- Propylene hydroformylation processes using bisphosphine ligands as catalysts, World Intellectual Property Organization, , ,
Cas no 154635-18-4 (Phosphine, [(1R,3S)-1,3-dimethyl-1,3-propanediyl]bis[diphenyl-, rel- (9CI))
154635-18-4 structure
Product Name:Phosphine, [(1R,3S)-1,3-dimethyl-1,3-propanediyl]bis[diphenyl-, rel- (9CI)
CAS No:154635-18-4
MF:C29H30P2
MW:440.496029376984
CID:1329381
Update Time:2023-04-02
Phosphine, [(1R,3S)-1,3-dimethyl-1,3-propanediyl]bis[diphenyl-, rel- (9CI) Chemical and Physical Properties
Names and Identifiers
-
- Phosphine, [(1R,3S)-1,3-dimethyl-1,3-propanediyl]bis[diphenyl-, rel-
- Phosphine, [(1R,3S)-1,3-dimethyl-1,3-propanediyl]bis[diphenyl-, rel- (9CI)
-
- Inchi: 1S/C29H30P2/c1-24(30(26-15-7-3-8-16-26)27-17-9-4-10-18-27)23-25(2)31(28-19-11-5-12-20-28)29-21-13-6-14-22-29/h3-22,24-25H,23H2,1-2H3/t24-,25+
- InChI Key: CTYPJIUQROQJBG-PLQXJYEYSA-N
- SMILES: [C@@H](P(C1=CC=CC=C1)C1=CC=CC=C1)(C)C[C@@H](P(C1=CC=CC=C1)C1=CC=CC=C1)C
Phosphine, [(1R,3S)-1,3-dimethyl-1,3-propanediyl]bis[diphenyl-, rel- (9CI) Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran , Hexane ; 15 min, 0 °C; 30 min, 0 °C; 2 h, rt; rt → 0 °C
1.2 Solvents: Tetrahydrofuran ; 30 min, 0 °C; 0 °C → rt; overnight, rt
1.2 Solvents: Tetrahydrofuran ; 30 min, 0 °C; 0 °C → rt; overnight, rt
Reference
Phosphine, [(1R,3S)-1,3-dimethyl-1,3-propanediyl]bis[diphenyl-, rel- (9CI) Raw materials
- 2,4-Pentanediol, 2,4-dimethanesulfonate, (2R,4S)-rel-
- 2,4-Pentanediol, dimethanesulfonate, (2S,4S)-
- 2,4-Pentanediol, 2,4-dimethanesulfonate, (2R,4R)-
- Diphenylphosphine
Phosphine, [(1R,3S)-1,3-dimethyl-1,3-propanediyl]bis[diphenyl-, rel- (9CI) Preparation Products
Phosphine, [(1R,3S)-1,3-dimethyl-1,3-propanediyl]bis[diphenyl-, rel- (9CI) Related Literature
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Ni-Na Sun,Fengli Qu,Xiaobing Zhang,Shufang Zhang,Jinmao You Analyst, 2015,140, 1827-1831
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Huabin Zhang,Shaowu Du CrystEngComm, 2014,16, 4059-4068
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S. Amaresh,K. Karthikeyan,K. J. Kim,Y. S. Lee RSC Adv., 2014,4, 23107-23115
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Yaqing Liu,Jiangtao Ren,Jing Li,Jiyang Liu,Erkang Wang Chem. Commun., 2012,48, 802-804
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