Production Method 1

73183-34-3

288101-48-4

863868-37-5

863868-36-4

Reaction Conditions

1.1 Catalysts: Sodium triethylborohydride ,  2094503-97-4 Solvents: Tetrahydrofuran ;  2 min, rt
1.2 Reagents: Cyclohexene ;  24 h, 100 °C

Reference

Cobalt-Catalyzed Regioselective Borylation of Arenes: N-Heterocyclic Silylene as an Electron Donor in the Metal-Mediated Activation of C-H Bonds

Ren, Hailong; et al, Chemistry - A European Journal, 2017, 23(24), 5663-5667

Production Method 2

25015-63-8

288101-48-4

863868-37-5

863868-36-4

Reaction Conditions

1.1 Reagents: Cyclohexene Catalysts: (SP-4-1)-[1,1′-(9,9-Dimethyl-9H-xanthene-4,5-diyl-κO)bis[1,1-bis(1-methylethyl)p… ;  24 h, 110 °C

Reference

POP-Rhodium-promoted C-H and B-H bond activation and C-B bond formation

Esteruelas, Miguel A.; et al, Organometallics, 2015, 34(10), 1911-1924

Production Method 3

73183-34-3

288101-48-4

863868-37-5

Reaction Conditions

1.1 Catalysts: [1,3-Bis(η2-ethenyl)-1,1,3,3-tetramethyldisiloxane](1,3-dicyclohexyl-1,3-dihydro… ;  20 h, 60 °C

Reference

C-H borylation by platinum catalysis

Furukawa, Takayuki; et al, Bulletin of the Chemical Society of Japan, 2017, 90(3), 332-342

Production Method 4

73183-34-3

288101-48-4

863868-37-5

863868-36-4

Reaction Conditions

1.1 Reagents: Butyllithium Catalysts: (SP-4-3)-Chloro[[2-(dicyclohexylphosphino-κP)phenyl][2-[(dimethylamino-κN)methyl… Solvents: Mesitylene ,  Hexane ;  rt; 4 h, 150 °C

Reference

Fluorine-controlled C-H borylation of arenes catalyzed by a PSiN-pincer platinum complex

Takaya, Jun; et al, Chemical Communications (Cambridge, 2015, 51(100), 17662-17665

Production Method 5

73183-34-3

288101-48-4

863868-37-5

863868-36-4

Reaction Conditions

1.1 Catalysts: [1,3-Bis(η2-ethenyl)-1,1,3,3-tetramethyldisiloxane](1,3-dicyclohexyl-1,3-dihydro… Solvents: 1,3-Difluorobenzene ;  20 h, 80 °C

Reference

C-H Functionalization at Sterically Congested Positions by the Platinum-Catalyzed Borylation of Arenes

Furukawa, Takayuki; et al, Journal of the American Chemical Society, 2015, 137(38), 12211-12214

Production Method 6

25015-63-8

288101-48-4

863868-37-5

863868-36-4

Reaction Conditions

1.1 Catalysts: Iridium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][1,3-propanediylbis(3-methyl-1H-imi… Solvents: 1,3-Difluorobenzene ;  30 min, 180 °C

Reference

Iridium complexes of N-heterocyclic carbenes in C-H borylation using energy efficient microwave technology: influence of structure, ligand donor strength and counter ion on catalytic activity

Rentzsch, Christoph F.; et al, Green Chemistry, 2009, 11(10), 1610-1617

Production Method 7

25015-63-8

288101-48-4

863868-37-5

863868-36-4

Reaction Conditions

1.1 Catalysts: 2489284-98-0 Solvents: Cyclohexene ;  18 h, 110 °C

Reference

Direct C-H Borylation of Arenes Catalyzed by Saturated Hydride-Boryl-Iridium-POP Complexes: Kinetic Analysis of the Elemental Steps

Esteruelas, Miguel A. ; et al, Chemistry - A European Journal, 2020, 26(55), 12632-12644

Production Method 8

73183-34-3

288101-48-4

863868-37-5

Reaction Conditions

1.1 Reagents: Butyllithium Catalysts: (SP-4-3)-[[2-[Bis(1-methylethyl)phosphino-κP]phenyl][2-[(dimethylamino-κN)methyl… Solvents: Mesitylene ,  Hexane ;  rt; 4 h, 150 °C

Reference

Fluorine-controlled C-H borylation of arenes catalyzed by a PSiN-pincer platinum complex

Takaya, Jun; et al, Chemical Communications (Cambridge, 2015, 51(100), 17662-17665

2,4-Difluorophenylboronic acid, pinacol ester Raw materials

• Bis(pinacolato)diborane
• Pinacolborane

2,4-Difluorophenylboronic acid, pinacol ester Preparation Products

• 2,6-Difluorophenylboronic acid, pinacol ester (863868-37-5)
• 2,4-Difluorophenylboronic acid, pinacol ester (288101-48-4)
• 2-(3,5-Difluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (863868-36-4)

• 1. Dissociative dynamics of O2 on Ag(110)?
  Ivor Lon?ari? Phys. Chem. Chem. Phys., 2015,17, 9436-9445
• 2. Excellent energy storage performance in NaNbO3-based relaxor antiferroeic ceramics under a low electric field
  XuxinCheng,XiaomingChen,PengyuanFan
• 3. Excellent mechanical performance and enhanced dielectric properties of OBC/SiO2 elastomeric nanocomposites: effect of dispersion of the SiO2 nanoparticles?
  Xing Zhao,Lu Bai,Rui-Ying Bao,Zheng-Ying Liu,Ming-Bo Yang,Wei Yang RSC Adv., 2017,7, 46297-46305
• 4. Fatty acid eutectic mixtures and derivatives from non-edible animal fat as phase change materials?
  Pau Gallart-Sirvent,Marc Martín,Gemma Villorbina,Mercè Balcells,Aran Solé,Luisa F. Cabeza,Ramon Canela-Garayoa RSC Adv., 2017,7, 24133-24139
• 5. Evidence for the intrinsic nature of band-gap states electrochemically observed on atomically flat TiO2(110) surfaces?
  Shintaro Takata,Yoshihiro Miura Phys. Chem. Chem. Phys., 2014,16, 24784-24789

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzene and substituted derivatives Halobenzenes Fluorobenzenes

• 1073339-20-4(4,4,5,5-tetramethyl-2-(2,3,4,5-tetrafluorophenyl)-1,3,2-dioxaborolane)
• 863868-37-5(2,6-Difluorophenylboronic acid, pinacol ester)
• 408492-24-0(2,2',2''-(2,4,6-Trifluorobenzene-1,3,5-triyl)tris(4,4,5,5-tetramethyl-1,3,2-dioxaborolane))
• 876062-39-4(2-(2-Fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
• 303006-90-8(2-[2,5-difluoro-4-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
• 819057-45-9(3-Fluoro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline)
• 214360-58-4(4-Fluorophenylboronic acid, pinacol ester)
• 1073339-11-3(4,4,5,5-tetramethyl-2-(2,3,5,6-tetrafluorophenyl)-1,3,2-dioxaborolane)
• 863868-36-4(2-(3,5-Difluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
• 325142-81-2(4,4,5,5-Tetramethyl-2-(perfluorophenyl)-1,3,2-dioxaborolane)