Production Method 1

35322-87-3

119947-37-4

206877-36-3

Reaction Conditions

1.1R:KOH, R:NaBH4, S:EtOH
2.1R:H2O2, S:AcOH
3.1

Reference

Stable endoperoxide of 4,5,6,8,16-pentamethyl[2.2]metacyclophane; structural analysis and deoxygenation

By Sawada, Tsuyoshi et al, Journal of the Chemical Society, 1998, (8), 1369-1372

Production Method 2

3022-16-0

35322-87-3

206877-36-3

206877-37-4

Reaction Conditions

1.1R:S=C(NH2)2, S:DMSO, 14 h, rt
1.2R:NaOH, S:H2O, 1 h, rt
1.3R:HCl, S:H2O, acidify
2.1R:KOH, R:NaBH4, S:EtOH, S:Benzene, 12 h, rt
3.1R:P(OEt)3, S:P(OEt)3, 6 h, rt
3.2R:NaOH, S:H2O, cooled; 3 h, rt
4.1C:MeNO2, C:AlCl3, S:Benzene, 3 h, 50°C

Reference

Synthesis of polymethyl substituted [2.2]metaparacyclophanes and their Lewis-acid induced isomerization to [2.2]metacyclophanes

By Shimizu, Tomoe et al, Journal of Chemical Research, 2009, (4), 244-247

Tricyclo[9.3.1.14,8]hexadeca-1(15),4,6,8(16),11,13-hexaene, 13-(1,1-dimethylethyl)-5,6,7,15,16-pentamethyl- Raw materials

• Benzene,1,4-bis(chloromethyl)-2,3,5,6-tetramethyl-
• Benzene, 1,3-bis(chloromethyl)-5-(1,1-dimethylethyl)-2-methyl-
• 1,3-Benzenedimethanethiol, 2,4,5,6-tetramethyl-

Tricyclo[9.3.1.14,8]hexadeca-1(15),4,6,8(16),11,13-hexaene, 13-(1,1-dimethylethyl)-5,6,7,15,16-pentamethyl- Preparation Products

• Tricyclo[9.3.1.14,8]hexadeca-1(15),4,6,8(16),11,13-hexaene, 5,6,7,15,16-pentamethyl- (206877-37-4)
• Tricyclo[9.3.1.14,8]hexadeca-1(15),4,6,8(16),11,13-hexaene, 13-(1,1-dimethylethyl)-5,6,7,15,16-pentamethyl- (206877-36-3)

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