Production Method 1

745783-97-5

99-36-5

517920-56-8

929626-17-5

Reaction Conditions

1.1 Catalysts: (SP-5-23)-[3,8-Bis[3,5-bis(trifluoromethyl)phenyl]-1,10-phenanthroline-κN1,κN10]… Solvents: Methylcyclohexane ;  20 min, 100 °C

Reference

Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity

Larsen, Matthew A.; Wilson, Conner V.; Hartwig, John F., Journal of the American Chemical Society, 2015, 137(26), 8633-8643

Benzoic acid, 3-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-, methyl ester Raw materials

• Et3SiB(pinacolato)
• Methyl 3-methylbenzoate

Benzoic acid, 3-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-, methyl ester Preparation Products

• Benzoic acid, 3-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-, methyl ester (517920-56-8)
• Methyl 3-methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate (929626-17-5)

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