Production Method 1

92-84-2

1207-71-2

Reaction Conditions

1.1 Reagents: Carbamide peroxide Catalysts: Urea sulfate Solvents: Methanol ;  3 h, rt

Reference

Uronium Hydrogen Sulfate/Urea-Hydrogen Peroxide as a Green and Metal-Free Catalytic System for the Efficient, Chemo-, and Homoselective Oxidation of Sulfides to Sulfoxides

Hasaninejad, Alireza; Chehardoli, Gholamabbas; Zolfigol, Mohammad Ali; Abdoli, Abbas, Phosphorus, 2011, 186(2), 271-280

Production Method 2

92-84-2

1207-71-2

Reaction Conditions

1.1 Reagents: Carbamide peroxide Catalysts: 12-Molybdophosphoric acid Solvents: Methanol ;  10 min, rt

Reference

Molybdatophosphoric acid as an efficient catalyst for the catalytic and chemoselective oxidation of sulfides to sulfoxides using urea hydrogen peroxide as a commercially available oxidant

Hasaninejad, Alireza; Ali Zolfigol, Mohammad; Chehardoli, Gholamabbas; Mokhlesi, Mohammad, Journal of the Serbian Chemical Society, 2010, 75(3), 307-316

Production Method 3

92-84-2

1207-71-2

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Solvents: Acetic acid ;  < 45 °C

Reference

Monomeric and Polymeric Phenothiazine Photosensitizers for Photoinitiated Cationic Polymerization

Gomurashvili, Zaza; Crivello, James V., Macromolecules, 2002, 35(8), 2962-2969

Production Method 4

1628-29-1

1207-71-2

1217-37-4

Reaction Conditions

1.1 Reagents: Sucrose ,  Potassium chloride ,  Sulfuric acid magnesium salt (1:1) ,  Monosodium phosphate ,  Sodium nitrate ,  Sodium chloride ,  Ferrous sulfate ,  Manganese sulfate Solvents: Dimethylformamide ,  Water ;  72 h, pH 5, 28 °C

Reference

Biotransformation of N-acetylphenothiazine by fungi

Parshikov, I. A.; Freeman, J. P.; Williams, A. J.; Moody, J. D.; Sutherland, J. B., Applied Microbiology and Biotechnology, 1999, 52(4), 553-557

Production Method 5

92-84-2

1207-71-2

Reaction Conditions

1.1 Reagents: 1H,5H-[1,2]Diselenolo[1,2-a][1,2]diselenolium, tetrahydro-, hexafluorophosphate(… Solvents: Acetonitrile
1.2 Reagents: Water

Reference

Reactivity of diselenide dication salt, 1,5-diselenoniabicyclo[3.3.0]octane bis(hexafluorophosphate), toward aromatics. A new mode of aromatic substitution and redox reaction

Fujihara, Hisashi; Nakamura, Akiko; Akaishi, Ryouichi; Furukawa, Naomichi, Chemistry Letters, 1990, (3), 393-6

Production Method 6

92-84-2

1207-71-2

Reaction Conditions

Reference

Fate of amine antioxidants during thermal oxidative aging of neopentylpolyl ester oils

Zeman, A.; Von Roenne, V.; Trebert, Y., Journal of Synthetic Lubrication, 1987, 4(3), 179-201

Production Method 7

58-40-2

1207-71-2

146-21-4

581-30-6

Reaction Conditions

1.1 Reagents: Iodylbenzene ,  Vanadyl acetylacetonate Solvents: Benzene

Reference

Biomimetic oxidation of some nitrogen-containing compounds by the iodoxybenzene-vanadyl acetylacetonate complex

Barret, R.; Pautet, F.; Daudon, M., Pharmazie, 1986, 41(4), 285-6

Production Method 8

262-71-5

1207-71-2

92-84-2

22253-91-4

96120-83-1

1918-37-2

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Solvents: Methanol

Reference

Cyclohepta[b][1,4]benzothiazines and their diazine analogs. 1. Formation and reactions of cyclohepta[b][1,4]benzothiazines

Shindo, Kimio; Ishikawa, Sumio; Nozoe, Tetsuo, Bulletin of the Chemical Society of Japan, 1985, 58(1), 165-71

Production Method 9

92-84-2

1207-71-2

Reaction Conditions

1.1 Reagents: Hydrogen peroxide ,  Potassium(1+), (1,4,7,10,13,16-hexaoxacyclooctadecane-κO1,κO4,κO7,κO10,κO13,κO16… Solvents: Acetonitrile ,  Water ;  35 min, reflux

Reference

H2O2 as a green and environmentally benign reagent for the oxidation of sulfides in the presence of {[K.18-Crown-6]X3}n (X=Br, I) compared with some other organic tribromides

Rasouli, Mohsen; Zolfigol, Mohammad Ali; Moslemin, Mohammad Hossien; Mohebat, Razieh; Chehardoli, Gholamabbas, Eurasian Chemical Communications, 2020, 2(1), 44-50

Production Method 10

606493-61-2

1207-71-2

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Catalysts: Cobalt (intercalated molybdenum disulfde) Solvents: Acetonitrile ;  20 min, 40 °C

Reference

Cobalt Single-Atom-Intercalated Molybdenum Disulfide for Sulfide Oxidation with Exceptional Chemoselectivity

Chen, Zhongxin ; Liu, Cuibo; Liu, Jia; Li, Jing; Xi, Shibo ; et al, Advanced Materials (Weinheim, 2020, 32(4),

Production Method 11

92-84-2

1207-71-2

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Catalysts: 2360866-41-5 Solvents: Acetonitrile ,  Water ;  12 h, rt

Reference

Pyridiniumporphyrazinato oxo-vanadium tribromomethanide as a new source of Br+ catalyst for the chemo and homoselective oxidation of sulfides and benzylic alcohols

Safaiee, Maliheh; Moeinimehr, Mahtab; Zolfigol, Mohammad Ali, Polyhedron, 2019, 170, 138-150

Production Method 12

92-84-2

1207-71-2

Reaction Conditions

1.1 Reagents: Oxalic acid ,  Hydrogen peroxide Solvents: Water ;  12 - 15 h, rt

Reference

Hydrodeoxygenation of sulfoxides to sulfides by a Pt and MoOx co-loaded TiO2 catalyst

Touchy, Abeda Sultana; Hakim Siddiki, S. M. A.; Onodera, Wataru; Kon, Kenichi; Shimizu, Ken-ichi, Green Chemistry, 2016, 18(8), 2554-2560

Production Method 13

92-84-2

1207-71-2

Reaction Conditions

1.1 Reagents: 1,3,5-Benzenetricarboxylic acid Solvents: Tetrahydrofuran ;  rt

Reference

10H-Phenothiazine 5-oxide

Jin, Rui-Fang; Yu, Kai; Yang, Shi-Yao; Huang, Rong-Bin, Acta Crystallographica, 2010, 66(12),

Production Method 14

92-84-2

1207-71-2

1209-66-1

Reaction Conditions

1.1 Reagents: Hydrogen peroxide Catalysts: Thermolysin Solvents: tert-Butanol ,  Water

Reference

Metal substitution in thermolysin: catalytic properties of tungstate thermolysin in sulfoxidation with H2O2

Bakker, Martin; Van Rantwijk, Fred; Sheldon, Roger A., Canadian Journal of Chemistry, 2002, 80(6), 622-625

Production Method 15

300686-85-5

1207-71-2

Reaction Conditions

1.1 Reagents: Hydrochloric acid

Reference

N-Heteroarylethylenes. II. Effect of the nature of the heterocycle on reactivity of cis- and trans-N-propenyl-substituted phenoxazine, phenothiazine, and carbazole in acidic hydrolysis

Khlebnikova, A. I.; Anfinogenov, V. A.; Filimonov, V. D.; Sokolova, I. V., Zhurnal Organicheskoi Khimii, 1989, 25(7), 1547-53

Production Method 16

112101-33-4

1207-71-2

Reaction Conditions

1.1 Reagents: Water Catalysts: Tetracyanoethylene Solvents: Water

Reference

Structure and hydrolytic activity of N-vinyl derivatives of phenothiazine, carbazole and acridone

Kurov, G. N.; Afonin, A. V.; Svyatkina, L. I.; Dmitrieva, L. L.; Pal'chuk, E. G., Izvestiya Akademii Nauk SSSR, 1987, (2), 444-7

Production Method 17

1207-72-3

1207-71-2

581-30-6

2234-09-5

Reaction Conditions

1.1 Reagents: Iodylbenzene Catalysts: Vanadyl acetylacetonate Solvents: Benzene

Reference

Oxidation of phenothiazine and its N-methyl derivatives by iodoxylbenzene-vanadyl acetylacetonate

Pautet, F.; Barret, R.; Daudon, M., Pharmazie, 1985, 40(3), 202-3

10H-Phenothiazine 5-Oxide Raw materials

• Phenothiazine
• Promazine
• 10-Acetylphenothiazine
• 10H-Phenothiazine, 10-(1-propen-1-yl)-, 5-oxide
• Benzo[b]cyclohepta[e][1,4]thiazine
• 10-Methylphenothiazine
• 10-ethenylphenothiazine 5-oxide
• 10H-Phenothiazine,4a,10a-dihydro-

10H-Phenothiazine 5-Oxide Preparation Products

• Phenothiazine (92-84-2)
• Promazine Sulfoxide (146-21-4)
• Phenothiazine S,S-Dioxide (1209-66-1)
• 3H-Phenothiazin-3-one (581-30-6)
• 10H-Phenothiazine-3-carboxaldehyde (22253-91-4)
• Methylphenothiazine Sulfoxide (2234-09-5)
• 10H-Phenothiazine 5-Oxide (1207-71-2)
• Ethanone,1-(5-oxido-10H-phenothiazin-10-yl)- (1217-37-4)
• 10H-Phenothiazine-1-carboxaldehyde, 5-oxide (96120-83-1)
• 10H-Phenothiazine-1-carboxaldehyde (1918-37-2)

• 1. Examination of ammonia–poly(pyrrole) interactions by piezoelectric and conductivity measurements
  Analyst, 1991,116, 1125-1130
• 2. Excellent mechanical performance and enhanced dielectric properties of OBC/SiO2 elastomeric nanocomposites: effect of dispersion of the SiO2 nanoparticles?
  Xing Zhao,Lu Bai,Rui-Ying Bao,Zheng-Ying Liu,Ming-Bo Yang,Wei Yang RSC Adv., 2017,7, 46297-46305
• 3. Ester-directed orthogonal dual C–H activation and ortho aryl C–H alkenylation via distal weak coordination?
  Manickam Bakthadoss,Tadiparthi Thirupathi Reddy,Vishal Agarwal,Duddu S. Sharada Chem. Commun., 2022,58, 1406-1409
• 4. Enabling shape memory and healable effects in a conjugated polymer by incorporating siloxane via dynamic imine bond?
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• 5. Evidence of CO2 molecule acting as an electron acceptor on a nanoporous metal–organic-framework MIL-53 or Cr3+(OH)(O2C–C6H4–CO2)?
  Alexandre Vimont,Arnaud Travert,Philippe Bazin,Jean-Claude Lavalley,Marco Daturi,Christian Serre,Gérard Férey,Sandrine Bourrelly,Philip L. Llewellyn Chem. Commun., 2007, 3291-3293

• Solvents and Organic Chemicals Organic Compounds Organoheterocyclic compounds Benzothiazines Phenothiazines

• 52914-17-7(Benzenamine, N-phenyl-2-(phenylsulfonyl)-)
• 1209-66-1(Phenothiazine S,S-Dioxide)
• 27612-10-8(10H-Phenothiazine,2-(methylsulfinyl)-)
• 18587-32-1(12h-Benzo[b]phenothiazine 5,5-dioxide)
• 2234-09-5(Methylphenothiazine Sulfoxide)
• 23503-68-6(2-(Methylsulfonyl) Phenothiazine)
• 58010-06-3(10H-Phenothiazine, 3-(phenylsulfonyl)-)
• 23503-67-5(2-(Methylsulfonyl)phenothiazine 5-Oxide)
• 19607-01-3(10-methyl-10H-phenothiazine 5,5-dioxide)
• 1225-11-2(&nbsp;)