- Rhodium-catalyzed aerobic conversion of 2-diazo-1,3-dicarbonyls to vicinal tricarbonyl compounds and their in-situ stability toward oxidative degradationBy Tsai, Yi-Ting and Zhu, Jia-Liang, Journal of Molecular Structure, 2023, 1274(Part_2), 134521
Cas no 120242-37-7 (2,2-Dihydroxy-1-phenyl-1,3-butanedione)
120242-37-7 structure
Product Name:2,2-Dihydroxy-1-phenyl-1,3-butanedione
CAS No:120242-37-7
MF:C10H10O4
MW:194.184003353119
CID:5667629
Update Time:2024-02-03
2,2-Dihydroxy-1-phenyl-1,3-butanedione Chemical and Physical Properties
Names and Identifiers
-
- 2,2-Dihydroxy-1-phenyl-1,3-butanedione
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- Inchi: 1S/C10H10O4/c1-7(11)10(13,14)9(12)8-5-3-2-4-6-8/h2-6,13-14H,1H3
- InChI Key: RAKAKMDGDMGMSH-UHFFFAOYSA-N
- SMILES: C(C1=CC=CC=C1)(=O)C(O)(O)C(=O)C
Experimental Properties
- Density: 1.328±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)
- Boiling Point: 313.5±37.0 °C(Predicted)
- pka: 8.53±0.50(Predicted)
2,2-Dihydroxy-1-phenyl-1,3-butanedione Production Method
Production Method 1
Reaction Conditions
1.1R:Et3N, S:MeCN, 5 min, rt
1.2R:p-AcNHC6H4SO2N3, 4-6 h, rt
2.1R:O2, C:Rh2(OAc)4, S:CH2Cl2, 5 min, rt; 3 h, rt
1.2R:p-AcNHC6H4SO2N3, 4-6 h, rt
2.1R:O2, C:Rh2(OAc)4, S:CH2Cl2, 5 min, rt; 3 h, rt
Reference
2,2-Dihydroxy-1-phenyl-1,3-butanedione Raw materials
2,2-Dihydroxy-1-phenyl-1,3-butanedione Preparation Products
2,2-Dihydroxy-1-phenyl-1,3-butanedione Related Literature
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Bruce Parkinson Energy Environ. Sci., 2010,3, 509-511
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Alexandre Vimont,Arnaud Travert,Philippe Bazin,Jean-Claude Lavalley,Marco Daturi,Christian Serre,Gérard Férey,Sandrine Bourrelly,Philip L. Llewellyn Chem. Commun., 2007, 3291-3293
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Yukiya Kitayama Polym. Chem., 2014,5, 2784-2792
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Daniel Messmer,Stefan Salentinig,Jakob Heier Nanoscale, 2019,11, 6929-6938
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Shintaro Takata,Yoshihiro Miura Phys. Chem. Chem. Phys., 2014,16, 24784-24789
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