- Rhodium(I)-Catalyzed Sequential C(sp)-C(sp3) and C(sp3)-C(sp3) Bond Formation through Migratory Carbene InsertionXia, Ying; Feng, Sheng; Liu, Zhen; Zhang, Yan; Wang, Jianbo, Angewandte Chemie, 2015, 54(27), 7891-7894
Cas no 125251-42-5 (Silane, 1,3-butadiyne-1,4-diylbis[tris(1-methylethyl)-)
125251-42-5 structure
Product Name:Silane, 1,3-butadiyne-1,4-diylbis[tris(1-methylethyl)-
CAS No:125251-42-5
MF:C22H42Si2
MW:362.73988866806
CID:1221384
PubChem ID:11405807
Update Time:2025-04-20
Silane, 1,3-butadiyne-1,4-diylbis[tris(1-methylethyl)- Chemical and Physical Properties
Names and Identifiers
-
- tri(propan-2-yl)-[4-tri(propan-2-yl)silylbuta-1,3-diynyl]silane
- 1,4-bis(triisopropylsilyl)buta-1,3-diyne
- 125251-42-5
- (Butane-1,3-diyne-1,4-diyl)bis(triisopropylsilane)
- CS-0254981
- DTXSID20464928
- Silane, 1,3-butadiyne-1,4-diylbis[tris(1-methylethyl)-
-
- Inchi： 1S/C22H42Si2/c1-17(2)23(18(3)4,19(5)6)15-13-14-16-24(20(7)8,21(9)10)22(11)12/h17-22H,1-12H3
- InChI Key： OICLCUORDURFKG-UHFFFAOYSA-N
- SMILES： [Si](C#CC#C[Si](C(C)C)(C(C)C)C(C)C)(C(C)C)(C(C)C)C(C)C
Computed Properties
- Exact Mass: 362.28266
- Monoisotopic Mass: 362.28250441g/mol
- Isotope Atom Count: 0
- Hydrogen Bond Donor Count: 0
- Hydrogen Bond Acceptor Count: 0
- Heavy Atom Count: 24
- Rotatable Bond Count: 9
- Complexity: 430
- Covalently-Bonded Unit Count: 1
- Defined Atom Stereocenter Count: 0
- Undefined Atom Stereocenter Count : 0
- Defined Bond Stereocenter Count: 0
- Undefined Bond Stereocenter Count: 0
- Topological Polar Surface Area: 0?2
Experimental Properties
- PSA: 0
Silane, 1,3-butadiyne-1,4-diylbis[tris(1-methylethyl)- Production Method
Production Method 1
Reaction Conditions
1.1 Reagents: Sodium methoxide , Benzeneacetic acid, α-diazo-, methyl ester Catalysts: Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-hydroxydirhodium , BINAP Solvents: Toluene ; 1 h, 90 °C; 90 °C → rt
Reference
Silane, 1,3-butadiyne-1,4-diylbis[tris(1-methylethyl)- Raw materials
Silane, 1,3-butadiyne-1,4-diylbis[tris(1-methylethyl)- Preparation Products
Silane, 1,3-butadiyne-1,4-diylbis[tris(1-methylethyl)- Related Literature
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Dhirendra K. Chaudhary,Pramendra Kumar,Lokendra Kumar RSC Adv., 2016,6, 94731-94738
-
Jacob S. Jordan,Evan R. Williams Analyst, 2021,146, 2617-2625
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Qiaoe Wang,Meiling Lian,Xiaowen Zhu,Xu Chen RSC Adv., 2021,11, 192-197
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Bo Wei,Zhenyu Liu,Chen Xie,Shu Yang,Wentao Tang,Aiwei Gu,Wing-Tak Wong,Ka-Leung Wong J. Mater. Chem. C, 2015,3, 12322-12327
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David White,Sean R. Stowell Biomater. Sci., 2017,5, 463-474
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