Production Method 1

111-70-6

264-09-5

141-93-5

931-88-4

2146-37-4

930-18-7

690-08-4

52161-57-6

16327-38-1

575-37-1

19037-72-0

624-64-6

824-90-8

622-96-8

3404-65-7

616-12-6

691-38-3

824-22-6

14686-13-6

2808-79-9

Reaction Conditions

1.1 Catalysts: Vanadium ;  100 - 550 °C

Reference

Catalytic conversion of alcohols having at least three carbon atoms to hydrocarbon blendstock

, World Intellectual Property Organization, , ,

7H-Benzocycloheptene Raw materials

• 1-Heptanol

7H-Benzocycloheptene Preparation Products

• 1,3-DIETHYLBENZENE (141-93-5)
• Cyclooctene (931-88-4)
• Ethylidenecyclopentane (2146-37-4)
• Cyclopropane,1,2-dimethyl-, (1R,2S)-rel- (930-18-7)
• 2-Pentene,4,4-dimethyl-, (2E)- (690-08-4)
• Benzene, 1-methyl-3-(1-methyl-2-propenyl)- (52161-57-6)
• Cyclobutene, 3,3-dimethyl- (16327-38-1)
• 1,7-Dimethylnaphthalene (575-37-1)
• Cyclopentene,4,4-dimethyl- (19037-72-0)
• 2-BUTENE (624-64-6)
• Benzene, 1-buten-1-yl- (824-90-8)
• 4-Ethyltoluene (622-96-8)
• 7H-Benzocycloheptene (264-09-5)
• 3-methyl-3-hexene (c,t) (3404-65-7)
• 2-Pentene, 3-methyl-,(2E)- (616-12-6)
• cis-4-Methyl-2-pentene (691-38-3)
• 4-Methylindan (824-22-6)
• 2-Heptene, (2E)- (14686-13-6)
• Cyclohexene,1,4-dimethyl- (2808-79-9)

• 1. Formation of bicyclic polycyclic aromatic hydrocarbons (PAHs) from the reaction of a phenyl radical with cis-3-penten-1-yne
  Mingrui Wei,Tingting Zhang,Xianfeng Chen,Fuwu Yan,Guanlun Guo,Dongju Zhang RSC Adv. 2018 8 13226
• 2. Photoinduced molecular transformations. Part 152. Ring expansion based on a sensitized [2 + 2] photoaddition of enol ethers of cyclic ketones with olefins, followed by a β-scission of alkoxyl radicals generated from the resulting cyclobutanols. Two-carbon ring expansion of β-indanone, β-tetralone and β-suberone
  Hiroshi Suginome,Toshihiro Takeda,Masahito Itoh,Yutaka Nakayama,Kazuhiro Kobayashi J. Chem. Soc. Perkin Trans. 1 1995 49
• 3. Rhodium-catalyzed migrative annulation and olefination of 2-aroylpyrroles with diazoesters
  Daniil M. Strashkov,Kirill V. Zavyalov,Pavel A. Sakharov,Anastasiya V. Agafonova,Nikolai V. Rostovskii,Alexander F. Khlebnikov,Mikhail S. Novikov Org. Chem. Front. 2023 10 506
• 4. Selenium analogues of rintodestrant (G1T48) as potent estrogen receptor modulators and downregulators
  Edgars Paegle,Pavels Dimitrijevs,Pavel Arsenyan New J. Chem. 2023 47 15472
• 5. Synthesis of an isolable 4aH-benzocycloheptene, ethyl 4-methoxy-4a-methyl-4aH-benzocycloheptene-5-carboxylate, and a study of its thermal rearrangement
  Robert H. Bradbury,Thomas L. Gilchrist,Charles W. Rees J. Chem. Soc. Perkin Trans. 1 1981 3225

• Solvents and Organic Chemicals Organic Compounds Benzenoids Benzenoids
• Solvents and Organic Chemicals Organic Compounds Benzenoids

• 22430-64-4(4,6-Dimethyl-1H-indene)
• 7344-34-5(4-methyl-1h-indene)
• 7372-92-1(7-methyl-1H-indene)
• 95-13-6(Indene)
• 6974-97-6(4,7-Dimethyl-1H-indene)
• 2098070-20-1(2-(3-(Pyridin-3-yl)-1H-pyrazol-1-yl)acetimidamide)
• 2680771-01-9(4-cyclopentyl-3-{(prop-2-en-1-yloxy)carbonylamino}butanoic acid)
• 1444113-98-7(N-(3-cyanothiolan-3-yl)-2-[(2,2,2-trifluoroethyl)sulfanyl]pyridine-4-carboxamide)
• 332062-08-5(Fmoc-S-3-amino-4,4-diphenyl-butyric acid)
• 1270529-38-8(1,2,3,4,5,6-Hexahydro-[2,3]bipyridinyl-6-ol)