- Enolate-Based Regioselective Anti-Beckmann C-C Bond Cleavage of KetonesMasek, Tomas; Jahn, Ullrich, Journal of Organic Chemistry, 2021, 86(17), 11608-11632
Cas no 622-32-2 ((Z)-Benzaldehyde oxime)
(Z)-Benzaldehyde oxime (CAS 622-31-1) is a stereospecific oxime derivative of benzaldehyde, characterized by its distinct (Z)-configuration around the C=N double bond. This compound serves as a versatile intermediate in organic synthesis, particularly in the preparation of heterocyclic compounds, pharmaceuticals, and agrochemicals. Its rigid structure and reactive oxime functional group enable selective transformations, such as Beckmann rearrangements or nucleophilic additions. The (Z)-isomer exhibits enhanced stability under certain conditions compared to its (E)-counterpart, making it preferable for controlled reactions. It is commonly employed in metal ligand systems due to its chelating properties. The compound is typically supplied as a white to off-white crystalline solid with high purity (>97%), ensuring reproducibility in research and industrial applications.
(Z)-Benzaldehyde oxime structure
Product Name:(Z)-Benzaldehyde oxime
CAS No:622-32-2
MF:C7H7NO
MW:121.136581659317
MDL:MFCD00063017
CID:506165
PubChem ID:5324470
Update Time:2025-07-02
(Z)-Benzaldehyde oxime Chemical and Physical Properties
Names and Identifiers
-
- (Z)-Benzaldehyde oxime
- (NZ)-N-benzylidenehydroxylamine
- Benzaldehyde, oxime, (Z)-
- SYN-BENZALDEHYDE OXIME
- (Z)-Benzaldoxime
- anti-Benzaldoxime
- Benzaldehyde oxime, cis
- cis-Benzaldoxime
- syn-Benzaldoxime
- (Z)-Benzaldehydeoxime
- Benzaldoxime, (Z)-
- CHEMBL265435
- BENZALDEHYDEOXIME
- 622-32-2
- 622-31-1
- NSC-154850
- (E)-benzaldehydeoxime
- 932-90-1
- NSC 154850
- BENZALDEHYDE, OXIME, (C(Z))-
- trans-Benzaldoxime
- D78196
- Z-Benzaldoxime
- (E)-Benzaldoxime
- (E)-Benzaldehyde oxime
- YR8F3Q0KSH
- SCHEMBL309201
- CS-0357523
- CIS-BENZALDEHYDE OXIME
- NS00039544
- Benzaldoxime
- Benzaldehyde, (Z)-
- DTXSID801031545
- (E)-N-(phenylmethylidene)hydroxylamine
- UNII-YR8F3Q0KSH
- NSC154850
-
- MDL： MFCD00063017
- Inchi： 1S/C7H7NO/c9-8-6-7-4-2-1-3-5-7/h1-6,9H/b8-6-
- InChI Key： VTWKXBJHBHYJBI-VURMDHGXSA-N
- SMILES： O/N=C\C1C=CC=CC=1
Computed Properties
- Exact Mass: 121.05281
- Monoisotopic Mass: 121.052764
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 1
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 9
- Rotatable Bond Count: 1
- Complexity: 95.1
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 1
- Undefined Bond Stereocenter Count: 0
- Surface Charge: 0
- Tautomer Count: 2
- XLogP3: nothing
- Topological Polar Surface Area: 32.6
Experimental Properties
- Color/Form: Acicular crystals
- Density: 1.1111
- Melting Point: 34-36?°C(lit.)
- Boiling Point: 200°C at 760 mmHg
- Flash Point: 228?°F
- Refractive Index: n20/D 1.591(lit.)
- Solubility: methanol: 0.1?g/mL, clear
- PSA: 32.59
- LogP: 1.49470
- Solubility: 0.1
(Z)-Benzaldehyde oxime Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| Alichem | A019142964-1g |
(Z)-Benzaldehyde oxime |
622-32-2 | 95% | 1g |
$465.60 | 2023-09-01 | |
| SHANG HAI MAI KE LIN SHENG HUA Technology Co., Ltd. | B886629-1g |
syn-Benzaldoxime |
622-32-2 | ≥95% | 1g |
2,239.20 | 2021-05-17 | |
| eNovation Chemicals LLC | Y0994596-1g |
(Z)-Benzaldehyde oxime |
622-32-2 | 95% | 1g |
$520 | 2024-08-02 | |
| SHANG HAI HAO HONG Biomedical Technology Co., Ltd. | 1428193-250mg |
(Z)-benzaldehyde oxime |
622-32-2 | 95+% | 250mg |
￥1310 | 2023-04-13 | |
| SHANG HAI HAO HONG Biomedical Technology Co., Ltd. | 1428193-1g |
(Z)-benzaldehyde oxime |
622-32-2 | 95+% | 1g |
￥3834 | 2023-04-13 | |
| 1PlusChem | 1P00EASV-250mg |
SYN-BENZALDEHYDE OXIME |
622-32-2 | ≥95% | 250mg |
$132.00 | 2024-04-22 | |
| 1PlusChem | 1P00EASV-1g |
SYN-BENZALDEHYDE OXIME |
622-32-2 | ≥95% | 1g |
$271.00 | 2024-04-22 | |
| Aaron | AR00EB17-250mg |
SYN-BENZALDEHYDE OXIME |
622-32-2 | 95% | 250mg |
$205.00 | 2025-02-11 | |
| Aaron | AR00EB17-1g |
SYN-BENZALDEHYDE OXIME |
622-32-2 | 1g |
$258.00 | 2023-12-14 | ||
| A2B Chem LLC | AG66383-250mg |
(Z)-Benzaldehyde oxime |
622-32-2 | ≥95% | 250mg |
$141.00 | 2024-04-19 |
(Z)-Benzaldehyde oxime Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Potassium bis(trimethylsilyl)amide Solvents: Tetrahydrofuran ; 2 min, cooled; 15 min, -78 °C
1.2 30 min, -78 °C; 4 h, -78 °C → 0 °C
1.2 30 min, -78 °C; 4 h, -78 °C → 0 °C
Reference
(Z)-Benzaldehyde oxime Raw materials
(Z)-Benzaldehyde oxime Preparation Products
(Z)-Benzaldehyde oxime Related Literature
-
Chen Long,Ying Dai,Jianwei Li,Hao Jin Nanoscale, 2020,12, 21124-21130
-
Dan Yang,Yanping Zhou,Xianhong Rui,Jixin Zhu,Ziyang Lu,Eileen Fong,Qingyu Yan RSC Adv., 2013,3, 14960-14962
-
Byungho Lim,Jaewon Jin,Jin Yoo,Seung Yong Han,Kyeongyeol Kim,Sungah Kang,Nojin Park,Sang Moon Lee,Hae Jin Kim,Seung Uk Son Chem. Commun., 2014,50, 7723-7726
-
Jonas Kind,Lukas Kaltschnee,Martin Leyendecker,Christina M. Thiele Chem. Commun., 2016,52, 12506-12509
622-32-2 ((Z)-Benzaldehyde oxime) Related Products
- 622-31-1(trans-Benzaldoxime)
- 24091-02-9(2-naphthaldehyde oxime)
- 932-90-1(Benzaldoxime)
- 18705-39-0(1,4-Benzenedicarboxaldehyde dioxime)
- 3235-02-7(N-(4-methylphenyl)methylidenehydroxylamine)
- 332062-08-5(Fmoc-S-3-amino-4,4-diphenyl-butyric acid)
- 1270529-38-8(1,2,3,4,5,6-Hexahydro-[2,3]bipyridinyl-6-ol)
- 2680771-01-9(4-cyclopentyl-3-{(prop-2-en-1-yloxy)carbonylamino}butanoic acid)
- 2098070-20-1(2-(3-(Pyridin-3-yl)-1H-pyrazol-1-yl)acetimidamide)
- 1444113-98-7(N-(3-cyanothiolan-3-yl)-2-[(2,2,2-trifluoroethyl)sulfanyl]pyridine-4-carboxamide)
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