- Catalytic asymmetric bromine-lithium exchange: a new tool to build axial chiralityPerron, Quentin; Alexakis, Alexandre, Advanced Synthesis & Catalysis, 2010, , 2611-2620
Cas no 66115-57-9 (2,4-dibromo-1-(2,4-dibromophenyl)benzene)
66115-57-9 structure
Product Name:2,4-dibromo-1-(2,4-dibromophenyl)benzene
CAS No:66115-57-9
MF:C12H6Br4
MW:469.792040348053
CID:963309
PubChem ID:181773
Update Time:2025-04-19
2,4-dibromo-1-(2,4-dibromophenyl)benzene Chemical and Physical Properties
Names and Identifiers
-
- 2,4-dibromo-1-(2,4-dibromophenyl)benzene
- 2,2’,4,4’-Tetrabromo-1,1’-biphenyl
- UNII-5PC8U9P5OZ
- PBB 47
- 2,2',4,4'-Tetrabromobiphenyl
- DTXSID30216314
- 66115-57-9
- 1,1'-Biphenyl, 2,2',4,4'-tetrabromo-
- Q27262691
- UBJWRBZIWNERQZ-UHFFFAOYSA-N
- NS00125586
- SCHEMBL11013516
- 5PC8U9P5OZ
-
- Inchi： 1S/C12H6Br4/c13-7-1-3-9(11(15)5-7)10-4-2-8(14)6-12(10)16/h1-6H
- InChI Key： UBJWRBZIWNERQZ-UHFFFAOYSA-N
- SMILES： BrC1C=C(C=CC=1C1C=CC(=CC=1Br)Br)Br
Computed Properties
- Exact Mass: 465.72018
- Monoisotopic Mass: 465.72
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 16
- Rotatable Bond Count: 1
- Complexity: 209
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- XLogP3: 6.5
- Topological Polar Surface Area: 0?2
Experimental Properties
- Density: 2.14
- Boiling Point: 413.7°C at 760 mmHg
- Flash Point: 197.4°C
- Refractive Index: 1.666
- PSA: 0
2,4-dibromo-1-(2,4-dibromophenyl)benzene Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Butyllithium Solvents: Diethyl ether , Hexane ; -78 °C; 30 min, -78 °C
1.2 Reagents: Methanol ; -78 °C → rt
1.2 Reagents: Methanol ; -78 °C → rt
Reference
2,4-dibromo-1-(2,4-dibromophenyl)benzene Raw materials
2,4-dibromo-1-(2,4-dibromophenyl)benzene Preparation Products
2,4-dibromo-1-(2,4-dibromophenyl)benzene Related Literature
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Yaqing Liu,Jiangtao Ren,Jing Li,Jiyang Liu,Erkang Wang Chem. Commun., 2012,48, 802-804
-
Yang Chen,Di Zhou,Zheyi Meng,Jin Zhai Chem. Commun., 2016,52, 10020-10023
-
Huifang Yang,Haoran Guo,Peidong Fan,Xinpan Li,Wenlu Ren,Rui Song Nanoscale, 2020,12, 7024-7034
-
David B. Cordes,Alexandra M. Z. Slawin,Stefania Righetto,Denis Jacquemin,Eli Zysman-Colman,Véronique Guerchais Dalton Trans., 2018,47, 8292-8300
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