- Phosphorus coordinated Rh single-atom sites on nanodiamond as highly regioselective catalyst for hydroformylation of olefinsGao, Peng; Liang, Guanfeng ; Ru, Tong; Liu, Xiaoyan ; Qi, Haifeng; et al, Nature Communications, 2021, 12(1),
Cas no 59452-89-0 (alpha,3-dimethyl-benzeneacetaldehyde)
59452-89-0 structure
Product Name:alpha,3-dimethyl-benzeneacetaldehyde
CAS No:59452-89-0
MF:C10H12O
MW:148.201683044434
CID:5057177
PubChem ID:58602882
Update Time:2024-03-01
alpha,3-dimethyl-benzeneacetaldehyde Chemical and Physical Properties
Names and Identifiers
-
- 2-m-Tolylpropanal
- 2-(3-methylphenyl)propanal
- 2-(m-tolyl)propanal
- 2-m-tolyl-propionaldehyde
- Benzeneacetaldehyde, alpha,3-dimethyl-
- alpha,3-dimethyl-benzeneacetaldehyde
-
- Inchi: 1S/C10H12O/c1-8-4-3-5-10(6-8)9(2)7-11/h3-7,9H,1-2H3
- InChI Key: BQOMLDKKNSTBKM-UHFFFAOYSA-N
- SMILES: O=CC(C)C1C=CC=C(C)C=1
Computed Properties
- Exact Mass: 148.088815002g/mol
- Monoisotopic Mass: 148.088815002g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 1
- Heavy Atom Count: 11
- Rotatable Bond Count: 2
- Complexity: 131
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 1
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- XLogP3: 2.3
- Topological Polar Surface Area: 17.1
alpha,3-dimethyl-benzeneacetaldehyde Pricemore >>
| Related Categories | No. | Product Name | Cas No. | Purity | Specification | Price | update time | Inquiry |
|---|---|---|---|---|---|---|---|---|
| TRC | B188843-10mg |
alpha,3-dimethyl-benzeneacetaldehyde |
59452-89-0 | 10mg |
$ 50.00 | 2022-06-07 | ||
| TRC | B188843-50mg |
alpha,3-dimethyl-benzeneacetaldehyde |
59452-89-0 | 50mg |
$ 210.00 | 2022-06-07 | ||
| TRC | B188843-100mg |
alpha,3-dimethyl-benzeneacetaldehyde |
59452-89-0 | 100mg |
$ 320.00 | 2022-06-07 | ||
| Enamine | EN300-1865870-0.05g |
2-(3-methylphenyl)propanal |
59452-89-0 | 95% | 0.05g |
$202.0 | 2023-09-18 | |
| Enamine | EN300-1865870-0.1g |
2-(3-methylphenyl)propanal |
59452-89-0 | 95% | 0.1g |
$301.0 | 2023-09-18 | |
| Enamine | EN300-1865870-0.25g |
2-(3-methylphenyl)propanal |
59452-89-0 | 95% | 0.25g |
$431.0 | 2023-09-18 | |
| Enamine | EN300-1865870-0.5g |
2-(3-methylphenyl)propanal |
59452-89-0 | 95% | 0.5g |
$679.0 | 2023-09-18 | |
| Enamine | EN300-1865870-1.0g |
2-(3-methylphenyl)propanal |
59452-89-0 | 95% | 1g |
$871.0 | 2023-06-01 | |
| Enamine | EN300-1865870-2.5g |
2-(3-methylphenyl)propanal |
59452-89-0 | 95% | 2.5g |
$1707.0 | 2023-09-18 | |
| Enamine | EN300-1865870-5.0g |
2-(3-methylphenyl)propanal |
59452-89-0 | 95% | 5g |
$2525.0 | 2023-06-01 |
alpha,3-dimethyl-benzeneacetaldehyde Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Hydrogen Catalysts: Rhodium Solvents: Toluene , Water ; 3 MPa, rt → 50 °C; 24 h, 50 °C
Reference
Production Method 2
Reaction Conditions
1.1 Reagents: Hydrogen Catalysts: Dicarbonylrhodium acetylacetonate , N,N′-[Propylidenebis(3-methyl-1H-indole-2,7-diyl)]bis[4-[(11bS)-dinaphtho[2,1-d:… (compound with Rh) Solvents: Dichloromethane ; 72 h, 20 bar, rt
Reference
- Beyond Classical Reactivity Patterns: Hydroformylation of Vinyl and Allyl Arenes to Valuable β- and γ-Aldehyde Intermediates Using Supramolecular CatalysisDydio, Pawel; Detz, Remko J.; de Bruin, Bas; Reek, Joost N. H., Journal of the American Chemical Society, 2014, 136(23), 8418-8429
Production Method 3
Reaction Conditions
1.1 Reagents: Hydrogen Catalysts: Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium , Sodium dodecylbenzenesulfonate , Benzenesulfonic acid, 2-[[bis[2-(diphenylphosphino)ethyl]amino]carbonyl]-, sodiu… Solvents: Toluene , Water ; 36 h, 4 MPa, 60 °C
Reference
- Synthesis of rac-α-aryl propionaldehydes via branched-selective hydroformylation of terminal arylalkenes using water-soluble Rh-PNP catalystGao, Peng; Ke, Miaolin; Ru, Tong; Liang, Guanfeng; Chen, Fen-Er, Chinese Chemical Letters, 2022, 33(2), 830-834
alpha,3-dimethyl-benzeneacetaldehyde Raw materials
alpha,3-dimethyl-benzeneacetaldehyde Preparation Products
alpha,3-dimethyl-benzeneacetaldehyde Related Literature
-
Maomao Hou,Fenglin Zhong,Qiu Jin,Enjiang Liu,Jie Feng,Tengyun Wang,Yue Gao RSC Adv., 2017,7, 34392-34400
-
Bo Wei,Zhenyu Liu,Chen Xie,Shu Yang,Wentao Tang,Aiwei Gu,Wing-Tak Wong,Ka-Leung Wong J. Mater. Chem. C, 2015,3, 12322-12327
-
Alexandre Vimont,Arnaud Travert,Philippe Bazin,Jean-Claude Lavalley,Marco Daturi,Christian Serre,Gérard Férey,Sandrine Bourrelly,Philip L. Llewellyn Chem. Commun., 2007, 3291-3293
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Gang Pan,Yi-jie Bao,Jie Xu,Tao Liu,Cheng Liu,Yan-yan Qiu,Xiao-jing Shi,Hui Yu,Ting-ting Jia,Xia Yuan,Ze-ting Yuan,Yi-jun Cao RSC Adv., 2016,6, 42109-42119
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Jacob S. Jordan,Evan R. Williams Analyst, 2021,146, 2617-2625
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