- B-H Bond Cleavage via Metal-Ligand Cooperation by Dearomatized Ruthenium Pincer ComplexesBy Anaby, Aviel et al, Organometallics, 2014, 33(14), 3716-3726
Cas no 1617495-63-2 (Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)-)
![Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)- structure](https://ossimg.kuujia.com/scimg/1617500/1617495-63-2x500.png)
1617495-63-2 structure
Product Name:Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)-
CAS No:1617495-63-2
MF:C30H57BNO3P2Ru
MW:653.607010602951
CID:5688777
Update Time:2023-10-13
Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)- Chemical and Physical Properties
Names and Identifiers
-
- (SP-5-52)-[6-[[Bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydroruthenium
- Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)-
-
- Inchi： 1S/C29H53BNO2P2.CHO.Ru.H/c1-24(2,3)34(25(4,5)6)20-21-18-17-19-22(31-21)23(35(26(7,8)9)27(10,11)12)30-32-28(13,14)29(15,16)33-30;1-2;;/h17-19H,20H2,1-16H3;1H;;/q-1;;+1;/p+2/b23-22-;;;
- InChI Key： OTUDZMQSULCRMZ-GMJJEYKASA-P
- SMILES： C([Ru+2]12(N3C(=CC=CC3=C(B3OC(C)(C)C(C)(C)O3)P1(C(C)(C)C)C(C)(C)C)CP2(C(C)(C)C)C(C)(C)C)[H])=O
Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)- Production Method
Production Method 1
Reaction Conditions
1.1C:863971-63-5, 48 h, 150°C
2.1S:THF, rt; 30 min, rt
1.1S:C6D6, rt
2.1S:C6D6, 16 h, rt → 80°C
2.1S:THF, rt; 30 min, rt
1.1S:C6D6, rt
2.1S:C6D6, 16 h, rt → 80°C
Reference
Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)- Raw materials
- Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP]methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)-
- Bis(pinacolato)diborane
Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)- Preparation Products
Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)- Related Literature
-
Xiaotong Feng,Lei Bian,Jie Ma,Lei Zhou,Xiayan Wang,Guangsheng Guo,Qiaosheng Pu Chem. Commun., 2019,55, 3963-3966
-
Vitaly Gurylev,Chung-Yi Su,Tsong-Pyng Perng Phys. Chem. Chem. Phys., 2016,18, 16033-16038
-
Yaling Zhang,Chunhui Dai,Shiwei Zhou,Bin Liu Chem. Commun., 2018,54, 10092-10095
-
Manickam Bakthadoss,Tadiparthi Thirupathi Reddy,Vishal Agarwal,Duddu S. Sharada Chem. Commun., 2022,58, 1406-1409
-
Jason Y. C. Lim,Yong Yu,Guorui Jin,Kai Li,Yi Lu,Jianping Xie Nanoscale Adv., 2020,2, 3921-3932
1617495-63-2 (Ruthenium, [6-[[bis(1,1-dimethylethyl)phosphino-κP]methyl]-2-[[bis(1,1-dimethylethyl)phosphino-κP](4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methylene]-1,2-dihydropyridinato-κN]carbonylhydro-, (SP-5-52)-) Related Products
- 332062-08-5(Fmoc-S-3-amino-4,4-diphenyl-butyric acid)
- 1270529-38-8(1,2,3,4,5,6-Hexahydro-[2,3]bipyridinyl-6-ol)
- 2680771-01-9(4-cyclopentyl-3-{(prop-2-en-1-yloxy)carbonylamino}butanoic acid)
- 2098070-20-1(2-(3-(Pyridin-3-yl)-1H-pyrazol-1-yl)acetimidamide)
- 1444113-98-7(N-(3-cyanothiolan-3-yl)-2-[(2,2,2-trifluoroethyl)sulfanyl]pyridine-4-carboxamide)
- 941977-17-9(N'-(3-chloro-2-methylphenyl)-N-2-(dimethylamino)-2-(naphthalen-1-yl)ethylethanediamide)
- 2138166-62-6(2,2-Difluoro-3-[methyl(2-methylbutyl)amino]propanoic acid)
- 89640-58-4(2-Iodo-4-nitrophenylhydrazine)
- 1449132-38-0(3-Fluoro-5-(2-fluoro-5-methylbenzylcarbamoyl)benzeneboronic acid)
- 2034271-14-0(2-(1H-indol-3-yl)-N-{[6-(thiophen-2-yl)-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]methyl}acetamide)
Recommended suppliers
上海帛亦醫(yī)藥科技有限公司
Gold Member
Audited Supplier
CN Supplier
Reagent
煙臺朗裕新材料科技有限公司
Gold Member
Audited Supplier
CN Supplier
Reagent
Xiamen PinR Bio-tech Co., Ltd.
Gold Member
Audited Supplier
CN Supplier
Bulk
Enjia Trading Co., Ltd
Gold Member
Audited Supplier
CN Supplier
Bulk
PRIBOLAB PTE.LTD
Gold Member
Audited Supplier
CN Supplier
Reagent
