

Production Method 17

127-19-5

797-70-6

723-45-5

Reaction Conditions

1.1 Reagents: Tetrakis(hydroxymethyl)phosphonium chloride ,  Potassium carbonate Catalysts: trans-Di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium

Reference

A new palladium-catalyzed P-C coupling reaction: synthesis of triarylphosphine oxides and diarylmethylphosphine oxides

Stark, Gene A.; et al, Synthetic Communications, 2000, 30(10), 1703-1711

Production Method 18

1038-95-5

797-70-6

Reaction Conditions

1.1 Solvents: Dichloromethane-d2 ;  16 h, rt

Reference

Gold peroxide complexes and the conversion of hydroperoxides into gold hydrides by successive oxygen-transfer reactions

Rpsca, Dragos-Adrian; et al, Nature Communications, 2013, 4, 3167/1-3167/7

Production Method 19

797-70-6

Reaction Conditions

1.1 Solvents: Toluene ,  Dodecane ;  12 h, rt
2.1 Solvents: Benzene-d6 ;  16 h, rt

Reference

Gold peroxide complexes and the conversion of hydroperoxides into gold hydrides by successive oxygen-transfer reactions

Rpsca, Dragos-Adrian; et al, Nature Communications, 2013, 4, 3167/1-3167/7

Production Method 20

797-70-6

Reaction Conditions

1.1 Reagents: Hydrogen peroxide ,  Oxygen Solvents: Toluene ,  Water ;  30 min, rt
2.1 Solvents: Dichloromethane-d2

Reference

Gold peroxide complexes and the conversion of hydroperoxides into gold hydrides by successive oxygen-transfer reactions

Rpsca, Dragos-Adrian; et al, Nature Communications, 2013, 4, 3167/1-3167/7

Production Method 21

797-70-6

Reaction Conditions

1.1 Reagents: Sodium hydroxide Solvents: Water ;  rt
2.1 Reagents: Sodium amide Solvents: Toluene ;  24 h, reflux

Reference

New reactions and reactive intermediates in the pyrolysis of cyclic phosphonium ylides

Aitken, R. Alan; et al, ARKIVOC (Gainesville, 2017, (3), 293-301

Production Method 22

1038-95-5

797-70-6

Reaction Conditions

1.1 Solvents: Dichloromethane-d2
2.1 Solvents: Acetone ;  16 h, 60 °C
3.1 Solvents: Dichloromethane-d2 ;  16 h, rt

Reference

Gold peroxide complexes and the conversion of hydroperoxides into gold hydrides by successive oxygen-transfer reactions

Rpsca, Dragos-Adrian; et al, Nature Communications, 2013, 4, 3167/1-3167/7

Production Method 23

1038-95-5

797-70-6

Reaction Conditions

1.1 Solvents: Dichloromethane-d2
2.1 Solvents: Toluene ,  Dodecane ;  12 h, rt
3.1 Solvents: Benzene-d6 ;  16 h, rt

Reference

Gold peroxide complexes and the conversion of hydroperoxides into gold hydrides by successive oxygen-transfer reactions

Rpsca, Dragos-Adrian; et al, Nature Communications, 2013, 4, 3167/1-3167/7

Tri-p-tolylphosphine Oxide Raw materials

• N,N-Dimethylacetamide
• Nonafluoro-1-butanesulfonyl Fluoride
• 1-Butanesulfonic acid, 1,1,2,2,3,3,4,4,4-nonafluoro-, 4-methylphenyl ester
• Bis(p-tolyl)phosphine oxide
• Tri-p-tolylphosphine
• Mesitonitrile N-Oxide
• tri(4-methylphenyl)phosphine sulfide

Tri-p-tolylphosphine Oxide Preparation Products

• Tri-p-tolylphosphine Oxide (797-70-6)
• Phosphine oxide, methylbis(4-methylphenyl)- (723-45-5)

• 1. Enabling chloride salts for thermal energy storage: implications of salt purity?
  J. Matthew Kurley,Phillip W. Halstenberg,Abbey McAlister,Stephen Raiman,Richard T. Mayes RSC Adv., 2019,9, 25602-25608
• 2. Evolution of cellulose into flexible conductive green electronics: a smart strategy to fabricate sustainable electrodes for supercapacitors
  Tengfei Yu,Yuehan Wu,Wei Li,Bin Li RSC Adv., 2014,4, 34134-34143
• 3. Empowering microfluidics by micro-3D printing and solution-based mineral coating?
  Hongxia Li,Aikifa Raza,Qiaoyu Ge,Jin-You Lu,TieJun Zhang Soft Matter, 2020,16, 6841-6849
• 4. Excess electrons in lithium–ethylamine solutions—density, electrical conductivity and EPR studies
  Phys. Chem. Chem. Phys., 1999,1, 3561-3565
• 5. Dissociation of large gaseous serine clusters produces abundant protonated serine octamer
  Jacob S. Jordan,Evan R. Williams Analyst, 2021,146, 2617-2625

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Phenylphosphines and derivatives

• 145290-34-2(Phosphine oxide, bis(3-methylphenyl))
• 5032-54-2(Benzonitrile, 4-(diphenylphosphinyl)-)
• 66568-24-9(Phosphine oxide, methylbis(2-methylphenyl)-)
• 87991-75-1(Phosphine oxide, tris([1,1'-biphenyl]-4-yl)-)
• 53888-89-4(Phosphine oxide, dimethyl(4-methylphenyl)-)
• 6840-26-2(Phosphine oxide, (2-methylphenyl)diphenyl-)
• 16069-43-5(Phosphine oxide, bis(3,4-dimethylphenyl)phenyl-)
• 2409-61-2(Bis(p-tolyl)phosphine oxide)
• 187344-92-9(Bis(3,5-dimethylphenyl)phosphineoxide)
• 103130-17-2(1-methyl-4-[methyl(phenyl)phosphoryl]naphthalene)